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Organisationseinheit der BAM
Climate and air quality are of fundamental interest worldwide.
Gas metrology provides profound solutions to measurement tasks on climate and air quality, e.g., when greenhouse gases or pollutants are to be quantified.
Metrological capabilities are demonstrated through participation in the framework of the CIPM Mutual Recognition Arrangement (CIPM MRA).
In Germany, this is covered by three institutes: Bundesanstalt für Materialforschung und -prüfung (BAM), Physikalisch-Technische Bundesanstalt (PTB), and Umweltbundesamt (UBA).
Together, the three laboratories realize the unit mole by means of the national gas standards and offer services to their customers that are backed-up by internationally accepted calibration and measurement capabilities (CMCs).
Flammable gases and vapors
(2013)
ULLMANN'S Encyclopedia of Industrial Chemistry is the benchmark reference in chemistry and chemical and life science engineering, covering inorganic and organic chemicals, advanced materials, pharmaceuticals, polymers and plastics, metals and alloys, biotechnology and biotechnological products, food chemistry, process engineering and unit operations, analytical methods, environmental protection, and much more.
In Gasphasen aus Ethylenoxid (EO) und Propylenoxid (PO), die bei technischen Alkoxylierungsreaktionen vorkommen, können auch ohne den Zutritt von Luft Zerfallsreaktionen stattfinden, die explosionsartig mit einer vielfachen Temperatur- und Drucksteigerung verlaufen. Zur Abschätzung der Auswirkungen solcher Explosionen wurden die Explosionsdrücke und die zeitlichen Druckanstiege von reinem EO und EO/PO-Gemischen bei Temperaturen von 100°C bis 200°C und Drücken von 1 - 10 bar in einem 3-dm³-Behälter und punktuell in einem 100-dm³-Behälter experimentell bestimmt.
Analysis of natural gas by gas chromatography Reduction of correlated uncertainties by normalisation
(2004)
The results of gas chromatographic analysis of natural gas mixtures reveal strong correlations (Pearson correlation coefficient of >0.96) between the uncertainty of each component and variations in the ambient pressure. Although correction for ambient pressure variations can reduce this variability, normalisation of the results of each analysis using the assumption that the sum of all component amount fractions is unity provides significantly greater reductions in the uncertainty of each measured component. We show that the uncertainty in normalised components can be estimated approximately using the correlation coefficient as a measure of the correlation present in the measurements, or exactly using a full calculation of the variance/covariance (V/C) structure of the data.