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Ultraschallunterstützte Zerspanung mit geometrisch bestimmter Schneide schwer spanbarer Werkstoffe
(2023)
Das hybride Fertigungsverfahren der ultraschallunterstützen Zerspanung wird mit geometrisch unbestimmter Schneide wie bspw. dem Schleifen bereits erfolgreich in der Industrie eingesetzt und verspricht auch unter Verwendung von Werkzeugen mit geometrisch bestimmter Schneide vielversprechende Vorteile gegenüber den konventionellen spanenden Fertigungsverfahren. In den letzten Jahren wurden an der BAM positive Ergebnisse beim ultraschallunterstützten Fräsen (USAM) von schwer spanbaren Werkstoffen wie z.B. Ni-/Co-Legierungen oder Eisenaluminid für den Leichtbau erzielt aber auch die Finishbearbeitung von schweißtechnisch generierten Bauteilen (AM) bspw. aus FeNi36 konnte hinsichtlich erreichbarer Werkzeuglebensdauer sowie Oberflächenintegrität zur Verbesserung der Komponentensicherheit beitragen. Die mittels USAM erzeugten Oberflächen erscheinen homogener und weisen weniger Defekte infolge des Materialabtrags auf, was sich ebenfalls in verringerten Rauheitskennwerten abbildet. Durch die geringere thermo-mechanische Belastung der Bauteiloberfläche sind Eigenschaftsdegradationen zusätzlich reduziert. Besonders großes Zukunftspotenzial besitzt das ultraschallunterstütze Fräsen durch die Erzeugung von erwünschten Druckeigenspannungen bis unter die Bauteiloberfläche, was auf die oszillierende Wirkung der Werkzeugschneide - vergleichbar mit einem Strahlprozess - zurückzuführen ist. Druckeigenspannungen tragen maßgeblich zur Risssicherheit hochbelasteter Komponenten bei wie sie bspw. in Turbinen vorzufinden sind und können somit zum Leichtbau und zur Ressourceneffizienz beitragen.
In der Abschlusspräsentation des ZIM-Kooperationsvorhabens "TeWuFeAl" werden die wichtigsten Ergebnisse zusammengefasst dargestellt. Ziel des Projektes war die Entwicklung einer Prozess- und Werkzeugtechnologie für das ultraschallunterstützte Fräsen von im Kokillenguss hergestellter Eisen- und Titan-Aluminid-Bauteilen. Auf Basis einer eigens entwickelten Werkzeugtechnologie und Prozessführung konnten die Belastungen auf das Werkzeug und die Oberfläche von Bauteilen aus dem schwer zerspanbaren Eisenaluminid bei der frästechnischen Bearbeitung signifikant verringert werden. Die Messung der Prozesskräfte und der thermischen Belastung der Werkzeugschneide ermöglicht die Ermittlung geeigneter Zerspanungsparameter für eine maximale Werkzeuglebensdauer. Die Anwendung des ultraschallunterstützten Fräsens (USAM) wirkt sich vorteilhaft auf den Zerspanprozess aus. Neben einer deutlichen verlängerung der Werkzeuglebensdauer, zeigen sich Vorteile in Bezug auf die topographischen, metallurgischen sowie mechanischen Eigenschaften der erzeugten Oberflächenintegrität. Die durch USAM erzeugte homogene Bauteiloberfläche weist eine reduzierte Defektdichte und verringerte Rauheitskennwerte auf. Besonders vielversprechend sind die Ergebnisse der Messungen der Eigenspannungen im Tiefenprofil der Oberfläche. Die Werkzeugoszillation bewirkt eine, vergleichbar zum Strahlprozess, Verdichtung der Oberfläche was in Druckeigenspannungen resultiert. Diese potenziell vorteilhaften Druckeigenspannungen können maßgeblich zur Risssicherheit hochbelasteter Komponenten und somit zum Leichtbau und Ressourceneffizienz beitragen.
Stresses in repair welding of high-strength steels Part 2: Heat Control and Stress Optimization
(2023)
In welding of high-strength steels, e.g., for foundations and erection structures of wind energy plants, unacceptable defects can occasionally be found in the weld area, which should be removed by thermal gouging and subsequent re-welding. High shrinkage restraint of repair welds may lead to crack formation and component failure, particularly in interaction with degraded microstructures and mechanical properties due to repair cycles. This study aims for elaboration of recommendations for repair concepts appropriate to the stresses and materials involved to avoid cold cracking, damage and expensive reworking. In part 1 [1] of this study systematic investigations of influences of shrinkage restraint on residual stresses and cold cracking risk during repair welding of two high-strength steels S500MLO for offshore application and S960QL for mobile crane structures were focussed. In this part 2, the microstructure and residual stresses due to gouging and influences of heat control parameters in repair welding are analysed. A clear reduction in residual stress after gouging can be observed, especially for the specimens with restrained transverse shrinkage. Gouging to a depth of approx. 2/3 of the seam height does not lead to a complete relaxation of the observed reaction forces. Particularly for the higher strength steel S960QL, there are pronounced areas influenced by the gouging process in which a degradation of the microstructure and properties should be assumed. Overall, the repair welds show a significant increase in the width of the weld and HAZ compared to the original weld, especially in the case of S960QL/G89. The repair welds show higher welding-induced stresses than the original welds, especially in the areas of the HAZ and the base metal close to the weld seam. This behaviour can be attributed overall to increased restraint conditions due to the remaining root weld or shorter gouge grooves. In good agreement with earlier investigations, the residual stresses transverse to the weld can be significantly reduced by upwardly limited working or interpass temperatures and the reaction stresses resulting from high restraint conditions can be effectively counteracted. The influence of the heat input on the stress formation is low compared to the interpass temperature for both test materials.
