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Various methods have been used for introducing fire retardant additives into polymers. Deposition of thick fire retardant coatings directly onto polymer substrates is an alternative technique. An important advantage of the coating technique is the preservation of the physical and chemical integrity of the polymer material. Moreover, the fire retardancy of the polymer materials can be achieved following their production. Suitable coating materials are inorganics, intumescent, char-forming, oxygendiluting, and cooling or radical quenching layers. The most important problem is to achieve sufficient coating thickness to withstand the direct attack of flame and to protect the polymer bulk from pyrolysis, otherwise blistering of coating, caused by emitted pyrolysis gases, is often observed. To avoid blistering of coating, the adhesion between polyolefin substrate and fire retardant coating has to be extraordinarily high.
In order to achieve such a high level of adhesion, the polymer surface has to be modified with adhesion-promoting functional groups. The deposition of thin plasma polymers as adhesion-promoting layers with NH2, OH or COOH groups has been the most suited method. These functional groups are able to form covalent bonds and other interactions between the fire-resistant coating and the plasma-modified polyolefin substrate. Additionally, the plasma polymer counteracts the strong mechanical stresses in the laminate on exposure to high temperatures by its flexibility.
The implementation of fluorescent methods is of outstanding importance in the field of optical chemical sensor Technology and biosciences. Their bioanalytical applications are manifold including fluorescence microscopy, fluorescence in situ hybridization, DNA sequencing, fluorescence-activated cell sorting, immunoassays, analysis of DNA and Protein microarrays, and quantitative PCR, just to name a few examples. Particularly, fluorescence microscopy is a valuable method in the versatile field of biomedical imaging methods which nowadays utilizes different fluorescence Parameters like emission wavelength/Color and lifetime for the discrimination between different targets. Sectional Images are available with confocal microscopes. Tissue, cells or single cellular compartments can be stained and visualized with fluorescent dyes and biomolecules can be selectively labeled with fluorescent dyes to Monitor biomolecular interactions inside cells or at Membrane bound receptors.
On the other hand , fluorophores can act as indicator (or "molecular probe") to visualize intrinsically colorless and non-fluorescent ionic and neutral analytes such as pH, Oxygen (pO2), metal ions, anions, hydrogen peroxide or bioactive small organic molecules such as Sugars or nucleotides. Thereby, their photoluminescent properties (fluorescence or phoporescence intensity, exitation and/or Emission wavelength, emission lifetime or anisotropy) respond to the presence of these species in their immediate Environment. In general, the use of luminescent probes has the advantage that they can be delivered directly into the sample, and detected in a contactless remote mode. By now, these probes are often encapsulated in different types of nanoparticles (NPs) made from (biodegradable) organic polymers, biopolymers or inorganic materials like silica or bound to their surface.
Seit 2009 entsteht die historisch-kritische Hybridediton von Goethes „Faust“. Im Januar 2013 ist im Rahmen dieses editorischen Unternehmens die Röntgenfluoreszenzanalyse (RFA) zum Einsatz gekommen, um auf der Grundlage der Zusammensetzung der verwendeten Eisengallustinten entstehungsgeschichtliche Erkenntnisse über das handschriftliche Material zu gewinnen. Im Mittelpunkt stand neben der zeitlichen Einordnung von Handschriften vor allem die Identifikation von unterscheidbaren Bearbeitungsschichten innerhalb der jeweiligen Handschrift. Besonderes Interesse kommt dabei denjenigen Handschriften zu, von denen sicher ist oder angenommen wird, dass Goethe sie über längere Zeit hinweg oder sogar in sehr großen Abständen bearbeitet hat.
Die von der traditionellen Philologie in Anschlag gebrachten äußeren und inneren Gründe und die darauf gestützten Hypothesen haben nicht ausgedient. Hypothesen zur Datierung von Handschriften Goethes lassen sich in der Regel gut anhand bestehender materieller Zusammenhänge (wie der Zuordnung des Papiers in Kombination mit der Bestimmung der Schreiberhand) verifizieren. Dagegen ermöglicht materialwissenschaftliche Charakterisierung der Eisengallustinten alleine zunächst noch keine vergleichbar genauen Datierungen. Eine Kombination der beiden Zugänge und Verfahren kann jedoch dort Erkenntnisse zutage fördern, wo die traditionellen philologischen Mittel ausgeschöpft sind. Dies wird exemplarisch innerhalb der Publikation gezeigt werden.
