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- Accelerated carbonation (1)
- Alkali-activated materials (1)
- Blended cements (1)
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- Calcined clays (1)
- Carbonation behaviour (1)
- Concrete (1)
- Cracks (1)
- Energy (1)
- Fibre pull-out (1)
Organisationseinheit der BAM
- 7.1 Baustoffe (4) (entfernen)
The thermal gravimetric analysis (TG) is a common method for the examination of the carbonation progress of cement-based materials. Unfortunately, the thermal properties of some components complicate the evaluation of TG results. Various hydrate phases, like ettringite (AFt), C-S-H and AFm decompose almost simultaneously in the temperature range up to 200 °C. Additionally, physical bound water is released in the same temperature range. In the temperature range between 450 °C and 600 °C the decomposition of calcium hydroxide and amorphous or weakly bound carbonates takes place simultaneously. Carbonates, like calcite, from limestone powder or other additives may be already contained in the noncarbonated sample material. For this research an attempt was made to minimise the influence of these effects. Therefore, differential curves from DTG-results of non-carbonated areas and areas with various states of carbonation of the same sample material were calculated and evaluated. Concretes based on three different types of cement were produced and stored under accelerated carbonation conditions (1 % CO2 in air). The required sample material was obtained by cutting slices from various depth of previously CO2-treated specimen and subsequent grinding. During the sample preparation, a special attention was paid that no additional carbonation processes took place. As reference method for the determination of the carbonation depth the sprayed application of phenolphthalein solution was carried out. Microscopic analysis where examined to confirm the assumptions made previously. Furthermore, the observed effect of encapsulation of calcium hydroxide by carbonates caused by the accelerated carbonation conditions was examined more closely.
Remediation of Cracks Formed in Grouted Connections of Offshore Energy Structures under Static Loads
(2018)
The future energy demand necessitates the exploration of all potential energy sources both onshore and offshore. Global trend has shifted towards offshore energy, which can be obtained from either carbon intensive or renewable options, hence requiring structures such as rigs, platforms, and monopiles. Most of these structures adopt easily installable construction techniques, where lower foundation need to be connected with the super structure by mean of grouted composite joints. Generally, these composite connections have exterior sleeve, interior pile and infill grout. Being located in remote offshore conditions, connections can experience considerable adverse loading during their lifetimes. Degradations were reported inside similar connections, which were installed in last three decades. Besides, grouting in the offshore sites may often be proven difficult, which eventually leads to reduced capacity of connections in the long run. Thus, repair and rehabilitation of such connections should be planned ahead to minimize operational delays and costs in the future. This study aims at characterizing the nature of crack generation in grouted connections and thereby identifying the potential of repair using suitable repair material. Scaled grouted joints were manufactured using a novel mold, and connections were loaded under static load to visualize the main failure pattern. The failure mechanism and loading capacity are found compatible to previous results from earlier literature. Grouted connection was then repaired using cementitious injectable grout. The effectiveness of the repair system is also discussed.
Alkali-activated materials are ideal for the repair of concrete structures in harsh environmental conditions due to their high durability in chemically aggressive environments. However, slag-based mortars, in particular, are prone to shrinkage and associated cracks. In this respect, the application of steel fibres is one solution to reduce the formation of shrinkage induced cracks and to improve post cracking behaviour of these mortars. This study investigated the influence of two different types of steel fibres on the tensile properties of two alkali-activated mortars. Direct tensile tests and single fibre pull-outs were performed to analyse the determining failure modes both on macro and micro scale. Mechanical testing was accompanied by non-destructive testing methods such as digital image correlation and acoustic emission for a detailed analysis of the fracture process.
The production of Portland cement causes a substantial environmental impact, since the calcination of limestone results in high emissions of carbon dioxide. The use of supplementary cementitious materials such as calcined clays as partial replacement for Portland cement offers a solution to limit this environmental impact. This paper investigates four clays from deposits in central Germany with the aim of obtaining pozzolans for the production of Portland-pozzolana cement. The results obtained show that the calcined clays possess pozzolanic properties, which differ depending on calcination temperature and the relative amounts of Kaolinite and 2:1 clay minerals.