Auf der Grundlage einer speziell entwickelten Werkzeugtechnologie sowie Prozessführung können die Belastungen auf das Werkzeug und die Bauteiloberfläche bei der frästechnischen Bearbeitung von Bauteilen aus dem innovativen jedoch schwer zerspanbaren Eisenaluminid deutlich reduziert werden. Die Messung der Prozesskräfte sowie der thermischen Belastung der Werkzeugschneide ermöglicht die Identifikation geeigneter Zerspanungsparameter hinsichtlich einer maximalen Werkzeuglebensdauer. Die Verwendung des ultraschallunterstützten Fräsens (USAM) besitzt vorteilhafte Einflüsse auf den Zerspanprozess, insbesondere hinsichtlich einer homogenen Bauteiloberfläche. Im Rahmen von Standzeitversuchen erfolgt durch USAM ein gleichmäßiger und im Vergleich zum konventionellen Fräsen (CM) deutlich reduzierter Werkzeugverschleiß. Mit wachsendem Zerspanvolumen verstärkt sich der positive Effekt von USAM und äußert sich in einer deutlichen Reduzierung der Rauheit und Defektdichte auf der Bauteiloberfläche.
We present a prototype of a distributed POF sensing system for strain detection in road construction and civil engineering ready to be used in practical applications. The system is based on a cost-efficient digital incoherent optical frequency domain reflectometry (I-OFDR). In this approach, the strain-induced changes in the Rayleigh backscattering profile along a perfluorinated polymer optical fiber (PF-POF) are determined by measuring the complex transfer function of the sensing fiber using a compact digital data acquisition unit. The digital unit replaces an oversized vector network analyzer (VNA) enabling suitability of the measurement system for out-door use and providing a significant reduction of the total system costs at the same time. The entire sensor con-cept includes the use of geosynthetics with integrated PF-POFs as two-dimensional sensor structures for geotech-nical applications. The robustness and the functionality of the distributed POF I-OFDR sensors were proven in the field. The field test involved embedding of two geomats, each with two polymer optical sensor loops, into the embankment of the federal road B 91 in a section near Leipzig. The measurements conducted after the sensor-based geomats had been installed confirmed both the potential of such smart geosynthetics and the functionali-ty of the digital I-OFDR prototype.
Kunststoffdichtungsbahnen (KDB) aus PE-HD (Polyethylen hoher Dichte) werden häufig zur Abdichtung von Bauwerken in der Geotechnik verwendet. Diese Produkte werden aus einem Kunststoff mit relativ komplexer Zusammensetzung hergestellt. Um eine Aussage über die Haltbarkeit von KDB aus PE-HD treffen zu können, muss das Materialverhalten berücksichtigt werden. In diesem Zusammenhang sind die wichtigsten Aspekte der Dauerhaftigkeit die Spannungsrissbeständigkeit und die Beständigkeit gegen Oxidation. Verschiedene PE-Sorten weisen eine unterschiedliche Spannungsrissbeständigkeit auf. Um dieser Eigenschaft von PE-HD zu begegnen, werden nur KDB aus sehr hochwertigen Rohstoffen zugelassen. Auf der anderen Seite werden hohe Anforderungen an die umgebenden Schichten, wie Auflager und Schutzschicht gestellt, um möglichst geringe Spannungen zu erzeugen und damit Dehnungen die Dehnungen der KDB gering zu halten. Bestimmte Medien, die bei den betreffenden Prüfungen verwendet werden, dürfen nicht mehr in der EU in Verkehr gebracht werden. Im Folgenden sollen die Zusammenhänge in Kürze dargestellt werden.
Darüber hinaus sollen Diskussionen und Änderungen im Zusammenhang mit der Zulassungsrichtlinie für KDB vorgestellt werden. Der aktuelle Stand der Diskussion im Zusammenhang mit den verwendeten Tensiden in Bezug auf die Spannungsrissprüfung und weiterer Prüfungen wird aufgezeigt. Änderungen der Fremdprüfung von sogenannten Sandschutzmatten, des Standards zur Qualitätsüberwachung (SQÜ) von Kunststoff Dränelementen (KDE) und der Anpassung der Formulierungen zum Überbau der in Abdichtungen verwendeten Produkte werden in Kürze aufgezeigt.
Kunststoffdichtungsbahnen (KDB) aus PE-HD (Polyethylen hoher Dichte) werden häufig zur Abdichtung von Bauwerken in der Geotechnik verwendet. Diese Produkte werden aus einem Kunststoff mit relativ komplexer Zusammensetzung hergestellt. Um eine Aussage über die Haltbarkeit von KDB aus PE-HD treffen zu können, muss das Materialverhalten berücksichtigt werden. In diesem Zusammenhang sind die wichtigsten Aspekte der Dauerhaftigkeit die Spannungsrissbeständigkeit und die Beständigkeit gegen Oxidation. Verschiedene PE-Sorten weisen eine unterschiedliche Spannungsrissbeständigkeit auf. Um dieser Eigenschaft von PE-HD zu begegnen, werden nur KDB aus sehr hochwertigen Rohstoffen zugelassen. Auf der anderen Seite werden hohe Anforderungen an die umgebenden Schichten, wie Auflager und Schutzschicht gestellt, um möglichst geringe Spannungen zu erzeugen und damit Dehnungen die Dehnungen der KDB gering zu halten. Bestimmte Medien, die bei den betreffenden Prüfungen verwendet werden, dürfen nicht mehr in der EU in Verkehr gebracht werden. Im Folgenden sollen die Zusammenhänge in Kürze dargestellt werden. Darüber hinaus sollen Diskussionen und Änderungen der Zulassungsrichtlinie für Schutzschichten im und durch den Fachbeirat vorgestellt werden.