Given their unique properties, ultrashort laser pulses with durations in the femtosecond to picosecond range currently open new avenues in the field of laser materials processing, resulting in groundbreaking new applications based on laser-induced surface functionalization. This article reviews the usability of temporally distributed energy deposition via double-pulse irradiation in applications based on laser ablation. This includes simple new techniques for surface nanostructuring and improved sensitivities in spectroscopic material analyses.
Im Beitrag wird über die mühevolle Sanierung von Objekten eines Kunstzweiges in Polen berichtet, der eine besondere diffizile Stellung in der langen Reihe von Werken der Kunst einnimmt. Es geht dabei um die bleiverglasten farbigen Fensterverschlüsse in Kirchen oder Profangebäuden. Das sind feingliedrige Gitterwerke aus zerbrechlichen und korrosionsanfälligen Materialien, die durch aggressive Umweltschadstoffe schweren Belastungen ausgesetzt sind. Wie bei keinem anderen Kunstzweig haben die einzelnen Bestandteile der Glasmalerei sowohl praktisch-technische als auch ästhetisch-künstlerische Aufgaben zu erfüllen. Bei der Restaurierung dieser Glasmalereifenster geht darum, neuentwickelte Methoden der Restaurierung oder Konservierung anzuwenden und letzte Erkenntnisse naturwissenschaftlicher Forschung zu nutzen. Diese Projekte sind ein Beispiel der interdisziplinären Zusammenarbeit zwischen Denkmalpflegern, Naturwissenschaftlern und Restauratoren aus Deutschland und Polen. An ausgewählten Restaurierungsobjekten wird von der fachgerechten, denkmalpflegerisch verantwortungsbewussten Arbeit berichtet.
This paper describes the experimental calibration of an existing Wiegmann–Polonceau roof truss based on modal parameters. Dynamic tests allowed the determination of the natural frequencies and mode shapes of the global truss and of individual truss members. The global and local modal configurations as well as coupled vibration of truss members are discussed. In addition, as truss members are axially loaded, the effect of stress stiffening on the modal parameters is considered. Moreover, several finite element models with different modelling assumptions for the details of the connections and member geometrical characteristics such as gusset plates and turnbuckles were developed. A suitable numerical model was chosen to represent the truss structural behavior. This paper focuses on the local measurement and analysis strategies applied to single truss members. The possibility of using a local analysis method, namely methods that consider individual members as part of a structure, is demonstrated to assess the behavior of the global truss structure. The comparison of the results after calibration reveals a very good correlation between the experimentally identified and numerically estimated modal parameters of the historic truss.
Literature provides a wide range of hydrogen diffusion coefficients for low alloyed steels used in power plants. In fact, experimental boundary conditions and calculation methods have influence on the determination of these coefficients. The diffusion and trapping behavior in creep-resistant steel 7CrMoVTiB10-10 has been studied. Based on experimental carrier gas hot extraction (CGHE) data, a numerical model has been developed to describe the hydrogen transport and respective hydrogen distribution at elevated temperatures. The numerical results suggest that common calculation methods for diffusion coefficients are limited for experimental data analysis. The sample preparation time before CGHE experiment influences the determined diffusion coefficients with the consequence that non-homogeneous hydrogen concentration profiles have to be considered in the simulations.
High-speed photography was applied to investigate the explosive behavior of bubble-containing systems of the type organic solvent---gaseous oxidizing agent. Knowledge about the explosive behavior of such systems is of great importance, for example, for the safe operation of chemical reactors in oxidation processes in the liquid phase. Examples of the complex dynamical reaction of bubbles are elucidated where bubble-containing liquids were subjected to the impact of shockwaves. The different stages of the shock-induced explosive behavior of oxygen and oxygen plus inert gas bubbles were studied experimentally and theoretically mainly in liquid cyclohexane. Other solvents, such as cumene and 2-ethylhexanal, have been found to show that shock-induced bubble explosions can occur even if the gas phase of the bubble is not in the explosive range before impact. Tue influence of different parameters on the bubble Explosion process, such as the composition of the bubbles and the initial pressure, was investigated.
