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Das Master Curve (MC) Konzept nach ASTM E1921 wird momentan u.a. in der Kerntechnik für die bruchmechanische Sicherheitsbewertung ferritischer Stähle eingesetzt. Für ferritisches Gusseisen mit Kugelgraphit (GJS) fehlt jedoch eine Validierung dieser Methode und ggf. eine systematische Überprüfung möglicher Modifikationen grundlegender Ansätze des MC-Konzepts. Aus diesem Grund soll in einem kürzlich gestarteten BMUV-Verbundprojekt zwischen der MPA Stuttgart und der BAM Berlin die Anwendbarkeit des MC-Konzepts auf GJS bei dynamischer Beanspruchung untersucht werden. Ziel ist es, eine effektive und effiziente Methodik bereitzustellen, mit der mittels einer vergleichsweise kleinen Stichprobe bruchmechanischer Kleinproben eine Referenztemperatur T0 zur werkstoffspezifischen Temperaturjustierung der MC ermittelt werden kann.
Als elektrische Durchschlagfestigkeit bezeichnet man die elektrische Feldstärke, bei der es zur Entladung durch ein isolierendes Medium kommt. Im Falle von Festkörpern ist dies ein zerstörender Prozess. Bei der messtechnischen Bestimmung der Durchschlagfestigkeit haben neben den verwendeten Messgeräten auch die eingesetzten Elektroden, die Form des Prüfkörpers und das Isoliermedium, in dem die Prüfung stattfindet, einen signifikanten Einfluss auf die ermittelten Messwerte. Im Vortrag werden die Einflüsse erläutert und anhand von Messreihen aus der Literatur und der eigenen Forschung quantifiziert. Aufgrund der vorgestellten Effekte wird klar, dass es sich bei elektrischer Durchschlagfestigkeit nicht um absolute Materialkennwerte handelt, sondern vielmehr um systemabhängige Größen.
Inorganic nanocrystals with linear and nonlinear luminescence in the ultraviolet, visible, near infrared and short-wave infrared like semiconductor quantum dots and spectrally shifting lanthanide-based nanophosphors have meanwhile found applications in the life and material sciences ranging from optical reporters for bioimaging and sensing over security barcodes to solid state lighting and photovoltaics. These nanomaterials commonly have increasingly sophisticated core/shell particle architectures with shells of different chemical composition and thickness to minimize radiationless deactivation at the particle surface that is usually the main energy loss mechanism [1]. For lanthanide-based spectral shifters, particularly for very small nanoparticles, also surface coatings are needed which protect near-surface lanthanide ions from luminescence quenching by high energy vibrators like O-H groups and prevent the disintegration of these nanoparticles under high dilution conditions. [2,3,4]. The identification of optimum particle structures requires quantitative spectroscopic studies focusing on the key performance parameter photoluminescence quantum yield [5,6], ideally flanked by single particle studies to assess spectroscopic inhomogeneities on a particle-to-particle level for typical preparation methods [7,8], Moreover, in the case of upconversion nanoparticles with a multi-photonic and hence, excitation power density (P)-dependent luminescence, quantitative luminescence studies over a broad P range are required to identify particle architectures that are best suited for applications in fluorescence assays up to fluorescence microscopy. Here, we present methods to quantify the photoluminescence of these different types of emitters in the vis/NIR/SWIR and as function of P and demonstrate the importance of such measurements for a profound mechanistic understanding of the nonradiative deactivation pathways in semiconductor and upconversion nanocrystals of different size and particle architecture in different environments.
After describing the basics of distributed fiber optic sensing in general and distributed fiber optic acoustic sensing (DAS) in particular, several currently and previously investigated fields of application of DASin infrastructure monitoring and seismic monitoring are presented. A focus is placed on seismic measurements and DAS measurements determining the dynamic responses of concrete structures to certain stimuli.
The variability and heterogeneity in their structural composition is significant for nearly all synthetic and natural polymers. Beside molar mass also functionality type distribution, copolymer composition distribution and architectural features are responsible for changing the material properties.
A wide range of analytical techniques are available to get insight into these parameters. However, in most cases it is essential to combine different sophisticated techniques to get closer to actual structures and to avoid statistical averages.
Different liquid chromatographic separation modes and their coupling in a two-dimensional way (SEC, LCCC, HILIC, 2D-LC) in combination with suitable detection techniques (e.g. UV, RI, LS, IR, MALDI/ESI-MS) as well as techniques like BET, DCS, SEM/TEM were applied to make structural features visible.