Through experimental observation and auxiliary numerical simulation, this investigation studies the different types of grain refinement of 5754 aluminum alloy laser beam welding by applying a transverse oscillating magnetic field. Scanning electron microscope results have proved that the application of a magnetic field can reduce the average crystal branch width and increase its number. The interaction between the induced eddy current generated by the Seebeck effect and the applied external magnetic field produces a Lorentz force, which is important for the increase in the number of crystal branches. Based on the theory of dendrite fragmentation and the magnetic field-induced branches increment, the grain size reduction caused by the magnetic field is studied. Furthermore, the effects of the magnetic field are ana lyzed by combining a phase field method model and simulations of nucleation and grain growth. The grain distribution and average grain size after welding verify the reliability of the model. In addition, the introduction of a magnetic field can increase the number of periodic three-dimensional solidification patterns. In the intersection of two periods of solidification patterns, the metal can be re-melted and then re-solidified, which prevents the grains, that have been solidified and formed previously, from further growth and generates some small cel lular grains in the new fusion line. The magnetic field increases the building frequency of these solidification structures and thus promotes this kind of grain refinement.
The effect of the oscillating metal vapor plume on the keyhole and molten pool behavior during the laser beam welding of AlMg3 aluminum alloys is investigated by experimental and numerical methods. The real-time height of the metal vapor plume is measured by high-speed camera observation. The obtained experimental results are used to evaluate the additional heating source and laser beam attenuation caused by the scattering and absorption based on the Beer–Lambert theory. Furthermore, the dynamic behavior of the metal vapor plume is incorporated into a 3D transient heat transfer and fluid flow model, coupled with the ray tracing method, for the laser beam welding of the AlMg3 alloy. It is found that additional heating resulting from the scattered and absorbed laser beam energy by the metal vapor plume significantly expands the shape of the molten pool on the top region. Moreover, the oscillating metal vapor plume caused the fluctuation of the high-temperature region in the molten pool. The probability of keyhole collapse at the bottom increases 17% due to the oscillating laser power induced by the laser beam attenuation. The internal interplay between the metal vapor plume, molten pool shape, and keyhole collapse is obtained. The developed model has been validated by experiments, which shows a good agreement.
Magnetohydrodynamic technology is increasingly recognized as a promising approach for enhancing the quality of deep penetration laser beam welding. This study employs experimental and numerical methods to investigate the effects of an auxiliary oscillating magnetic field on reducing porosity in the laser beam welding of 5754 aluminum alloy. The experimental results clearly demonstrate a significant reduction in the porosity ratio, thereby validating the efficacy of applying MHD technology in mitigating porosity during the laser beam welding process. In addition, a transient 3D multi-physical model has been developed, integrating the magnetohydrodynamic and metal vapor plume, to gain a more comprehensive understanding of the porosity suppression mechanism. The introduction of an oscillating magnetic field generates a time-averaged downward Lorentz force. This Lorentz force, in turn, induces an electromagnetic expulsive force, which effectively increases the upward escape velocity of bubbles in the molten pool. Furthermore, the molten pool shape is significantly enlarged, which further facilitate the escape of bubbles. The simulation results agree well with the experimental results.
The high-throughput synthesis and characterization of potential material combinations plays an important role in accelerating the development of new materials. Diffusion controlled synthesis of gradient alloys is widely used to create phase diagrams, and it is also one of the most effective combinatorial approaches for rapid realization of potential material combinations.
This study focuses on the synthesis and investigation of the quaternary multi-principle-element alloy (MPEA) FeNiCrMn by means of diffusion multiples, the correlation of their microstructural and chemical characterization data with their application relevant properties like local mechanical and corrosion properties. A diffusion system was set up by combining an equimolar ternary alloy (FeNiCr) with a single diffusing metallic component (Mn) with the highest interdiffusion coefficient. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) were used to collect microstructural and compositional information which were correlated to local mechanical properties studied with nanoindentation. Local corrosion properties were investigated by means of Atomic Force Microscopy (AFM) and Scanning Electrochemical Microscopy (SECM). We have observed that a >50 μm deep homogeneous diffusion zone was formed the thickness of which scales with the duration of the thermal treatment. Beyond the Mn-concentration gradient in the FeNiCr matrix, a distinct Cr-rich secondary phase, characterized by high hardness and elastic modulus values appeared. We synthesized MPEAs with selected compositions from the diffusion zone as well as the Cr-rich phase as bulk alloys for electrochemical corrosion studies under different environmental conditions. The presentation will summarize the results of our correlative study on the mechanical properties and corrosion resistance of the quaternary multi-principle-element alloy (MPEA) FeNiCrMn family.
The efficient exploration of novel alloy chemistries is crucial for advancing the development of new materials. Diffusion-controlled synthesis of gradient alloys is an intelligent approach for creating phase diagrams and to effectively identify potential material combinations with tailored properties.
This project focusses on the design of quaternary multi-principle-element alloys (MPEAs) using diffusion couples. Our diffusion system contains an equimolar ternary alloy (FeNiCr) and additional single diffusing elements e.g. Mn and Mo. We determined the optimal temperature ranges for the diffusion thermal treatment by means of ThermoCalc simulations with the aim to form single-phase MPEAs. Microstructure and chemical characterization of the diffusion couples were performed by means of scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). For most alloy couples, the diffusion zone contained a single-phase alloy matrix with diffusion-induced compositional gradient as well as precipitation phases. This heterogeneity makes the diffusion couples interesting materials to investigate local mechanical and corrosion properties. Thus, local corrosion properties were examined using Atomic Force Microscopy (AFM) and Scanning Electrochemical Microscopy (SECM). Nanoindentation was used for the analysis of local mechanical properties.
