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Slags from the production of high-alloyed steel contain both chemically bound chromium (mainly as Cr2O3) in the mineral fraction and elemental chromium in the metallic remainders. Thermochemical post treatment of the slag in an electric arc furnace under reducing conditions enables the nearly complete recovery of the total amount of chromium in form of a metallic alloy. The best results were achieved by resistance melting (submerged electrodes) with addition of a reducing agent into the melt. The efficiencies of the reducing agents carbon, aluminium, silicon (as ferrosilicon) and silicon carbide were investigated and compared. As aluminium is the strongest reducing agent, it is less selective and reduces much more SiO2 than Cr2O3. While SiC shows only low reactivity because of its high thermal resistance, carbon and silicon had the highest reducing potentials: More than 97% of the chemically bound chromium can be recovered by application of these reducing agents. Due to the high temperature required for the reduction of the chromium compounds, the reduction of SiO2 as an undesired side reaction cannot be avoided. However, compared with mechanical procedures that are limited to the recovery of the metallic remainders, the total chromium recovery can be significantly increased by the described reductive melting procedure.
Amelogenin nanoparticles in suspension: Deviations from spherical shape and pH-dependent aggregation
(2010)
It is well-known that amelogenin self-assembles to form nanoparticles, usually referred to as amelogenin nanospheres, despite the fact that not much is known about their actual shape in solution. In the current paper, we combine SAXS and DLS to study the three-dimensional shape of the recombinant amelogenins rP172 and rM179. Our results show for the first time that amelogenins build oblate nanoparticles in suspension using experimental approaches that do not require the proteins to be in contact with a support material surface. The SAXS studies give evidence for the existence of isolated amelogenin nano-oblates with aspect ratios in the range of 0.45-0.5 at pH values higher than pH 7.2 and show an aggregation of these nano-oblates at lower pH values. The role of the observed oblate shape in the formation of chain-like structures at physiological conditions is discussed as a key factor in the biomineralization of dental enamel.
The impact-echo method has been successfully applied to identify defects inside concrete. In addition, to detect ungrouted tendon ducts in a large concrete slab, a scanning impact-echo technique is developed. However, since resonant frequencies in the spectrum responsible for the travel paths via defects are only taken into account, the method could lead to erroneous results due to complicated spectra obtained in the tests. Consequently, Stack Imaging of spectral amplitudes Based on Impact-Echo (SIBIE) procedure has been developed to improve the data interpretation. Conventionally, SIBIE is applied to a single measurement data and a point information of defects is obtained at the area, where the impact test is performed. In this study, SIBIE is applied to scanning impact-echo data. Locations of ungrouted tendon ducts embedded in a large concrete specimen are investigated. In order to visualize the whole cross-section tested, the SIBIE analysis is modified, introducing an elliptical integration mode. It is demonstrated that ungrouted tendon ducts are successfully located by the modified SIBIE analysis, whereas results of the conventional B-scan analysis are not so good as the modified SIBIE analysis.
The development of dendritic metal ion carrier systems for use in a biological environment is a challenging task as the carrier system must possess multiple features (e.g. a protective shell for metal decomplexation, targeting functions, metal-intradendrimer complexes, etc.) to substitute for the function of metal proteins in processes such as copper metabolism. Thus, Cu(II) complexation by a series of poly(propyleneimine) glycodendrimers ranging up to the fifth generation that have either a dense maltose or maltotriose shell was investigated by UV/Vis spectroscopy and electron paramagnetic resonance (EPR). As a necessary step towards potential biological application, we elucidated the complexation capacity, location of the Cu(II)-dendrimer complexes and the Cu(II) coordination sphere in the dendritic environment. A generation-dependent Cu(II) complexation was found. Furthermore, analysis of the EPR spectra revealed that internal and external Cu(II) coordination and the symmetry (axial and rhombic) of the generated complexes depend on the oligosaccharide shell, dendrimer generation and the relative concentrations of Cu(II) and the dendrimers. Both axial and rhombic symmetries are generation dependent, but also distort with increasing generation number. External coordination of Cu(II) is supported by sugar groups and water molecules. Finally, a third-generation dendrimer with a maltose shell was used to explore the general complexation behaviour of the dendritic poly(propyleneimine) scaffold towards different metal ions [Cu(II), Ag(I), VO(IV), Ni(II), Eu(III) and UO2(VI)].
A method is presented which allows to calculate the wave-field in a homogeneous or layered soil in case of a dynamic interior load. The wave propagation along the surface, the distribution of the response over the depth, the horizontal propagation at different depths and the vertical downward propagation are shown and compared with the simpler surface solution of the half-space and the interior solution of the full-space. The complete wave-field (Green's function) is applied to the dynamic behaviour of piles and pile groups by use of a boundary element formulation. The stiffness, damping and – typically for piles – mass of different groups of piles are presented. Different group effects occur for lines, circles, grids, parallels and crosses of piles, which can be regarded as oscillations around average values. Moreover, the piles and pile groups behave almost like a damper for most of the frequencies. A building on a pile group that is excited by ground vibration due to surface or interior loads shows a reduction of the wave-field due to kinematic and inertial soil–building interaction effects. The results presented lead to simplified descriptions of the wave-field due to interior loads and of the soil–pile–building interaction which can be used for the prediction of technically induced vibration.
Transfer admittance spectra of technically induced surface wave fields are analyzed in theory and experiments. Theoretical admittance spectra of layered soils are obtained by integration in wavenumber domain and compared with experimental admittances due to hammer or vibrator excitation. The admittance spectra are strongly influenced by the layering and damping of the soil. Deep stiff-soil layers yield a low-frequency cutoff, whereas a strong damping yields a high-frequency cutoff. A sharp cutoff in a narrow frequency band, which is measured at some sites, can be explained by a damping that increases with frequency, such as viscous material or scattering damping.
Excitation force spectra are necessary for a realistic prediction of railway-induced ground vibration. The excitation forces cause the ground vibration and they are themselves a result of irregularities passed by the train. The methods of the related analyses - the wavenumber integration for the wave propagation in homogeneous or layered soils, the combined finite-element boundary-element method for the vehicle-track-soil interaction - have already been presented and are the base for the advanced topic of this contribution. This contribution determines excitation force spectra of railway traffic by two completely different methods. The forward analysis starts with vehicle, track and soil irregularities, which are taken from literature and axle-box measurements, calculates the vehicle-track interaction and gets theoretical force spectra as the result. The second method is a backward analysis from the measured ground vibration of railway traffic. A calculated or measured transfer function of the soil is used to determine the excitation force spectrum of the train. A number of measurements of different soils and different trains with different speeds are analysed in that way. Forward and backward analysis yield the same approximate force spectra with values around 1 kN for each axle and third of octave.
The attenuation of the amplitudes with distance of technically induced surface wave fields is analyzed in theory and experiments. Experimental results of technically induced ground vibration are presented and collected from literature, which show a power-low attenuation A ~ r–q of amplitudes A with distance r and exponents q > 0.5 higher than for elastic surface waves. Additional attenuation effects are analyzed theoretically. The most important effect is due to the material or scattering damping. Each frequency component is attenuated exponentially as A ~ exp(–kr), but for a broadband excitation, the sum of the exponential laws yields a power law with a higher exponent. Some more effects are discussed, for example the dispersion of the Rayleigh wave due to the layering of the soil, which yields a stronger attenuation A ~ r–q–dq, including an additional exponent of dq = 0.5 in case of an impulsive loading.