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Eingeladener Vortrag
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In this paper we report on the characterization by X-ray computed tomography of calcium phosphate (CaP) and polycaprolactone (PCL) coatings on Ti-6Al-4V alloy scaffolds used as a material for medical implants. The cylindrical scaffold has greater porosity of the inner part than the external part, thus, mimicking trabecular and cortical bone, respectively. The prismatic scaffolds have uniform porosity. Surface of the scaffolds was modified with calcium phosphate (CaP) and polycaprolactone (PCL) by dip-coating to improve biocompatibility and mechanical properties. Computed tomography performed with X-ray and synchrotron radiation revealed the defects of structure and morphology of CaP and PCL coatings showing small platelet-like and spider-web-like structures, respectively.
Chemical companies must find new paths to successfully survive in a changing environment. The potential of digital technologies belongs to these. Flexible and modular chemical plants can produce various high-quality products using multi-purpose equipment with short down-times between campaigns and reduce time to market for new products. Intensified continuous production plants allow for difficult to produce compounds.
Therefore, fully automated “chemical” process control along with real-time quality control are prerequisites to such concepts and thus should be based on “chemical” information. The advances of a fully automated NMR sensor were exploited, using a given pharmaceutical lithiation reaction as an example process within a modular pilot plant. A commercially available benchtop NMR spectrometer was integrated to the full requirements of an automated chemical production environment such as , e.g., explosion safety, field communication, and robust evaluation of sensor data. It was thereof used for direct loop advanced process control and real-time optimization of the process. NMR appeared as preeminent online analytical tool and allowed using a modular data analysis tool, which even served as reliable reference method for further PAT applications.
In future, such fully integrated and intelligently interconnecting “smart” systems and processes can speed up the high-quality production of specialty chemicals and pharmaceuticals.
Concrete is typically perceived as a grey material that is relatively cheap and easy to use for mass application. The global relevance of concrete is often ignored despite its tremendous environmental, economic, and social impact. Construction materials are a major impact on the climate change, but building is inevitable for social and economic development. Therefore, it is important to develop more sustainable materials to build habitat and infrastructures. A reasonable approach to build more sustainably with concrete is to use agricultural by-products as chemical or fibrous performance enhancers and/or as replacement of cement in the binder.
Worldwide there is a variety of regulatory provisions addressing nanomaterials. The identification as nanomaterial in a regulatory context often has the consequence that specific legal rules apply. In identifying nanomaterials, and to find out whether nanomaterial-specific provisions apply, the external size of particles is globally used as a criterion. For legal certainty, its assessment for regulatory purposes should be based on measurements and methods that are robust, fit for the purpose and ready to be accepted by different stakeholders and authorities. This should help to assure the safety of nanomaterials and at the same time facilitate their international trading. Therefore, we propose a categorisation scheme which is driven by the capabilities of common characterisation techniques for particle size measurement. Categorising materials according to this scheme takes into account the particle properties that are most important for a determination of their size. The categorisation is exemplified for the specific particle number based size metric of the European Commission's recommendation on the definition of nanomaterial, but it is applicable to other metrics as well. Matching the performance profiles of the measurement techniques with the material property profiles (i) allows selecting the most appropriate size determination technique for every type of material considered, (ii) enables proper identification of nanomaterials, and (iii) has the potential to be accepted by regulators, industry and consumers alike. Having such a scheme in place would facilitate the regulatory assessment of nanomaterials in regional legislation as well as in international relations between different regulatory regions assuring the safe trade of nanomaterials.
Solutions of organic analytes of known mass fraction are typically used to calibrate the measurement processes used to determine these compounds in matrix samples. Appropriate value assignments and uncertainty calculations for calibration solutions are critical for accurate measurements. Evidence of successful participation in formal, relevant international comparisons is needed to document measurement capability claims (CMCs) made by national metrology institutes (NMIs) and designated institutes (DIs). To enable NMIs and DIs to update or establish their claims, in 2015 the Organic Analysis Working Group (OAWG) sponsored CCQM-K131 "Low-Polarity Analytes in a Multicomponent Organic Solution: Polycyclic Aromatic Hydrocarbons (PAHs) in Acetonitrile".
Polycyclic aromatic hydrocarbons (PAHs) result from combustion sources and are ubiquitous in environmental samples. The PAH congeners, benz[a]anthracene (BaA), benzo[a]pyrene (BaP), and naphthalene (Nap) were selected as the target analytes for CCQM-K131. These targets span the volatility range of PAHs found in environmental samples and include potentially problematic chromatographic separations. Nineteen NMIs participated in CCQM-K131. The consensus summary mass fractions for the three PAHs are in the range of (5 to 25) μg/g with relative standard deviations of (2.5 to 3.5) %.
Successful participation in CCQM-K131 demonstrates the following measurement capabilities in determining mass fraction of organic compounds of moderate to insignificant volatility, molar mass of 100 g/mol up to 500 g/mol, and polarity pKow < −2 in a multicomponent organic solution ranging in mass fraction from 100 ng/g to 100 μg/g: (1) value assignment of primary reference standards (if in-house purity assessment carried out), (2) value assignment of single and/or multi-component organic solutions, and (3) separation and quantification using gas chromatography or liquid chromatography.
The acronym IBESS stands for "Integrale Bruchmechanische Ermittlung der Schwingfestigkeit von Schweißverbindungen" which, translated from German, means "integral fracture mechanics determination of the fatigue strength of welds". the method introduced in this study is the outcome of a German Research cluster in which eight partners were involved. A list of them is found at the end this study. The IBESS method is characterized by a number of partially novel aspects and elements of fracture mechanics applied to the evaluation of fatigue stength of welds. The most important ones are: (a) Determination of fatigue crack propagation for mechanically/physically short and long cracks. (b) Determination of an elastic-plastic crack driving force for the treatment of mechanically short cracks. To that purpose an analytical expression for the cyclic J-integral was developed and validated against finite element results. (c) The gradual build-up of the crack closure phenomenon is determined by using cyclic R-curves which describe the crack size dependency of the fatigue crack propagation threshold in the physically short crack growth regime. (d) A physically meaningful initial crack size is defined for total life consideration. It is based on a two-criteria approach. Based on a cyclic R-curve analysis, the crack size at crack arrest is determined as a lower bound. If, however, a pre-existing crack-like defect is larger than this, its dimensions define the initial crack size. (e) Multiple crack propagation at the weld toe is considered. (f) In conjunction with this, the variation of the weld toe geometry is considered in a stochastic model. (g) As a result, both the fatigue limit (defined for 107 loading cycles) and the finite life (high cycle) fatigue S-N curve are obtained statistically. (h) At various analysis steps, parametric equations have been developed which allow for analytical calculations instead of complete stochastic analyses based on finite elements which are unrealistic even at present. (i) The method has been validated with a large number of S-N curves including two materials, three weldment types with two geometries, each referring to differnt manufacturing technologies and the as-welded and stressrelieved state. (j) Althrough not finally solved, an extended discussion is provided on the issue of welding residual stresses including their redistribution under cyclic loading. (k) A number of simplifications is proposed at lower analyses levels which, however, partly lack complete validation by now.