Based on the results of the local corrosion analysis, we have selected single-phase alloy chemistries along the diffusion zone and reproducibly synthesized these alloys in bulk for detailed corrosion studies by means of potentiodynamic polarization and SECM.
The presentation will briefly summarize our methodology and motivation for using diffusion couples as an efficient tool for exploring phase diagrams of MPEAs in the search for new alloy chemistries and the results of our correlative study on the mechanical and corrosion properties of these materials.
The efficient exploration of novel alloy compositions is crucial for advancing the development of new materials. One widely utilized approach for creating phase diagrams is the use of diffusion-controlled synthesis for gradient alloys. This method is also an effective means for rapidly identifying potential material combinations.
The present study focusses on the exploration of quaternary multi-principle-element alloys (MPEAs) using diffusion multiples. We established a diffusion system by combining an equimolar ternary alloy (FeNiCr) with single diffusing elements Mn and Mo. Using ThermoCalc simulations, we determined suitable temperature ranges where we can expect the formation of single-phase alloys. Depending on the diffusion constants of the selected metals, diffusion times were adjusted to obtain diffusion zones with a depth of greater than 50 μm. Microstructural and compositional information was gathered via scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) and correlated to local mechanical properties evaluated by means of nanoindentation. Local corrosion properties were examined using Atomic Force Microscopy (AFM) and Scanning Electrochemical Microscopy (SECM).
Our results indicate that the ThermoCalc simulations have a good predictive power for crystallographic phases. However, especially with the Mn-FeNiCr system, formation of Cr-rich secondary phases were observed, which led to Cr-depletion and thus to localized corrosion processes in the matrix at the vicinity of the secondary phases. Based on the results of the local electrochemical tests, we have selected single-phase compositions along the diffusion zone and synthesized these alloys in bulk for corrosion studies by means of potentiodynamic polarization and SECM.
The presentation will summarize our methodology using diffusion couples as an
efficient tool for exploring compositional spaces of MPEAs in the search for novel single-phase alloys and the results of our correlative study on the mechanical and corrosion properties of these materials.
Guided wave ultrasonic features in composite overwrapped pressure vessels towards digital twin
(2023)
The digitalization of quality control processes and the underlying data infrastructures for safety relevant components, such as hydrogen pressure vessels, plays a significant role in the transition towards Industry 4.0. In the current safety regulations for hydrogen pressure vessels, there is no established concept for structural health monitoring. The development of a reliable structural health monitoring methodology for monitoring the structural integrity of pressure vessels enables a fast-forward transition from personnel- and costintensive recurring inspections, a.k.a. periodic maintenance, to predictive maintenance. In the work presented; we investigated the application of ultrasonic guided wave propagation to monitor and assess the condition of Type IV composite overwrapped pressure vessel (COPV). A sensor network of fifteen piezo-electric wafers is placed on the carbon fibre reinforced composite cylinder. Five different artificial damage configurations are created by gluing two different weight blocks on three different locations. The database containing measured guided wave data sets is enriched by two different boundary conditions. We utilized an open-source software, openBIS labnotebook, to store and analyse experimental datasets. The guided wave ultrasonic signals were investigated and analysed by using commonly used ultrasonic features (e.g., amplitude, frequency, time of flight) as well as non-traditional time-series features (kurtosis, skewness, variance). The features were used to calculate damage index and the detection performance for the results has been evaluated. The results suggest that both traditional and non-traditional features assume significant importance in artificial damage detection. The future works will additionally involve the impacts of operational conditions, such as periodic pressure variations temperature loadings as well as material degradations.
Inductively coupled plasma mass spectrometry (ICP-MS) emerged as a powerful technique for trace analysis of soil due to its multi-element capability, high sensitivity and low sample consumption. However, despite its success and widespread use, ICP-MS has several persistent drawbacks, such as high argon gas consumption, argon-based polyatomic interferences and the need for complicated RF-power generators. Unlike argon-based ICP, the nitrogen microwave inductively coupled atmospheric pressure mass spectrometry (MICAP-MS) uses nitrogen as plasma gas, which eliminates high operating costs associated with argon-gas consumption as well as the argon-based interferences1. In this work, the applicability of MICAP-MS for elemental analysis in different matrices is investigated. For this purpose, reference soil samples and steel samples are digested with aqua regia and used for analysis. Concentrations of selected elements are determined using MICAP-MS and validated with ICP-MS und certified values. Sensitivities, limits of detection and gas consumption for both methods are compared and discussed in detail. Performance of MICAP-MS under different nitrogen plasma gas concentrations is investigated and compared. Moreover, the performance of MICAP-MS in alloy matrices is investigated and discussed.
In the current study, we investigate an interaction under high-pressure high-temperature of single phase fcc-, hcp- and bcc-structured high-entropy alloys with hydrogen, carbon and nitrogen to obtain high-entropy hydrides, carbides and nitrides. Structural changes in high-entropy alloys upon compression and heating in the presence of these light elements are in the focus of our investigation. An easy route to high-entropy hydrides, carbides and nitrides will open new synthetic horizons in compositionally complex materials. Our study suggests that high-entropy alloys form high- entropy hydrides mainly with a composition close to M:H 1:1 ratio. Hydrides can be obtained under compression with hydrogen as a pressure compression medium or using hydrogen fluid as reactive agent.
Hydrogenated nitrile butadiene rubber (HNBR) elastomer was thermo-oxidatively aged at different temperatures up to 150°C. Fourier transform infrared spectroscopy (FTIR), compression stress relaxation (CSR) and IRHD microhardness were used to characterise the chemo-mechanical changes of HNBR O-rings during thermo-oxidative ageing. FTIR shows the development of carbonyl, methyl and ester groups but the nitrile content was not affected by ageing. The effect of sample geometry during CSR was investigated. CSR data were converted through integrated kinetic laws. The conversion has proven its sensibility to detect heterogeneous ageing. This was confirmed by the IRHD measurements across the section of O-rings. Oxidation profiles were determined by applying the model of Wise et al. to the IRHD experimental results.
