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Durch das alkalische Porenwassermilieu ist Stahl im Beton vor Korrosion geschützt. Unter ungünstigen Umgebungsbedingungen (Karbonatisierung, Chlorideintrag) kann die passive Deckschicht auf der Stahloberfläche zerstört werden. Im weiteren Verlauf können sich korrosionsbedingte Folgeschäden, wie Risse und Abplatzungen am Bauwerk ergeben. Um notwendige Sanierungsmaßnahmen sind frühzeitige und weitgehend zerstörungsfrei ermittelte Informationen über das aktuelle Korrosionsverhalten der Stahlbewehrung von großer Bedeutung. Die Potentialfeldmessung ist ein etabliertes und weit verbreitetes Verfahren zur Beurteilung des Korrosionszustandes der Bewehrung in Stahlbetonbauwerken. Mit Hilfe dieses Verfahrens können Bereiche aktiv korrodierender Bewehrung zerstörungsfrei lokalisiert werden. In der Regel kommt diese Messmethode bei der Detektion chloridinduzierter Korrosion zum Einsatz.
The present contribution evaluates four measuring series made by the Federal Institute of Material Research and Testing for the relations between train speed and ground vibration amplitudes. This experimental evaluation is supported by the simulation of the train passages at the different sites by using appropriate excitation mechanisms and forces as well as layered soil models which have been derived from impact measurements at each site.
High performance polymers of intrinsic microporosity (PIMs) have emerged as novel materials with broad applications from gas separation to electronic devices. Sufficiently rigid, even contorted polymer chains show only limited molecular mobility, therefore undergo inefficient packing and give rise to intrinsic microporosity with pore size generally smaller than 1 nm and BET surface areas larger than 700 m2/g. Further performance optimization and long-term stability of devices incorporating PIMs rely on our understanding of structure-processing-property relationships and physical aging, in which glass transition plays a key role. Up to now no glass transition temperature (Tg) of PIMs could be detected with conventional thermal analysis techniques before degradation. Decoupling the time scales responsible for the glass transition and the thermal decomposition is a reliable strategy to overcome this. This was achieved by employing fast scanning calorimetry (FSC) based on a chip sensor, which is capable to heat and cool a small sample (ng-range) with ultrafast rates of several ten thousand K/s. FSC provides definitive evidence of glass transition of a series of PIMs with a special consideration on the chain rigidity. The determined glass transition temperature of these PIMs follows the order of the rigidity of their backbone structures. FSC provides the first clear-cut experimental evidence of the glass transition of PIM-EA-TB with a Tg of 663 K, PIM-1 of 644 K and PIM-DMDPH-TB of 630 K at a heating rate of 1Χ104 K/s. Local fluctuations are featured in glass transition of highly rigid PIMs. As conformational changes are prevented by the backbone rigidity, the glass transition must rather be assigned to local small scale fluctuations.
Zum Schutz vor Korrosionsprozessen werden metallene Werkstoffe in der Automobilindustrie üblicherweise mit komplexen Beschichtungssystemen versehen. Durch eine Beschädigung des Beschichtungssystems kann bei Zutritt von Feuchtigkeit und korrosionsstimulierenden Ionen das Metallsubstrat korrodieren und unter Umständen die Beschichtung im Bereich neben der Verletzung enthaften. Dabei gibt es verschiedene Mechanismen, die zu einer Unterwanderung und Enthaftung der Beschichtung führen können. In jedem Fall wird aber die Dauerhaftigkeit des Korrosionsschutzes negativ beeinflusst und die Lebensdauer des Bauteils herabgesetzt.
