A systematic study of annealing behavior of drawn PMMA fibers was performed. Annealing Dynamics were investigated under different environmental conditions by fiber longitudinal shrinkage monitoring. The shrinkage process was found to follow a stretched exponential decay function revealing the heterogeneous nature of the underlying molecular dynamics. The complex dependence of the fiber shrinkage on initial degree of molecular alignment in the fiber, annealing time and temperature was investigated and interpreted. Moreover, humidity was shown to have a profound effect on the annealing process, which was not recognized previously. Annealing was also shown to have considerable effect on the fiber mechanical properties associated with the relaxation of molecular alignment in the fiber. The consequences of fiber annealing for the climatic stability of certain polymer optical fiber-based sensors are discussed, emphasizing the importance of fiber controlled pre-annealing with respect to the foreseeable
operating conditions.
Systematic investigation of annealing behavior of drawn PMMA fibers was performed. Dynamics of annealing process were measured under different environmental conditions by fiber longitudinal shrinkage monitoring. Process was found to follow stretched exponential decay function indicating heterogeneous nature of underlying molecular dynamics. Consequences of fiber annealing for climatic stability of polymer optical fiber-based sensors are discussed, emphasizing importance of fiber controlled post-fabrication annealing. Dependence of induced fiber shrinkage on annealing time, temperature and fiber drawing conditions is investigated and interpreted. In addition, strong influence of humidity on annealing process was observed, which was not recognized in previous studies. This further highlights role of fiber post-fabrication thermal treatment with respect to intended operating conditions.