Overview of ongoing research and future prospects on polyethylene neutron shielding materials at BAM
(2023)
The extension of the interim storage period of radioactive waste before disposal will cause additional challenges for the nuclear waste management in Germany, so that an extensive knowledge of the long-term performance of casks, including their components and inventories, will be required for future extended storage licenses.
Ultra-high and high molecular weight polyethylenes ((U)HMW-PE) are used for neutron shielding purposes in casks for storage and transport of spent fuel and high-level waste due to their extremely high hydrogen content. During their service life of several decades as cask components, the PE materials are exposed to neutron and gamma radiation from the radioactive inventory of the casks, mechanical assembling stresses and temperature. All these combined effects affect the material properties of such components which in turn may be crucial for some possible accident scenarios.
At the Bundesanstalt für Materialforschung und -prüfung (BAM), the effects of high temperature exposure in combination with subsequent or previous irradiation were investigated with a comprehensive aging program including thermal aging at 125 °C for different aging periods up to 5 years and irradiation with doses ranging from 50 to 600 kGy.
This contribution provides an overview of the ongoing research related to the structural changes of (U)HMW-PE induced by gamma irradiation and high temperature exposure and focuses on current research perspectives at BAM with regard to the prediction of the dynamic behavior of the material during extended interim storage in case of an accident scenario. First results of the coupled effect of temperature, radiation and mechanical loading will be presented. The effect of microstructural changes induced by gamma irradiation and high temperature on the mechanical behavior of (U)HMW-PE will be assessed.
The development of offshore wind turbines (WTGs) presents many challenges in terms of safe operation over extended periods of time. One of these is the corrosive environment towards metallic materials, which can lead to a loss of material thickness and thus to a deterioration of mechanical performances, especially the strength of infrastructures. This can be counteracted by painting and cathodic protection (CP). Much research has already been done in this area about inhibiting the corrosion process. However, gaps exist regarding free corrosion. This plays a greater role especially for time intervals during the installation of the systems and their maintenance, during which often no CP can be operated. This is especially true for areas where painting surfaces is impossible e.g., sediment areas. This problem is exacerbated by the different corrosion rates caused by the different zones (water and sediment), with their different amounts of dissolved oxygen.
This presentation deals with experiments in artificial seawater and sediment. Classical S355J2 steel samples in the form of coupons were fitted with welding wires that carried out the electrical contact to the outer side of the basin. Inside the basins, the specimens are stored in different zones like water and sediment which should simulate the foundation situation of monopiles. The mass loss was determined gravimetrically, elemental currents between specimens in water and sediment were measured and electrochemical investigations were carried out. The influences of the zones, based on different solved oxygen contents, and the rolling skin towards the corrosion behavior of the mild steel samples were determined in this work. Especially the influence of the sediment showed unexpected behavior, determined by electrochemical investigations. These results allow better conclusions to be drawn about the corrosion behavior of low alloy steels in offshore environments used in sediment and seawater, which cannot always be protected.
The prevention of brittle fracture of spent fuel claddings during long-term dry interim storage is based on experimental investigations, numerical analyses and assessment methods for predicting the mechanical behavior and determining limiting conditions. The ring compression test (RCT) is an established experimental method for characterizing cladding material. Test results for various high-burnup pressure water reactor zirconium-based fuel cladding alloys (e.g., ZIRLO®, M5®) are publicly available. To reduce the effort associated with irradiated samples in hot cells, it is helpful to perform studies on unirradiated surrogate cladding material. Based on such experimental data, load-displacement curves were numerically analyzed for selected cladding materials. In the presence of radial hydrides, a sample may suddenly fail by fracture even at small deformations. Noticeable load drops in the RCT occur associated to unstable crack propagation through the radial hydride network. The failure mechanism is quasi-cleavage in the hydrides and micro-void nucleation, growth, and coalescence in the zirconium matrix, with ductile tearing patches connecting neighboring hydrides. The failure process was simulated by cohesive zones controlled by the fracture energy and the cohesive strength. A modeling approach is presented in which the radial hydride morphology is taken into account. Based on the developed fracture mechanics approach with cohesive zone modeling, not only the deformation behavior but also the failure behavior of irradiated as well as unirradiated claddings with radial hydrides under RCT loading conditions can be adequately described.
Task 3 of Work package 8 (Spent Fuel Characterization) of the European Joint Programme on Radioactive Waste Management (EURAD) investigates the behaviour of nuclear fuel and cladding after discharge. The aim of the work is to understand and describe the be-haviour of spent nuclear fuel (SNF), irradiated cladding, fuel/cladding chemical interaction (FCCI) and ageing under conditions of extended interim storage, transportation and em-placement in a final disposal system. BAM contributes to the project as partner and leads Task 3. The presentation gives an overview of the project status, main achievements in experimental work and modelling studies, deviations from the plan, delays and challenges ahead.
The European Joint Programme on Radioactive Waste Management (EURAD) is working on Spent Fuel Characterization (SFC) in its work package (WP) 8. Inspired by the EURAD activities, the International Atomic Energy Agency (IAEA) established an international Coordinated Research Project (CRP) on SFC. The EURAD WP SFC
participants are collaborating as a team on the IAEA CRP on SFC. The EURAD WP SFC project consists of four tasks. Task 3 investigates the behaviour of nuclear fuel and cladding after discharge. The aim of these activities is to understand and describe the evolution of the cladding-pellet system and its ageing under conditions of extended interim storage, transportation and emplacement in a final disposal system. At a Consultancy Meeting, BAM as contributor to Task 3 presented current results of the failure analysis of irradiated ZIRLO® claddings under conditions of the Ring Compression Test.