Die Industrie versucht deshalb, Beschichtungssysteme zu entwickeln, die dem Vorgang der kathodischen Enthaftung bestmöglich widerstehen können. Einen kritischen Entwicklungs- und Qualifizierungsschritt stellt dabei die geeignete Prüfung auf kathodische Unterwanderung und Enthaftung dar, da eine Prüfung der Beschichtung möglichst schnell und kosteneffizient zu belastbaren Ergebnissen führen soll. Neben den industriell üblichen Salzsprühnebeltests kommen häufig elektrochemische Polarisationstests zur Anwendung. Verschiedene Automobilherstellerhaben verwenden jeweils angepasste Tests, die sich bezüglich der Prüfparameter unterscheiden. Bei allen Testvarianten wird aber versucht, durch Verschärfung der Prüfparameter kurze Prüfzeiträume zu erreichen. Dabei kann es aber dazu kommen, dass die real ablaufenden Mechanismen der Unterwanderung beeinflusst und verändert werden und das Prüfergebnis von Ergebnissen im Feld zum Teil stark abweicht.
Im Vortrag werden mit Blick auf die geltenden Regelwerke und Normen die Unterschiede verschiedener Prüfmethoden zur kathodischen Enthaftung bei organischen Beschichtungen vorgestellt und deren Aussagekraft kritisch betrachtet. Am Beispiel von systematischen Versuchsreihen an einem ausgewählten Kurzzeittest werden die Grenzen einiger Methoden herausgearbeitet und die Anwendbarkeit für Qualitätsprüfungen betrachtet. Durch den Ansatz der statistischen Versuchsplanung wird der Einfluss einzelner Prüfparameter auf die Enthaftung und das Ergebnis des Kurzzeittests gezeigt.
Crisis management, particularly the evacuation of handicapped people during a fire scenario presents a highly demanding challenge for nursing staff and rescue forces on site. The German research Project SiME is an interdisciplinary cooperation of university and non-university research institutions as well as medium-sized companies, which work together to develop strategies to manage such critical scenarios. In the SiME project, which is funded by the German Federal Ministry of Education and Research, evacuation characteristics of pedestrians with physical, mental or age-related disabilities are investigated to fit consisting numerical evacuation models with data. One of the major tasks of the OvGU was to set up a database of scenarios related to fire, explosion or substance releases in the working and living environment of handicapped people. Therefore, more than 463 fire Events occurring over the last decade in Germany were documented in this database and categorized by a suitable assignment of characteristics e.g. location of fire, ignition source, number of fatalities and injured.
Die Erkenntnisse zu reaktiven Brandschutzsystemen (RBS) werden kontinuierlich erweitert, was sich in der Entwicklung neuer Produkte und der Ausweitung des durch technische Regelungen abgedeckten Anwendungsbereichs äußert. Der hier vorliegende Beitrag konzentriert sich auf die Verwendung von RBS auf Stahlkonstruktionen. In den vergangenen zehn Jahren wurden, abgesichert durch neue Erkenntnisse aus der Forschung, die Anwendung auf Stahlzuggliedern mit offenem Profil präzisiert und im Rahmen allgemeiner bauaufsichtlicher Zulassungen (abZ) neu geregelt. Ferner wurde die Grundlage geschaffen, die Anwendung von RBS auf Zuggliedern mit kreisrundem Vollprofil zu bewerten und auf Basis der abZ zu ermöglichen. Neben einer umfassenden Darstellung der aktuellen nationalen und europäischen Regelungen zu RBS, werden technologische Besonderheiten und deren Einfluss auf den Regelungsinhalt im Beitrag thematisiert. In der jüngsten Vergangenheit stellt sich mit zunehmender Dringlichkeit die Frage nach der Bewertung der Dauerhaftigkeit von RBS für lange Zeiträume, wobei damit Nutzungsdauern weit jenseits der in den nationalen und europäischen Regelungen bereits etablierten 10 Jahre gemeint sind. In diesem Zusammenhang ist zu klären, wie der Feuerwiderstand von Konstruktionen zu bewerten ist, die bereits über lange Zeiträume mit RBS versehen sind.
In Europe biodiesel gained from rapeseeds are considered as an alternative to common fossil fuels due to its environmental performance and its independence from import of raw materials. Biodiesel is also suitable to serve as blending component to heating oil. In that case, it must be considered that changes of fuel composition might cause material degradation.