Limiting conditions for bubble explosions were determined. In addition to the behavior of individual bubbles, the interaction of exploding bubbles with one another was observed, which provides information on the Propagation mechanism of self-sustaining bubble-detonation waves. The results are important for the safety assessment of the explosion risks in corresponding two-phase systems.
Electromagnetic methods are widely used in Non-destructive Testing industries (NDT). In order to meet the requirements, safety-relevant products and structures have to be tested reliably during production or within subsequent maintenance cycles. For this purpose industrial users call for adapted testing methods which allow the detection of relevant defects such as cracks and pore in ferromagnetic or conductive materials. Automated testing systems and the application of sensor arrays are of great interest in order to enhance inspection quality and to decrease testing time and costs. Magneto resistance (MR) sensors like giant magneto resistance (GMR) or tunnel magneto resistance sensor (TMR) have proofed their suitability in many NDT-applications due to their extraordinary properties which combine high field sensitivity, a high spatial resolution and low costs. Due to their small size these sensors can be useful – in addition to the pure detection task – for a more detailed defect characterization and defect reconstruction providing defect size, orientation and geometry. This chapter gives a brief introduction of electromagnetic testing methods, i.e., magnetic particle inspection (MPI) and eddy current testing (ET), followed by two different approaches for which MR sensor arrays were successfully adapted.
Due to their simple and reliable application, elastomers are used for many tasks. Many fields of application like transport, aviation and process technology, entail low temperatures where proper functionality of the employed seals has to be ensured. Therefore, understanding the low temperature behavior of elastomeric seals is important for safe seal operation to restrict the temperature application range.
For all areas of application, the question of seal lifetime is also important for replacement or maintenance intervals. The lifetime is especially important in applications that allow no seal replacement. Since the seal can determine the lifetime of storage in such cases, reliable lifetime estimation is necessary for these applications, and requires an extensive knowledge of the specific aging behavior.
Sol-Gel wood preservation
(2017)
The sol–gel-based modification of wood introduces chemical substances into wood in order to improve its characteristics and impart new properties. It stabilizes dimensions of wood (timber) components, increases its strength and resistance to water, and reduces cracking. Many sol–gel-based impregnations aim to protect against wood rot and fire. In most cases, the treatments are performed with alkoxysilanes, polysiloxanes, colloidal silica, or organically modified silica. In addition further substances such as titania, copper, and boron compounds have been applied on different types of wood. The precursor solutions were introduced by immersion, painting, or spray coating of wood followed by a drying and heat treatment process. The structure of the impregnated wood was investigated by SEM, EDX, TEM, FT-IR, NMR, and XRD. Frequently, test procedures according to standards were applied in order to assess the improvement in properties. Investigations demonstrate that silica and titania impregnations change properties first of all with increasing the amount of absorbed inorganic material (WPG), which is determined by the concentration of precursors, amount and size of particles in the sol, and the impregnation method. Sol–gel impregnation can be considered as an environmentally friendly approach of wood preservation. Various improvements in wood properties can be achieved such as reduced water uptake and volume swelling, improved weather stability, resistance against biodegradation, and fire retardancy.
Inductively coupled plasma mass spectrometry (ICP-MS) is a well-established analytical method for multi-elemental analysis in particular for elements at trace and ultra-trace levels. It has found acceptance in various application areas during the last decade. ICP-MS is also more and more applied for detection in the life sciences. For these applications, ICP-MS excels by a high sensitivity, which is independent of the molecular structure of the analyte, a wide linear dynamic range and by excellent multi-element capabilities. Furthermore, methods based on ICP-MS offer simple quantification concepts, for which usually (liquid) standards are applied, low matrix effects compared to other conventional bioanalytical techniques, and relative limits of detection (LODs) in the low pg g−1 range and absolute LODs down to the attomol range.