Im Rahmen des Forschungsprojekts "Artificial Intelligence for Rail Inspection" (AIFRI) wird ein KI-Algorithmus entwickelt, um die Fehlererkennung bei der Auswertung von Schienenprüfungen zu verbessern. Der Prozess der mechanisierten Schienenprüfung wird analysiert und die Schienenfehler sowie Artefakte werden in einem digitalen Zwilling abgebildet, um in einem weiteren Schritt die automatische Fehlererkennung und Klassifizierung mit KI-Algorithmen trainieren zu können. Zu diesem Zweck werden Ultraschalldatensätze auf der Grundlage der Regelwerke und Informationen aus der Instandhaltung mit einer Simulationssoftware erstellt, die Anzeigen der verschiedenen Schienenschädigungen und Artefakte enthalten.
Die Schienenfehler werden bei der Auswertung in Fehlerklassen eingeordnet, für das KI-Training priorisiert und auf Basis der von der DB Netz AG ausgewählten Informationen untersucht. Hierfür werden die Schienenfehler nach den für das KI-Training relevanten Merkmalen zerlegt und die Konfiguration der Parameter der Simulation entsprechend abgestimmt.
Für die Grundstruktur des Datensatzes wird ein Schienenmodell mit einer Länge von einem Meter für die Simulation eingesetzt, auf dessen Basis alle bei der Schienenprüfung zu verwendenden Prüfköpfe für den jeweiligen Reflektortyp betrachtet werden. Die simulierten Daten werden auf einer Testschiene im Labormaßstab validiert. Mögliche Einflussparameter wie z. B. der Signal-Rausch-Abstand sowie die Fahrgeschwindigkeit werden in den Datensätzen herangezogen. Die Zusammenstellung eines Testdatensatzes mit lokal veränderlichen Einflussgrößen erfolgt aus den simulierten Daten unter Verwendung der skriptbasierten Programmierumgebung Python und Matlab.
Das Projekt AIFRI wird im Rahmen der Innovationsinitiative mFUND unter dem Förderkennzeichen 19FS2014 durch das Bundesministerium für Digitales und Verkehr gefördert.
Im Rahmen des Forschungsvorhabens AIFRI „Arteficial Intelligence for Rail Inspection“ wird der Prozess der mechanisierten Schienenprüfung in einem digitalen Zwilling abgebildet, um in einem zweiten Schritt mit KI-Algorithmen eine automatisierte Defekterkennung und -klassifizierung trainieren zu können. Hierzu werden relevante Schienenschädigungen und in der Schiene vorhandene Artefakte analysiert und in skalierbare Modelle übertragen.
Die Norm DIN EN 16729-1 „Bahnanwendungen - Infrastruktur - Zerstörungsfreie Prüfung an Schienen im Gleis - Teil 1: Anforderungen an Ultraschallprüfungen und Bewertungsgrundlagen“ gilt für die Prüfausrüstung von Schienenprüffahrzeugen und handgeführten Rollgeräten und legt die Anforderungen an die Prüfgrundsätze und -systeme bei der Prüfung verlegter Eisenbahnschienen fest, um vergleichbare Ergebnisse in Bezug auf Lage, Art und Größe der Unregelmäßigkeiten in den Schienen zu erhalten.
Um die Performance von Prüfsystemen in der Simulation zu evaluieren, wurden die in den Anhängen der DIN EN 16729-1 angegebenen Bezugsreflektoren als künstliche Reflektoren (nach Anhang A) und simulierte Reflektoren (nach Anhang B) in einem digitalen Zwilling mit einem Schienenprofil 54E4 nach DIN EN 13674-1 sowie mit vereinfachter Geometrie als virtuelle Testschienen abgebildet.
Die Simulationen wurden mit den in den Tabellen 3 und 4 nach DIN EN 16729-1 definierten Prüfkopfwinkeln durchgeführt. Die Rechnungen wurden im Labormaßstab an Testkörpern verifiziert und die Signal-Rausch-Abstände für Untersuchungen im Feld ermittelt.
Ergebnisse der Untersuchungen und Möglichkeiten der Anwendung werden vorgestellt.
Das Forschungsvorhaben wird durch das Bundesministerium für Verkehr und digitale Infrastruktur (BMVI) im Rahmen von mFund unter dem Förderkennzeichen 19FS2014 gefördert.
Die Thermografie ist trotz ihrer ausgereiften wissenschaftlichen und technologischen Grundlagen ein noch relativ junges Mitglied in der Familie der zerstörungsfreien Prüfverfahren. Sie erschließt sich aufgrund einer Reihe von Vorzügen eine wachsende Anwendungsgemeinde. Für eine weitere Verbreitung insbesondere im industriellen Kontext spielen Normen, Standards und technische Regeln eine wichtige Rolle. In diesem Beitrag wird der aktuelle Stand der Normung in Deutschland vorgestellt. Wir zeigen, welche Normen und technischen Regeln es für die Thermografie in Deutschland und international gibt und wir wagen einen Blick in die Zukunft. Darüber hinaus lebt auch die Normierungsarbeit von der Beteiligung durch interessierte Kreise. Dies können industrielle und akademische Anwender*innen, Hersteller*innen von Geräten, Forschungseinrichtungen oder Dienstleistungsunternehmen sein. Sie können gern Ihre Bedarfe bezüglich Normierungsprojekten mitbringen und/oder direkt an die Autoren senden.
The aim of the study is to infer the soil stratification from the provided CPT and borehole data. We infer the soil type at any location within the domain of interest from the SBT index Ic (Robertson, 2009). This index can be directly related to the CPT data through an empirical correlation model. In addition, the soil classes contained in the borehole logs can be expressed as bounds on Ic. A log-transformation was applied to Ic, Y = ln(Ic), and Y was modelled by a 3D Random Field, with a fully Bayesian hierarchical Gaussian Process model to explicitly capture uncertainties.