The objective of this research was to investigate the resistance of metallic materials exposed to heating oil, heating oil blend B20 with 20 % biodiesel and pure biodiesel. Furthermore, the resistance of metals to eight-year aged B10 and six-year aged pure biodiesel was evaluated. Ageing of biodiesel forms acids and water which might propagate metal corrosion. The investigated metals (aluminium, unalloyed steel, austenitic CrNi-steel, copper, die cast zinc and brass) are commonly used for components in middle distillate facilities.
According to DIN 50905-4 the immersed metals were exposed in a climate chamber at 50°C for 4 weeks. The metallic materials were evaluated as resistant if the annual corrosion rate due to uniform corrosion remained under 0.1 mm/year and no localized corrosion in the form of pitting occurred.
The corrosion rates of the exposed materials stayed far below the limit of 0.1 mm/year for all tested fuels. An exception was die cast zinc ZP0410 in eight-year aged B10; a corrosion rate up to 0.3 mm/year due to uniform corrosion was measured. In no case localized corrosion occurred. Copper and brass caused discolouration of biodiesel from yellow to green.
In conclusion, the tested metallic materials were resistant in heating oil, heating oil blend B20 and pure biodiesel at 50 °C. Even the metals exposed to six-year aged biodiesel and eight-year aged B10 showed no uniform or localized corrosion; except for zinc, which was not resistant in eight-year aged B10.
Two measurement campaigns of train-induced ground vibrations are evaluated for the vehicle-track-soil interaction. Ground vibrations, track vibrations and vehicle vibrations have been measured for train passages and impulse excitation and compared with theoretical results. The soil and the track-soil system are calculated by wavenumber integrals. The influence of the vehicle is introduced by a substructure method. By comparing theory and measurement the different components of excitation force and ground vibration can be analysed, the quasi-static excitation, track-alignment errors, the out-of-roundness of wheels, the wheel and rail roughness, and moreover, scattered axle impulses and ineffective high-frequency parts of the wheelset accelerations and forces.
Mortars for application on concrete, e.g. repair mortars or protective coatings, need to have a durable bond to the substrate. This bond is determined by the adhesion between the two materials and by the differential deformations of the mortar and the substrate. In the present contribution, the hygric deformations (shrinkage/expansion) of novel one-part alkali-activated mortars and their bond to concrete substrates are studied. Shrinkage of the mortars was studied at 50 % r.H., while expansion was studied on mortars stored over an open water surface (> 99% r.H.). The bond behaviour was studied by pull-off tests according to DIN EN 1542 and by optical microscopy.
The alkali-activated mortars exhibit hygric deformations much lower than the deformations of an established, commercial mortar for sewer maintenance that was tested as reference in parallel with the alkali-activated mortars. The bond behaviour of the alkali-activated mortars depends strongly on their mix-design and curing. Optical microscopy showed that in the mortars with lower bond strength, cracks developed in the mortar during curing. Mortars with appropriate mix-design and curing did not exhibit cracking, and their pull-off strength (up to > 3 MPa) conformed to the requirements of relevant standards.
Evakuierungsübung Werkstatt: positives Ergebnis
Evakuierungsübung Wohnbereich: Optimierungspotential identifiziert
•Lange Evakuierungszeiten
•Vorzeitige Rückkehr in das Gebäude / Freigabe
•Gefährdungsbeurteilungen
•Einweisung / regelmäßige Übung Assistenzmittel
•Intensivierung der Zusammenarbeit / Abstimmung mit örtlicher Feuerwehr
Subspace-based damage detection handling temperature effects and uncertainty in the reference
(2019)
Temperature variation can be a nuisance that perturbs vibration based structural health monitoring (SHM)approaches for civil engineering structures. In this paper, temperature affected vibration data is evaluated within a stochastic damage detection framework, which relies on a null space based residual. Besides two existing temperature rejection approaches – building a reference state from an averaging method or a piecewise method – a new approach is proposed, using model interpolation. In this approach, a general reference model is obtained from data in the reference state at several known reference temperatures. Then, for a particular tested temperature, a local reference model is derived from the general reference model. Thus, a well fitting reference null space for the formulation of a residual is available when new data is tested for damage detection at an arbitrary temperature. Particular attention is paid to the computation of the residual covariance, taking into account the uncertainty related to the null space matrix estimate. This improves the test performance, contrary to prior methods, for local and global damages, resulting in a higher probability of detection (PoD) for the new interpolation approach compared to previous approaches.
