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Biocides are commonly applied to construction materials such as facade renders and paints in order to protect them from microbial spoilage. These renders and paints are exposed to weathering conditions, e.g., sunlight and rain. Pigments are interacting intensively with the spectrum of the incoming light; thus, an effect of paint pigments on phototransformation rates and reaction pathways of the biocides is hypothesized.
In this study, the phototransformation of four commonly used biocides (carbendazim, diuron, octylisothiazolinone (OIT) and terbutryn) in four different paint formulations differing solely in pigments (red and black iron oxides, white titanium dioxide, and one pigment-free formulation) were investigated. Paints surfaces were irradiated under controlled conditions. The results show that biocides degrade most rapidly in the pigment-free formulation. The degradation in the pigment-free formulation followed a first-order kinetic model with the respective photolysis rate constants: kp,Diuron=0.0090 h−1, kp,OIT=0.1205 h−1, kp,Terbutryn=0.0079 h−1.
Carbendazim concentrations did not change significantly. The degradation was considerably lower in the pigment-containing paints. The determination of several phototransformation products of terbutryn and octylisothiazolinone showed different transformation product ratios dependent on the pigment. Consequently, pigments not only reflect the incoming light, but also interact with the biocide photodegradation.
This paper studies the spatial and temporal spectral absorption of reflector signals of a 1.5 GHz ground penetrating radar (GPR) during a drying process of a brickwall from initial wet to later dry state. The non-stationary GPR signals were processed with short time-Fourier transform (STFT) and wavelet transform (WT) in a novel spatial-timefrequency (STF) domain. Spatial distribution of peak frequency at the direct wave (DW) across the antenna and a backwall reflection was studied to characterize the mechanism of spectral absorption of GPR wave. Results from WT were shown to be more preferred to those from STFT because the WT offers multiple resolutions to cope with both low and high frequency components in GPR wavelets but STFT does not. In addition to the traditional GPR signal interpretation in time-domain and our previous works on time–frequency domain, the analysis method operated in the STF domain provides another possibility of material characterization by GPR in large and field scale.
Using ground penetrating radar and time-frequency analysis to characterize construction materials
(2011)
For decades, applications of nondestructive evaluation-civil engineering (NDE-CE) focus on object identifications (such as steel bars, tendon ducts and backwall reflections) in infrastructures. Because of the advantage of efficient visualization of internal structure, utilization of these methods can probably be extended to material characterization (MC) of aging and adversely exposed infrastructures. However, two factors yield a big gap between NDE and MC. First, for the ease of visualization, the primary focus of NDE-signal processing is object identification, which usually alters the originality of the signal. Second, there is lack of relationship and inverse models bridging the NDE-derived and conventional material properties compared to other disciplines of science, such as geophysics. These disadvantages make laboratory and field-scale NDE-MC still a far-reaching holy grail and is possibly the greatest hurdle to be regularly adopted in CE structures. This paper attempts to address this gap from object identification to MC using ground penetrating radar (GPR) as one of the most frequently used NDE-CE methods, and signal processing with joint timefrequency domain (JTFA) analysis. Three examples of material property characterization regarding the individual effects of steel bar corrosion in concrete, hydration and moisture content distribution of construction materials are given.
The method requires two parallel boreholes in the specimen in which two microwave antennae can be moved. The moisture content in the material can be calculated from the microwave intensity transmitted between the two boreholes. Moisture profiles along the boreholes can be obtained by moving the antennae in steps along the length of the boreholes and taking measurements at each step.
The microwave frequencies used in the laboratory measurements ranged from 8 to 16.5 GHz in steps of 0.5 GHz. The diameters of the antennae were between 7 and 9 mm, and of the boreholes between 8 and 12 mm. The microwave method produced measurement uncertainties between 0 and 2% by volume for all the materials studied in this report.