In this chapter, we focus on new applications where the multi-element capability of ICP-MS is used for detection of lanthanoides or rare earth elements, which are applied as elemental stains or tags of biomolecules and in particular of antibodies.
Inductively coupled plasma mass spectrometry (ICP-MS) is based on formation of positively charged atomic ions in a high-frequency inductively coupled Argon plasma at atmospheric pressure. The ions are extracted and transferred from the plasma source into a mass analyzer operated at high vacuum via an interface equipped with a sampling and a skimmer cone. The ions are separated in the mass analyzer according to their charge to mass ratio. The ions are converted at a conversion dynode and are detected by use of a secondary electron multiplier or a Faraday cup.
From an analytical point of view, ICP-MS is a well-established method for multi-elemental analysis in particular for elements at trace- and ultra-trace levels. Furthermore, methods based on ICP-MS offer simple quantification concepts, for which usually (liquid) standards are applied, low matrix effects compared to other conventional analytical techniques, and relative limits of detection (LODs) in the low pg g−1 range and absolute LODs down to the attomol range. For these applications, ICP-MS excels by a high sensitivity which is independent of the molecular structure and a wide linear dynamic range. It has found acceptance in various application areas and during the last decade ICP-MS is also more and more applied for detection of rare earth elements particularly in the life sciences.
Due to the fact that all molecules introduced into the high temperature of the plasma in the ion source were completely dissociated and broken down into atoms, which are subsequently ionized, all elemental species information is completely lost. However, if the different species are separated before they enter the plasma by using adequate fractionation or separation techniques, then ICP-MS can be used as a very sensitive element-specific detector. We will discuss this feature of ICP-MS in this chapter in more detail at hand of the speciation of gadolinium-containing contrast agents.
Unterschiedliche Werkstoffeigenschaften reagieren auf jeweils spezifische Weise auf Gittertyp, Gefüge und Defekte. Für die schadenstolerante Betrachtung von Werkstoff und Bauteil ist das Verständnis dieser Zusammenhänge essentiell. Der Beitrag gibt mit Hinblick auf additiv gefertigte metallische Bauteile mittels Selective Laser Melting einen kurzen, keineswegs vollständigen Überblick über Faktoren, die die Steifigkeit, Festigkeit, Duktilität, Zähigkeit, Ermüdungsrissausbreitung und Schwingfestigkeit beeinflussen. Es wird aufgezeigt, wie die bruchmechanische Betrachtung zur Quantifizierung der Zusammenhänge beitragen kann.
China
(2017)
The contributions included in the book provide a reconnaissance on the conservation rules and current protection policies of more than 100 countries, with particular attention to the emerging nations and twentieth-century architecture. The contributions illustrate the critical issues related to architectural listings, with a brief history of national approaches, a linkography and a short bibliography. The book also provides a short critical lexicography, with 12 papers written by scholars and experts including topics on identities, heritages, conservation, memories and the economy. By examining the methods used to designate building as heritage sites across the continents, this book provides a com¬prehensive overview of current protection policies of twentieth-century architecture as well as the role of architectural history.
In diesem Beitrag werden numerische Analysen der mechanischen Eigenschaften von Lehmsteinmauerwerk unter Druck- und Schubbeanspruchung vorgestellt. Ergebnisse von einachsigen Druck- und Schubversuchen an Wandprüfkörpern lieferten dafür grundlegende mechanische Kennwerte im elastischen Bereich und im nichtelastischen Versagenszustand.Die Testergebnisse zeigten, dass verschiedene Vorlasten keinen wesentlichen Einfluss auf die Schubfestigkeit haben. Außerdem bestätigten die Ergebnisse das spröde Verhalten von Lehmsteinmauerwerk unter einachsiger Druckbelastung und es zeigte sich, dass das Versagen des Lehmsteinmauerwerks unter Scherbelastung entlang der Mörtelfugen erfolgt.
