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- Dendrons (1)
- Hydration (1)
- MALDI Massenspektrometrie (1)
- Pozzolana-lime mortars (1)
- Restoration (1)
- Silane (1)
- Stearates (1)
- Water absorption (1)
- Water-repellent admixtures (1)
Efficient Cu-catalyzed 1,3-dipolar cycloaddition reactions have been used to prepare two series of three regioisomers of G-1 and G-2 poly(triazole-pyridine) dendrons. The G-1 and G-2 dendrons consist of branched yet conformationally pre-organized 2,6-bis(phenyl/pyridyl-1,2,3-triazol-4-yl)pyridine (BPTP) monomeric and trimeric cores, respectively, carrying one focal and either two or four peripheral alkyl side chains. In the solid state, the conformation and supramolecular organization were studied by means of a single crystal X-ray structure analysis of one derivative. At the liquidsolid interface, the self-assembly behavior was investigated by scanning tunneling microscopy (STM) on graphite surfaces. Based on the observed supramolecular organization, it appears that the subtle balance between conformational preferences inherent in the dendritic backbone on the one side and the adsorption and packing of the alkyl side chains on the graphite substrate on the other side dictate the overall structure formation in 2D.
Pozzolanalime mortars modified with water-repellent admixtures were designed and studied to obtain mortars for restoration application. Powdered silane and calcium stearates were mixed with pozzolana, lime and sand and the chemicalphysical properties of the resulting mortars were evaluated by X-ray diffraction, electron microscopy (SEM-EDX), thermogravimetric analysis and FT-IR spectroscopy. The mechanical behavior, the pore structure and the hygric behavior were measured. The resistance of water-repellent mortars to the salt crystallization was evaluated. Both calcium stearates and powdered silane allowed good water-repellent protection even if the water-repellent agents and their dosage modified some physical properties and the hydration kinetic.