Temperature variation can be a nuisance that perturbs vibration based structural health monitoring (SHM) approaches for civil engineering structures. In this paper, temperature affected vibration data is evaluated within a stochastic damage detection framework, which relies on a null space based residual. Besides two existing temperature rejection approaches – building a reference state from an averaging method or a piecewise method – a new approach is proposed, using model interpolation. In this approach, a General reference model is obtained from data in the reference state at several known reference temperatures.
Then, for a particular tested temperature, a local reference model is derived from the general reference model. Thus, a well fitting reference null space for the formulation of a residual is available when new data is tested for damage detection at an arbitrary temperature. Particular attention is paid to the computation of the residual covariance, taking into account the uncertainty related to the null space Matrix estimate. This improves the test performance, contrary to prior methods, for local and global damages, resulting in a higher probability of detection (PoD) for the new interpolation approach compared to previous approaches.
Nanomaterials are a relatively new class of materials for which a regulatory framework still has to be established and regulators require comprehensive datasets of well characterized nanomaterials for the implementation. Especially information about the surface chemistry of nanoparticles is crucial, since it largely determines their biological and environmental fate. How the surface chemistry changes under relevant ageing conditions is of particular interest, because exposure will normally occur not to the pristine material but to a nanoform that underwent some kind of transformation.
In this talk, first a short overview about the contributions of division 6.1 to multiple European-funded projects will be presented, in which surface analytical techniques are used to improve the physical-chemical characterization of nanomaterials. Secondly, a study investigating the surface-chemical transformations of a representative set of titanium dioxide nanoparticles is discussed in more detail. The ageing has partly been performed at the BAM division 7.5, and the surface chemistry was analyzed using time-of-flight secondary ion mass spectrometry (ToF-SIMS) and X-ray photoelectron spectroscopy (XPS). By analyzing the complex mass spectra with principal component analysis (PCA), it was possible to identify even subtle changes that occur upon ageing.
Susceptibility of 304 stainless steel to crevice corrosion in electrochemically active fluids
(2019)
The susceptibility of AISI 304 stainless steel to crevice corrosion on the effect of contact with electrochemically active fluids was investigated using exposure and stepwise potentiostatic polarisation. Crevice materials made up of 304 SS and Polyether ether ketone (PEEK) forming two kinds of crevices including 304 SS-to-PEEK and 304 SS-to-304 SS were tested.
Susceptibility of 304 stainless steel to crevice corrosion in electrochemically active fluids
(2019)
The susceptibility of AISI 304 stainless steel to crevice corrosion on the effect of contact with electrochemically active fluids was investigated using exposure and stepwise potentiostatic polarisation. Crevice materials made up of 304 SS and Polyether ether ketone (PEEK) forming two kinds of crevices including 304 SS-to-PEEK and 304 SS-to-304 SS were tested.
According to the results of the experiments carried out, the following points can be concluded:
1. Exposure tests showed that specimens with the addition of SiO2 particles and polyaniline particles exhibit better corrosion resistance than specimens with the addition of only polyaniline particles or binder only.
2. Open circuit potential measurements showed that in the beginning of the experiments, both coatings had an open circuit potential 100 mV higher than carbon steel. Within one day of immersion, the potential of carbon steel increased significantly, indicating the formation of oxide layer. After extended exposure the carbon steel potential sat between PS1 (which had higher potential) and PS2 (which had a lower potential) and all three were in the range –600 mV to –500 mV vs Ag/AgCl.
3. Both coatings PS-1 and PS-2 were degraded with increasing exposure time, shown by the decrease of absolute impedance value at low frequency range after 2, 4, and 6 days exposure.
4. Potentiodynamic test was performed after 3 hours and 6 days exposure, and it was shown that the coating in the initial stage exhibited more passive behavior than the specimens exposed for 6 days.