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Contamination of natural bodies of water with oil and lubricants (or generally, hydrocarbon derivatives such as petrol, fuel and others) is a commonly found phenomenon around the world due to the extensive production, transfer and use of fossil fuels. The timely identification of these contaminants is of utmost importance, since they directly affect water quality and represent a risk for wildlife and human health even in trace amounts.
In this work, we develop a simple system for the on-field detection of total petroleum hydrocarbons (TPH) in water and soil, the "Spectrocube". The test is based on the measurement of the fluorescence signal emitted by the molecular rotor 4-DNS-OH dye. This dye is embedded in a hydrophobic polymeric matrix (PVDF), avoiding interactions of water with the dye and providing a robust support for use in test-strip fashion. The test-strip’s fluorescence intensity increases linearly at low concentrations of TPH, reaching a saturation value at higher concentrations.
For excitation and evaluation of the test-strip fluorescence, a simple miniature optical system was designed. The system works semi-quantitatively as solvent-free TPH detection kit, as well as quantitatively when using a simple cyclopentane extraction step. To simplify the fluorescence read-out, the device is coupled to a tablet computer via Bluetooth, running a self-programmed software ("app").
Small-arm shooting ranges often receive a significant input of lead (Pb), copper (Cu) and antimony (Sb) from ammunition. The goal of the present study was to investigate the mobility, distribution and speciation of Pb and Sb pollution under field conditions in both untreated and sorbent-amended shooting range soil. Elevated Sb (19–349 μg L⁻¹) and Pb (7–1495 μg Pb L⁻¹) concentrations in the porewater of untreated soil over the four-year test period indicated a long-term Sb and Pb source to the adjacent environment in the absence of remedial measures. Mixing ferric oxyhydroxide powder (CFH-12) (2%) together with limestone (1%) into the soil resulted in an average decrease of Sb and Pb porewater concentrations of 66% and 97%, respectively. A similar reduction was achieved by adding 2% zerovalent iron (Fe°) to the soil. The remediation effect was stable over the four-year experimental period indicating no remobilization. Water- and 1 M NH₄NO₃-extractable levels of Sb and Pb in field soil samples indicated significant immobilization by both treatments (89–90% for Sb and 89–99% for Pb). Results from sequential extraction analysis indicate fixation of Sb and Pb in less accessible fractions like amorphous iron oxides or even more crystalline and residual mineral phases, respectively. This work shows that amendment with Fe-based sorbents can be an effective method to reduce the mobility of metals both in cationic and anionic form in polluted shooting range soil.
Background: Biocidal products can be sources of active substances in surface waters caused by weathering of treated articles. Marketing and use of biocidal products can be limited according to the European Biocidal Products Regulation if unacceptable risks to the environment are expected. Leaching of active substances from treated articles was observed in field experiments to obtain information on leaching processes and investigate the suitability of a proposed test method.
Results: Leaching under weathering conditions proceeds discontinuously and tends to decrease with duration of exposure. It mainly depends on the availability of water, but is also controlled by transport processes within the materials and stability of the observed substances. Runoff amount proved to be a suitable basis to compare results from different experiments. Concentrations of substances are higher in runoff collected from vertical surfaces compared to horizontal ones, whereas the leached amounts per surface area are higher from horizontal surfaces. Gaps in mass balances indicate that additional processes such as degradation and evaporation may be relevant to the fate of active substances in treated articles. Leached amounts of substances were considerably higher when the materials were exposed to intermittent water contact under laboratory conditions as compared to weathering of vertically exposed surfaces.
Conclusions: Experiences from the field experiments were used to define parameters of a procedure that is now provided to fulfil requirements of the Biocidal Products Regulation. The experiments confirmed that the amount of water which is in contact with exposed surfaces is the crucial parameter determining leaching of substances.
Offshore-Pfähle in Mehrpfahlgründungsstrukturen wie Jacket-Gründungen müssen nach der Rammung überwiegend zyklisch axialen Belastungen widerstehen. Die Abmessungen der Pfähle werden sowohl von der inneren Tragfähigkeit und dem Ermüdungsverhalten des Stahlquerschnittes als auch von der äußeren Tragfähigkeit und der Pfahl-Boden-Interaktion bestimmt. Aufgrund der großen Zahl von Pfahlgründungen, die für aktuelle und zukünftige Windparkprojekte benötigt werden, besteht ein dringender Bedarf, die Dimensionierung und die damit verbundenen Kosten des Einzelpfahles zu optimieren. Bezüglich der Pfahltragfähigkeit sind wichtige aktuelle Forschungsthemen eine mögliche Traglaststeigerung durch Anwachsen und die geeignete Abschätzung der zyklischen Degradation. Zur Untersuchung beider Effekte wurde eine großmaßstäbliche Versuchsanlage auf dem Testgelände BAM TTS in Horstwalde nahe Berlin errichtet. Auf diesem Versuchsfeld können große Stahlrohrammpfähle zyklisch druck- und zugbelastet werden. Zudem kann die Untersuchung von Alterungseffekten durch zeitlichen Versatz zwischen den Messkampagnen untersucht werden. Erste Ergebnisse zeigen einen Anstieg der Pfahltragfähigkeit bis zu ca. 60 % nach einer Standzeit von ca. 18 Monaten. Für die Degradation der Tragfähigkeit der zyklisch belasteten Pfähle zeigen die ersten vorläufigen Ergebnisse ein zum Teil unerwartetes Verhalten. Zusätzliche Untersuchungen werden derzeit zur weiteren Abklärung durchgeführt.