Die experimentellen Ergebnisse wurden verwendet, um das Verhalten von Lehmsteinmauerwerk durch nichtlineare Finite-Elemente-Methoden auf der Basis von Makro- und Mikro-Modellierungsansätzen zu simulieren. Entsprechendes konstitutives Materialverhalten und Zwängungen, die in den Versuchen durch die Art der Lasteinleitung in Form von Stahlprofilen und Stahlschuhen verursacht wurden, wurde in den Modellen berücksichtigt. Es wurde zuerst ein auf der Grundlage der experimentellen Daten kalibriertes Makro-Modell entwickelt, was zu einer brauchbaren Vorhersage des Versagensverhaltens der Mauerwerksprüfkörper führte. Die simulierten Spannungs-Dehnungs-Kurven, berechnet unter einachsiger Druckbelastung, zeigten eine gute Übereinstimmung mit den Ergebnissen der geprüften Mauerwerkskörper, sowohl im elastischen als auch im nichtelastischen Bereich. Ein vereinfachter Ansatz, basierend auf der Makro-Modellierung und einem homogenisierten Prüfkörper, kann für die Untersuchung größerer Tragsysteme oder ganzer Gebäude angewendet werden, wobei eine zufriedenstellende Genauigkeit bei geringerem Rechenaufwand erreicht wird. Obwohl das globale Spannungs-Dehnungs-Verhalten zufriedenstellend wiedergegeben wurde, ist ein solches nichtlineares isotropes Kontinuumsmodell für Lehmsteinmauerwerk nicht in vollem Umfang geeignet, um das bei den Versuchen beobachtete Rissbild an den Prüfkörpern zu simulieren.
Eine detailliertere Analyse des mechanischen Verhaltensdes Mauerwerks wurde mit einem Mikro-Modellierungsansatz durchgeführt. Das Modell, in dem ein Wandabschnitt nicht mehr homogenisiert, sondern in konkrete Stein- und Fugenelemente diskretisiert wird, hat sich insbesondere für das Verhalten von Lehmsteinmauerwerk unter Schubbeanspruchung als geeignet erwiesen. Die Auswertung der Spannungsverteilungen bei der nichtlinearen Analyse lieferte Informationen über die tatsächlichen Mechanismen der Lastübertragung zwischen Steinen und Mörtelfugen. Mit dem Mikro-Modell war es möglich, das nichtlineare Verhalten von Lehmsteinmauerwerk vorherzusagen. Es stellt somit ein geeignetes Werkzeug für die Untersuchung der Versagensmechanismen von Lehmsteinmauerwerk dar. Allerdings sind aufgrund der Komplexität des Modells für die Beschreibung der Stein/Mörtel-Schnittstelle und die hohe Anzahl an erforderlichen mechanischen Parametern umfassendere Untersuchungen notwendig. Die zukünftige Forschung wird sich daher einerseits auf die Verfeinerung der numerischen Modelle und andererseits auf die Simulation komplexer Belastungssituationen und Gebäudekomponenten konzentrieren.
Ziel der vorliegenden Untersuchung war es zu überprüfen, inwiefern eine Bemessungsvorschrift auf Basis von Teilsicherheitsbeiwerten im Lehmmauerwerksbau möglich ist. Bemessungsvorschriften im konventionellen Mauerwerksbau und im Lehmmauerwerksbau waren aufgrund des prinzipiell gleichen Tragverhaltens stets eng miteinander verknüpft. Die im Rahmen dieser Arbeit durchgeführten Druckversuche an Lehmmauermörtel, Lehmsteinen und Lehmmauerwerk konnten zeigen, dass die Streuungen der Festigkeiten von Lehmbaustoffen aufgrund der industriellen Herstellung sehr gering sind. Es konnte festgestellt werden, dass eine Bemessung auf Grundlage des semiprobabilistischen Bemessungskonzeptes in Anlehnung an den konventionellen Mauerwerksbau möglich ist. Neben einem ersten Vorschlag des Teilsicherheitsbeiwertes für den Lastzustand Druck werden Vorschläge für Prüfvorschriften im Lehmbau beziehungsweise deren Modifikation unterbreitet und künftige Forschungsschwerpunkte herausgearbeitet.
