Electron microscopy investigation of the structure of a compact extruded from nanopowder of nickel
(2007)
Porous ceramic diesel particulate filters (DPFs) are extruded products that possess macroscopic anisotropic mechanical and thermal properties. This anisotropy is caused by both morphologic features (mostly the orientation of porosity) and crystallographic texture. We systematically studied those two aspects in a cordierite and two aluminum titanate (AT) ceramic materials of different porosity using mercury porosimetry, gas adsorption, electron microscopy, X-ray diffraction, and X-ray refraction radiography. We found that a lower porosity in AT content implies a larger isotropy of both the crystal texture and the porous space orientation. We also found that, analogous to cordierite, AT crystallites do align with their axis of negative thermal expansion along the extrusion direction. However, unlike what found for cordierite, the aluminium titanate crystallite form is such that a more pronounced (0 0 2) texture along the extrusion direction implies porosity aligned perpendicular to it.
Porous ceramic diesel particulate filters (DPFs) are extruded products that possess macroscopic anisotropic mechanical and thermal properties. This anisotropy is caused by both morphological features (mostly the orientation of porosity) and crystallographic texture. We systematically studied those two aspects in two aluminum titanate ceramic materials of different porosity using mercury porosimetry, gas adsorption, electron microscopy, X-ray diffraction, and X-ray refraction radiography. We found that a lower porosity content implies a larger isotropy of both the crystal texture and the porosity orientation. We also found that, analogous to cordierite, crystallites do align with their axis of negative thermal expansion along the extrusion direction. However, unlike what found for cordierite, the aluminium titanate crystallite form is such that a more pronounced (0 0 2) texture along the extrusion direction implies porosity aligned perpendicular to it.
Functionalized graphene nanosheets TRGO and MLG 250, prepared from thermally reduced graphite oxide, represent attractive carbon additives for improving the performance of flame retardant polypropylene (PP-FR). The influence of carbon nanofiller type and content on morphology, thermal, mechanical, and electrical properties as well as the fire behavior of melt-extruded PP-FR is investigated. In contrast to conventional nano- and micron-sized carbon fillers such as expanded graphite (EG 40), nano-scaled carbon black (CB), and multiwall carbon nanotubes (CNT), only TRGO and MLG 250 afford uniform dispersion combined with simultaneously improved stiffness (+80%), electrical conductivity (3 × 10-5 S · cm-1) and enhanced flame retardancy of PP-FR, as expressed by lower peak heat release rate (-76%).
During hot extrusion of aluminium alloys, extrusion dies experience cyclic temperature changes as well as multiaxial loadings. To improve the service life of the dies, cleaner and high hot strength materials are designed as well as an optimised process control is performed. For the improvement of the process guiding and a comparison of lifetime behaviour of different hot work tool steels, modelling and simulation are appropriate means. The extrusion process has been simulated using the FE-program Deform to find the stress and temperature history at the inner diameter of the liner, i.e. the boundary conditions for the subsequent cyclic simulation of the container during service. Inelastic constitutive equations have been implemented into Abaqus Standard to describe strain hardening and time recovery effects. They include the Norton viscoplastic flow rule, thermo-mechanical isotropic hardening and two non-linear kinematic hardening laws. A damage-rate model predicts failure and thus the lifetime of the container. The procedure for the identification of material parameters for both the constitutive and the damage model is described in detail for the hot work tool steel Böhler W400 VMR (EN 1.2343).
During aluminium extrusion, the die experience cyclic thermo-mechanical loads that can lead to materials degradation and failure. For a process optimization and a comparison of different hot work tool steels, the finite element method is an appropriate means. Local inelastic strains result from the interaction of the applied temperature and stress loading and can be computed by suitable inelastic constitutive equations. Stress amplitudes and dwell times during extrusion result in creep-fatigue damage. A lifetime consumption model sums increments of a damage variable over time and defines materials failure as the accumulation of the resulting damage variable to a critical value. The procedure for the identification of the material parameters for both the constitutive and the damage model is described in detail, including the material parameters for the description of time-effects, and applied to the hot work tool steel Böhler W300 ISOBLOC (EN 1.2343). The lifetime consumption for two different hot work tool steels is compared on the basis of an example in aluminium extrusion.