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A testing rig for the measurement of the dynamic loads on the rails due to cargo sloshing,has been proposedin this paper. The system represents a scale-down approach that simulates astraightening maneuver of the railway car after negotiating a turn. As part of the experimental effort, a mathematical model was developed that, oncevalidated, will provide more insights about the potential effect of many other cardesign factors, on the level of stress developed in the raildue to the sloshing cargo.A fundamental output from the testing, will be the objective comparison between the railloads due toa sloshing and a non-sloshing cargo, together with a validated model that wouldallow parametric studies in relation withthe potential effect,of several track and carproperties,on the magnitude of the sloshing forces on the rail.
Nanocomposites of a charring polymer (like polyurethane foam) filled with aluminum phosphinate (AlPi) with or without melamine cyanurate (MelCy) have been prepared by microwave processing and their thermal stability and fire behavior have been studied. Results on the interaction between flame retardants and layered silicates were provided as well as detailed investigation of the char strength, which has been carried out using a suitably developed method based on dynamic-mechanic analysis.
Generally, the thermo-oxidative stability in presence of layered silicates was higher than the counterparts even if an additive rather than synergic effect took place; however, in some cases the interaction between clays and phosphinate led to a significant decrease of weight residue. In nitrogen the residue amounts were about the same but a higher amount of phosphorus was retained in the solid phase in presence of clays. Cone calorimeter results showed that the use of phosphinates led to a decrease of the PHRR; further addition of clays did not reduce the PHRR owing to the worse quality of char layer as demonstrated by the char strength test. However, it has been shown that the partial substitution of aluminum phosphinate with melamine cyanurate gave improved results: the AlPi–MelCy filled foams showed similar pHRR and THE but lower TSR and higher char strength than AlPi filled foams. It was also confirmed that phosphinate acted by flame inhibition but its action was depressed by the use of nanoclays owing to their interaction.
Interaction forces between all objects are either of repulsive or attractive nature. Concerning attractive interactions, the determination of dispersion forces are of special interest since they appear in all colloidal systems and have a crucial influence on the properties and processes in these systems. One possibility to link theory and experiment is the description of the London–Van der Waals forces in terms of the Hamaker constant, which leads to the challenging problem of calculating the van der Waals interaction energies between colloidal particles. Hence, the determination of a Hamaker constant for a given material is needed when interfacial phenomena such as adhesion are discussed in terms of the total potential energy between particles and substrates. In this work, the asymmetrical flow field-flow fractionation (AF-FFF) in combination with a Newton algorithm based iteration process was used for the determination of Hamaker constants of different nanoparticles in toluene.
A method is presented which allows to calculate the wave-field in a homogeneous or layered soil in case of a dynamic interior load. The wave propagation along the surface, the distribution of the response over the depth, the horizontal propagation at different depths and the vertical downward propagation are shown and compared with the simpler surface solution of the half-space and the interior solution of the full-space. The complete wave-field (Green's function) is applied to the dynamic behaviour of piles and pile groups by use of a boundary element formulation. The stiffness, damping and – typically for piles – mass of different groups of piles are presented. Different group effects occur for lines, circles, grids, parallels and crosses of piles, which can be regarded as oscillations around average values. Moreover, the piles and pile groups behave almost like a damper for most of the frequencies. A building on a pile group that is excited by ground vibration due to surface or interior loads shows a reduction of the wave-field due to kinematic and inertial soil–building interaction effects. The results presented lead to simplified descriptions of the wave-field due to interior loads and of the soil–pile–building interaction which can be used for the prediction of technically induced vibration.