The presentation will start with an overview of ceramic additive manufacturing (AM) technologies and will discuss the potential of AM in the field of bioceramics.
The presentation will then focus on two possible use cases of binder jetting technologies.
In the first example, standard powder-based binder jetting is used to manufacture a porous implant design for large scale bone defects. The related challenges in the process chain will be discussed, from powder synthesis to sintering and characterization of the printed part.
In the second example, the LSD-print slurry-based binder jetting technology is presented as a possibility to adapt powder-bed AM to produce dense ceramic parts. The use case will focus on an application in the field of dental ceramics, specifically for the manufacturing of patient individualized single tooth restorations (veneers, crowns) with a high throughput process chain.
The presentation gives an overview of two slurry-based additive manufacturing (AM) technologies specifically developed for advanced ceramic materials.
The “Layerwise Slurry Deposition” (LSD-print) is a modification of Binder Jetting making use of a ceramic slurry instead of a dry powder as a feedstock. In this process, a slurry is deposited layer-by-layer by means of a doctor blade and dried to achieve a highly packed powder layer, which is then printed by jetting a binder. The LSD-print technology combines the high-speed printing of binder jetting with the possibility of producing a variety of high-quality ceramics with properties comparable to those achieved by traditional processing.
The Laser Induced Slip casting (LIS) technology follows a novel working principle by locally drying and selectively consolidating layer-by-layer a ceramic green body in a vat of slurry, using a laser as energy source. LIS combines elements of Vat Photopolymerization with the use of water-based feedstocks containing a minimal amount of organic additives. The resulting technology can be directly integrated into a traditional ceramic process chain by manufacturing green bodies that are sintered without the need of a dedicated debinding.
Both technologies offer high flexibility in the ceramic feedstock used, especially concerning material and particle size. Advantages and disadvantages are briefly described to outline the specific features of LSD-print and LIS depending on the targeted application.
Additive Manufacturing for dental restorations by layerwise slurry deposition (LSD-print) technology
(2023)
The growing market of custom-made dental restorations offers a major potential for an application of ceramic additive manufacturing (AM).
The possibility to individualize patient specific design and to establish new efficient workflows, from model generation to manufacturing, can be fully exploited by AM technologies. However, for mass customization to be truly envisioned, ceramic AM needs to achieve a level of maturity, aesthetic quality, and productivity comparable to established manufacturing processes.
In this presentation, the potential of the “layerwise slurry deposition” LSD-print technology for dental applications will be explored. It has been shown in the past years that the LSD-print can be applied to advanced ceramic materials such as alumina and silicon-infiltrated silicon carbide. For these materials, the LSD-print technology combines the high-speed printing of binder jetting with the possibility of producing a variety of high-quality ceramics.
The current development deals with the challenges of applying this technology to a feldspar dental material, comparing the quality of AM restorations with the equivalent material for an established CAD/CAM workflow.
Preliminary results not only indicate that the AM material produced by LSD-print can be competitive in terms of mechanical properties, but also that aesthetically satisfactory restorations can be manufactured for veneers, inlays and onlays as well as single unit fixed dental prostheses (FDPs).
The presentation focuses on the material and technological challenges alongside the process chain, from the printing process, to debinding, firing and finishing the restorations.
In our current view, reference datasets in the MSE domain represent specific material properties, e.g., structural, mechanical, … characteristics. A reference dataset must fulfill high-quality standards, not only in precision of measurement but also in a comprehensive documentation of material, processing, and testing history (metadata). This Infrastructure Use Case (IUC) aims to develop a framework for generating reference material datasets using creep data of a single crystal Ni-based superalloy as a best practice example. In a community-driven process, we aim to encourage the discussion and establish a framework for the creation and distribution of reference material datasets. In this poster presentation, we highlight our current vision and activities and intend to stimulate the discussion about the topic reference datasets and future collaborations and work.
High-power hybrid laser arc welding of thick materials with electromagnetic weld pool support
(2023)
In addition to the many advantages of deep penetration, increased welding speed and a low sensitivity to manufacturing tolerances such as gap and edge offset, the hybrid laser arc welding (HLAW) process is used increasingly in industrial applications such as shipbuilding or pipeline manufacturing. Nonetheless, thick-walled sheets with a wall thickness of 20 mm or more are still multi-pass welded using the arc welding process, due to increased process instability by increasing laser power. Welding at reduced speed, especially in a flat position, leads to an irregular formation of the root part such as dropping. The hydrostatic pressure exceeds the surface tension, which decreases with increasing seam width. In order to prevent gravity drop-outs, the use of a melt pool support is necessary. Usual weld pool supports such as ceramic or powder supports require time-consuming mechanical detachment. The electromagnetic weld pool support system, which is described in this study, operates without contact and based on generating Lorentz forces in the weld pool. An externally applied oscillating magnetic field induces eddy currents and generates an upward directed Lorentz force, which counteracts the hydrostatic pressure. This allows single-pass welds up to 30 mm by hybrid laser arc welding process with a 20-kW fibre laser. Moreover, it is favoured by the diminished welding speed the cooling rate which leads to an improvement of the mechanical-technological properties of the seams – the lower formation of martensite in the microstructure enables better Charpy impact toughness. The electromagnetic weld pool support extends the limitation of the laser hybrid welding process in the thick sheet area. By adapting the electromagnetic weld pool support to the laser and laser hybrid welding process, the application potential of these technologies for industrial implementation can be drastically increased.
