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Intermediate level waste often contains residual water or other liquids. The liquids can be decomposed due to radiolysis and can also vaporize especially under fire impact. These pressure generating processes are described. One example for the pressure determination inside a closed cask is discussed using two different approaches: analytical and CFD
Packages for intermediate level waste (ILW) often contain residual water besides the actual waste. The water either exists as obvious free water or it may be bound physically or chemically, e.g. as pore water. A water driven gas generation could occur by vaporisation and by radiolysis. Steam as the result of vaporisation causes an increasing pressure inside a package and can affect corrosion. Vaporisation and condensation processes itself change the thermal behavior of the content especially during strongly unsteady thermal situations like accident fire situations. Radiolysis changes the chemical composition of the content which could cause an unexpected interaction, e.g. hydrogen embrittlement. Besides the pressure build-up the radiolysis of water generates hydrogen and oxygen, which can be highly flammable respectively explosive. The gas generation caused by vaporisation and radiolysis must be taken into account during the design and the safety assessment of a package. Pressure build-up, a changed thermal behavior and content chemistry, and especially the risk of accumulation of combustible gases exceeding the limiting concentration for flammability has to be considered in the safety assessment. Approaches to ensure the transportability of stored packages due to radiolysis will be discussed.
Packages for intermediate level waste (ILW) often contain residual water besides the actual waste. The water either exists as obvious free water or it may be bound physically or chemically, e.g. as pore water. A water driven gas generation could occur by vaporisation and by radiolysis. Steam as the result of vaporisation causes an increasing pressure inside a package and can affect corrosion. Vaporisation and condensation processes itself change the thermal behavior of the content especially during strongly unsteady thermal situations like accident fire situations. Radiolysis changes the chemical composition of the content which could cause an unexpected interaction, e.g. hydrogen embrittlement. Besides the pressure build-up the radiolysis of water generates hydrogen and oxygen, which can be highly flammable respectively explosive. The gas generation caused by vaporisation and radiolysis must be taken into account during the design and the safety assessment of a package. Pressure build-up, a changed thermal behavior and content chemistry, and especially the risk of accumulation of combustible gases exceeding the limiting concentration for flammability has to be considered in the safety assessment. Approaches to ensure the transportability of stored packages due to radiolysis will be discussed.
Thermal test driven pressure build-up inside type-B packages containing wet radioactive waste
(2013)
In recent years several German approval procedures for ductile cast iron transport containers containing wet intermediate level waste were conducted. BAM, as one of the German competent authorities, was involved in the complex design assessment work with this specific issue. Thermal analysis is one part of the authority assessment work done by BAM in Germany. The radioactive contents of package designs which were not dried, only drained, consist of saturated ion exchange resin and a small amount of free water. Compared to the safety assessment of packages with dry content, attention must be paid to some more specific points. The most interesting point, however, is the pressure build-up inside the package due to vaporization. This could be caused by radiolysis of the liquid and must be taken into account for the storage period. The inner pressure of the package leads to mechanical loads to the package body, the lid and the lid bolts. Thus, the pressure is the driving force on the gasket system regarding the activity release and a possible loss of tightness. The paper deals primarily with the pressure build-up inside the package caused by the transport regulatory thermal test (30 min at 800 °C) as part of the cumulative test scenario under accident conditions of transport. The pressure build-up is estimated by calculation in a very conservative way regarding conduction and heat radiation. Furthermore the paper discusses a conservative approach for the estimation of the resulting pressure depending on the percentage of water inside the cask. To get trustworthy results without an exact specification of the content, experimental fire tests should be conducted. However, this paper shows the difficulties of assessing casks containing wet content. From the authority assessment point of view, drying of the content could be an effective way to avoid the above described pressure build-up and the associated difficulties for the safety assessment.
In Germany, the mechanical and thermal safety assessment of approved packages for the transport of RAM is carried out by BAM as the competent authority according to the International Atomic Energy Agency regulations. BAM was involved in several approval procedures with ductile cast iron containers containing wet intermediate level waste. These contents, which are not dried, only drained, consist of saturated ion exchange resin and a small amount of free water. Compared to the safety assessment of packages with dry content, attention must be paid to some more specific points. The physical and chemical compatibility of the content itself and of the content with materials of the package must be shown. From the mechanical resistance point of view, the package has to withstand the forces resulting from the freezing liquid. The most interesting point, however, is the pressure build-up inside the package due to vapourisation. This could be caused by radiolysis of the liquid and must be taken into account for the storage period. The paper deals primarily with the pressure build-up inside the package caused by the regulatory thermal test (30 min at 800°C) as part of the cumulative test scenario under accident conditions of transport. To determine the pressure, the temperature distribution in the content must be calculated for the whole period from the beginning of the thermal test until cooling down. In this case, calculating the temperature distribution requires, besides the consideration of conduction and heat radiation, consideration of evaporation and condensation including the associated processes of transport.