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Mapping Epoxy Interphases
(2005)
The breakage of a fiber and its effect on the strain energy is studied in a model composite, this is, a single fiber embedded in a dogbone specimen. The fracture process is recorded by an acoustic emission device, the crack patterns are monitored under a microscope. A finite element analysis is performed in order to estimate the energy released by different failure scenarios. The abilities and limitations of the acoustic emission analysis in characterizing different failure types in fiber reinforced composites are evaluated.
A mathematical model for the description of the overall crystallization of polymers has been developed which separates the pure geometric spreading of the semicrystalline superstructures from the increasing crystallinity inside these entities. The model uses the Avrami theory for the geometric part and a freely optional function for the increasing local crystallinity. The two functions are combined by a mathematical procedure called convolution. The free option of the local crystallinity function enables this model to permit calculation of this function, which is not accessible to direct measurement. Thus with given Avrami parameters and measured values of the time-dependent overall crystallinity, this function of the local crystallinity (secondary crystallization function) can be calculated. The model has been applied to test data produced by computer simulations.