The study deals with the influence of the heat input on the thermal cycles, the microstructure and the mechanical properties for laser-hybrid welded steels of S355J2 with thicknesses up to 30 mm using a 20-kW high-power laser with contactless electromagnetic backing. The focus is on the change of the mechanical properties over the seam thickness. Therefore, the impact toughness and tensile strength were tested in different depths. Based on the experiments, a heat input of 1.3 kJ/mm - 1.6 kJ/mm, 2 kJ/mm - 2.4 kJ/mm and 3.7 kJ/mm were recommended when single-pass welding of 20 mm, 25 mm and 30 mm with a 20-kW laser in regard to the minimum requirements of the mechanical properties, respectively. Lower heat inputs led to undesired microstructure consisting of martensite, hardening and deteriorated impact toughness, where higher heat inputs led to grain-coarsening and even loss of impact strength due to the formation of retained-austenite on the grain boundaries.
The laser hybrid welding process offers many advantages during welding oft hick-walled steels, such as the increased penetration depth and, thus, reduced number of layers, reduced heat input and decreased distortion compared to arc-based welding processes. Especially, when welding high-strength steels (HSS), the reduced heat input plays an essential role. However, a major challenge when laser hybrid welding of thick-walled steels is the limited filler wire mixing over the entire seam thickness, which can lead to changed mechanical properties over the depth. To overcome this issue, the add of oxygen into the shielding gas and its influence on the filler wire mixing and finally to the mechanical properties were investigated within this work. Therefore, 20 mm thick S690QL steels were laser hybrid welded in a single-pass. A contactless electromagnetic backing was used to avoid sagging. The admixture of oxygen was performed by a gas mixer, where the oxygen content was varied between 0 % and 7.2 %. The experiments were also accompanied by laser beam welding tests in steel/glass configuration, where the melt pool geometry as well as the melt flow characteristics were captured by a high-speed camera. It can be concluded, that adding of 2 % to 4 % oxygen into the shielding gas had a positive effect on the filler wire mixing, were up to a depth of 18 mm elements of the filler wire could be observed.
The most common welding processes when joining thick-walled steels in the industry are arc-based welding processes such as GMAW or SAW. For this purpose, the sheets are joined in multi-layer technique, which can lead to productivity losses due to high welding times. The process-specific challenges in welding thick steels using multi-layer technique relate to the high heat input from the process. Therefore, alternative welding processes are being actively sought. A suitable alternative is provided by beam-based welding processes such as the laser beam or laser hybrid welding processes, which are characterized by deep penetration welds and lower heat input. With implementation of the laser hybrid welding process in the heavy industry, such as the wind tower industry, economic benefits can be reached such as the increase in productivity by reducing the layer number, and the lower consumption of filler material and energy. When comparing SAW welded 25 mm thick steels in five to six layers and single-pass laser hybrid welding, the welding time can be reduced more than 80 % and the costs of filler material, flux and energy can be saved up to 90 %. However, the industrial use of the laser hybrid welding process is still limited to applications, where the material thickness does not exceed 15 mm due to some process-specific challenges such as the sagging, sensitivity to manufacturing tolerances such as gaps and misalignment, limited filler wire mixing, and deteriorated mechanical properties resulting from high cooling rates. To overcome these challenges, an electromagnetic backing was used within the framework of this work, which works contactless and is based on an externally applied AC magnetic field. Eddy currents are induced due to the oscillating magnetic field, and an upward-oriented Lorentz force is generated to counteract the droplets formed due to gravitational forces. It allows to weld up to 30 mm thick structural steels in a single-pass with a 20-kW fiber laser system. Additionally, the gap bridgeability and the misalignment of edges were increased to 2 mm when welding 20 mm thick steels. With the aid of the AC magnetic field, a vortex was formed in the weld root, which had a positive effect on the filler wire mixing. A further significant advantage of the EM backing was the possibility to expand the process parameter window to maintain desired cooling times and mechanical properties, without suffering adverse effects concerning the root quality of the weld.
The laser hybrid welding process offers many advantages such as the high penetration depth and high welding speed, and it is characterized by its low heat input compared to the arc-based welding processes, which makes the laser hybrid welding process as a suitable alternative process when welding thick-walled steels. However, there are some challenges when using laser hybrid welding process for thick steels. Due to the uneven cooling conditions and the inhomogeneous filler wire mixing, a typical laser hybrid weld can be divided into two different zones over the depth: the arc-dominated zone on the upper part and the laser-dominated zone in the root part. This leads to different mechanical properties in a laser hybrid welded joint. Due to the high cooling rates and the lack of filler wire in the laser-dominated zone, this area is more critical regarding the mechanical properties, especially the Charpy impact toughness. A low heat input can lead to undesired microstructure consisting of martensite, hardening and deteriorated impact toughness due to the high cooling rate, where higher heat inputs can lead to grain-coarsening and even loss of impact strength. This study deals with the influence of the welding speed and resulting heat input on the cooling rates, the microstructure and the mechanical properties of single-pass laser hybrid welded steels of S355J2 with thickness up to 30 mm. The experiments were performed with a 20-kW fibre laser system and a contactless electromagnetic weld backing on up to 30 mm thick steels in butt-joint configuration in 1G welding position. The cooling time was measured in three different locations near to fusion lines corresponding to different heights of the seam using a special configuration with pyrometers, collimators, and optical fibres. The test specimens for the Charpy impact testing and tensile testing were extracted in up to three different depths. Based on the experiments, a heat input of 1.3 kJ/mm - 1.6 kJ/mm, 2 kJ/mm - 2.4 kJ/mm and 3.7 kJ/mm were recommended when single-pass laser hybrid welding of 20 mm, 25 mm and 30 mm thick structural steels in regard to the minimum requirements of the mechanical properties, respectively. The optical measurement of the cooling times in different depths could be carried out reproducibly.