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Eingeladener Vortrag
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Zero wear (Null Verschleiß)
(2013)
Tribologie des céramiques
(2013)
Les ceramiques modernes sont differentes des ceramiques traditionnelles (carrelage, materiaux de construction, porcelaine); on les distingue par des adjectifs tels que « techniques », « industrielles » ou « thermomecaniques ». Les ceramiques industrielles sont caracterisees par leur caractere refractaire marque et de grandes duretes. Leur mediocre tenacite explique leur sensibilite ä la presence de defauts, d'oü leur reputation d'etre peu resistantes et cassantes.
Les ceramiques techniques sont utilisees pour:
• leurs proprietes electriques ou dielectriques;
• leurs proprietes magnetiques et de supraconducteurs ;
• leurs proprietes optiques;
• leurs proprietes chimiques;
• leurs proprietes biologiques;
• leurs proprietes nucleaires.
En outre, eiles sont employees pour leurs proprietes mecaniques, thermomecaniques et tribologiques, ainsi que pour leur tenue face ä la corrosion. Nous allons nous concentrer sur leur comportement tribologique.
Environmental legislations prescribe globally more and more environmentally acceptable lubricants (EALs), based on esters and polyglycols. The compatibility of EALs with tribo-materials used in hydraulic System such sliding parts and oil seals needs to be considered. Aluminium alloys are widely used as lightweight material for sliding parts in many applications. It is necessary to provide optimized design on its surface because of the inferior wear resistance under mixed/ boundary lubrication. The AA6061 alloy (uncoated and coated by different conversion coatings) and an alternative AI-Fe-XY alloy (uncoated) were tested by a continuous sliding test (cylinder-on-disk) under mixed/boundary lubrication with commercially available EALs at 80°C against 100Cr6 Steel. Appropriate combinations of aluminium alloys (coated or uncoated) and commercially available EALs have the potential to compete with conventional tribo-system like steel/steel lubricated with mineral hydraulic fluids under mixed/boundary lubrication.
The tribological profile of alumina (99,7%) mated against binderless niobium Carbide (NbC) rotating disks under under unlubricated (dry) friction and the type of motions of unidirectional sliding (0.1 m/s to 7.5 m/s; 22°C and 400°C) and oscillation (f= 20 Hz, Ax= 200 mm, 2/50/98% rel. humidity, n= 105/106 cycles) was determined including the microstructure and mechanical properties. The obtained tribological data were benchmarked with different ceramics, cermets and thermally sprayed coatings. The established tribological profile revealed a strong position of NbC under tribological considerations and for closed tribosystems against traditional references, like WC, Ci‘3C2, (Ti,Mo)(C,N), etc..
The tribological profile of alumina (99.7%) mated against rotating disks in two niobium carbide (NbC) grades were determined in unidirectional sliding tests (0.1 m/s to 7.5 m/s; 22°C and 400°C) as well as in oscillation tests (f= 20 Hz, δx= 0.2 mm, 2/50/98% rel. humidity, n= 106 cycles) under unlubricated (dry) conditions. In addition, the microstructure and mechanical properties of NbC were determined as well. The reason for testing hot-pressed NbC was to avoid side effects generated by sintering additives and/or second phases. The tribological data obtained were benchmarked with different ceramics, cermets and thermally sprayed coatings. NbC exhibited low wear rates under dry sliding associated with high load carrying capacity. The tribological profile established revealed a strong position of NbC under tribological considerations and for closed tribo-systems against traditional references, such as WC, Cr3C2, (Ti,Mo)(C,N), etc.
The tribological profile of alumina (99.7%) mated against rotating disks in two niobium Carbide (NbC) grades were determined in unidirectional sliding tests (0.1 m/s to 7.5 m/s; 22°C and 400°C) as well as in oscillation tests (f= 20 Hz, Ax= 0.2 mm, 2/50/98% rel. humidity, n= 1062 c* y*c *l es) under unlubricated (dry) conditions. In addition, the microstructure and mechanical properties of NbC were determined as well. The reason for testing hot-pressed NbC was to avoid side effects generated by sintering additives and/or second phases. The tribological data obtained were benchmarked with different ceramics, cermets and thermally sprayed coatings. NbC exhibited low wear rates under dry sliding associated with high load carrying capacity. The tribological profile established revealed a strong Position of NbC under tribological considerations and for closed tribo-systems against traditional references, such as WC, Cr3C2, (Ti,Mo)(C,N), etc..