Gravity has significant effects on alloy solidification, primarily due to thermosolutal convection and solid phase buoyancy. Since 2004, the European Space Agency has been supporting investigation of these effects by promoting in situ X-ray monitoring of the solidification of aluminium alloys on microgravity platforms, on earth, and in periodically varying g conditions. The first microgravity experiment-investigating foaming of liquid metals - was performed on board a sounding rocket, in 2008. In 2012 the first ever X-ray-monitored solidification of a fully dense metallic alloy in space was achieved: the focus was columnar solidification of an Al-Cu alloy. This was followed in 2015 by a similar experiment, investigating equiaxed solidification. Ground reference experiments were completed in all cases. In addition, experiments have been performed on board parabolic flights-where the effects of varying gravity have been studied. We review here the technical and scientific progress to date, and outline future perspectives.
Offshore wind turbines enter unknown territory, especially where the foundations are concerned. This is because offshore wind power can only make use of the experience from the common offshore constructions used by the oil and gas industry to a limited extent. The offshore wind industry has tried to reduce foundation dimensions, especially the pile lengths, as much as possible compared with those of the oil and gas industry. This is because with the large number of wind turbines involved it can provide considerable economic advantages. On the other hand, the stability of the foundations is additionally at risk because due to the much larger number of cyclic loads they are subjected to it is very difficult to predict how they will behave. Since offshore wind farms are manufactured in series, every systematic fault in the foundation acts as a series fault for a large number of turbines. This calls for monitoring – and the right dimensions of pile foundation, the most common type of foundations used for wind turbines
A great deal is possible, even on the seabed. Together, wind and waves shake the foundations of the offshore wind turbines. "ere is also the “normal” current and ebb and #ow of the tides that are so distinctive in the North Sea. Pore water pressure can also occur on the seabed, loosening it. Where monopiles are involved, the worst case is that the stability of the whole turbine can be altered – even if such a monopile rammed into the seabed has a diameter of up to eight metres. Over half the planned offshore wind turbines in the North and Baltic Seas are to have monopile foundations, and over 40 % are to have multi-pile foundations, designed for example as a tripod. "is is why pile foundations and their loads deserve special attention. For one thing above all is to be avoided in plant operations, and that is the risk of turbine tilt.
Welding is the most important joining technology. In the steel construction
industry, e.g. production of windmill sections, welding accounts for a
main part of the manufacturing costs and resource consumption. Moreover, social
issues attached to welding involve working in dangerous environments. This aspect
has unfortunately been neglected so far, in light of a predominant focus on economics
combined with a lack of suitable assessment methods. In this chapter,
exemplary welding processes are presented that reduce the environmental and
social impacts of thick metal plate welding. Social and environmental Life Cycle
Assessments for a thick metal plate joint are conducted for the purpose of
expressing and analysing the social and environmental impacts of welding.
Furthermore, it is shown that state-of-the-art technologies like Gas Metal Arc
Welding with modified spray arcs and Laser Arc-Hybrid Welding serve to increase
social and environmental performance in contrast to common technologies, and
therefore offer great potential for sustainable manufacturing.
The investigation of physical properties and chemical composition generates data important for answering art-historical questions. Due to technological developments, technical diagnostics in art and culture are in ever-greater demand in such fields of transdisciplinary research. Based on one example, a collar drawing from the Berlin Diez albums, the present paper aims to give some insights into the multi-instrumental approach in the material analysis of cultural artefacts. The same methods were also applied to other drawings from the Diez Albums.
An ideal sensor system is a combination of a selective receptor, an effective transducer, and a sensitive detector. To utilize molecularly imprinted polymers (MIPs) as responsive recognition phases in sensors, the employment of fluorescent molecules or nanoparticles (NPs) that show prominent changes in their spectroscopic properties after binding of the target molecule in the MIP’s cavity is particularly attractive. Such fluorescent MIPs (fMIPs) act through target-induced quenching, enhancement, or spectral shifts of the fluorescence. This contribution introduces different strategies of incorporation of fluorescent dyes, probes, and NPs into fMIPs. In addition, various sensing mechanisms are reviewed, and depending on the application of the sensor, the different deployable formats, their advantages, drawbacks, and impact will be presented and discussed.