A few aspects are discussed for structural different polylactides from various synthesis routes and their behavior in LC-MS. Moreover, some analytical results for technical lignins valorized by mechanochemical treatment or modified by functional polymers are presented.
Inductively coupled plasma mass spectrometry (ICP-MS) emerged as a powerful technique for trace analysis of soil due to its multi-element capability, high sensitivity and low sample consumption. However, despite its success and widespread use, ICP-MS has several persistent drawbacks, such as high argon gas consumption, argon-based polyatomic interferences and the need for complicated RF-power generators. Unlike argon-based ICP, the nitrogen microwave inductively coupled atmospheric pressure mass spectrometry (MICAP-MS) uses nitrogen as plasma gas, which eliminates high operating costs associated with argon-gas consumption as well as the argon-based interferences1. In this work, the applicability of MICAP-MS for elemental analysis in different matrices is investigated. For this purpose, reference soil samples and steel samples are digested with aqua regia and used for analysis. Concentrations of selected elements are determined using MICAP-MS and validated with ICP-MS und certified values. Sensitivities, limits of detection and gas consumption for both methods are compared and discussed in detail. Performance of MICAP-MS under different nitrogen plasma gas concentrations is investigated and compared. Moreover, the performance of MICAP-MS in alloy matrices is investigated and discussed.
Die VDI Richtlinie 3837 enthält detaillierte Angaben zur Erschütterungsemission. Die DIN 45672-3 enthält nur den Tunnel- oder einen Bodenmesspunkt als Ausgangspunkt der Prognose. Die Erschütterungsanregung durch die Fahrzeug-Fahrweg-Wechselwirkung wird beschrieben. Die ERgebnisse der BAM stimmen sehr gut mit dem Prognosekonzept von Highspeed 2 überein. Dies wird an den Punkten 1. Störgrößen, 2. Achsimpulse, 3. Tunnelstrecken aufgezeigt.
Der Vortrag stellt die wesentlichen Inhalte sowie die wichtigsten Änderungen der TRGS 510 "Lagerung von Gefahrstoffen in ortsbeweglichen Behältern" vor.
Die TRGS 510 zeichnet sich durch ein gestuftes Maßnahmenkonzept in Abhängigkeit von der Art und Menge der gelagerten Gefahrstoffe aus. Folgende Maßnahmenstufen werden durch die TRGS 510 beschrieben:
1. Kleinmengen -> Allgemeine Maßnahmen
2. Überschreitung der Kleinmengen -> Lagerung im Lager
3. Überschreitung bestimmter Mengen für spezielle Gefahrstoffe -> Spezielle Maßnahmen
4. Verschiedene Gefahrstoffe und Lagerung im Lager erforderlich -> ggf. Getrenntlagerung und Separatlagerung
Im Rahmen dieses Vortrags werden die Besonderheiten beim Einsatz von Messtechnik bei Versuchen im Groß- und Realmaßstab und unter Freifeldbedingungen dargestellt. Anhand des Themenfeldprojektes CoFi-ABV und der dort durchgeführten Versuchsreihen werden die Rand- und Rahmenbedingungen beim Durchführen der Experimente, Instrumentierung und Versuchsaufbau sowie beispielhafte Ergebnisse erläutert.
Der Erhalt einer dauerhaft sicheren Infrastruktur erfordert neben der Berücksichtigung technisch bedingter Alterungs- und Schädigungsprozesse auch die Umsetzung aktueller gesellschaftlicher Herausforderungen wie die Integration neuer Mobilitätskonzepte, Steigerung der Resilienz gegenüber Klimawandel oder Ressourcenschonung. Die parallele Umsetzung dieser „alten“ und „neuen“ Anforderungen lässt sich nur durch räumlich und zeitlich skalenübergreifende Betrachtungen lösen, die ohne digitale Prozesse nicht möglich sein werden. Am Beispiel des Elements der Querscheinfuge in Betonstraßenoberflächen wird in diesem Vortrag aufgezeigt, wie die BAM durch Kombination diverser Projekte zu einzelnen Aspekten dieser Fragestellung in einem ganzheitlichen Konzept eines digitalen Zwillings dieses Bauelements löst.
Laser-induced Periodic Surface Structures (LIPSS, ripples) are a universal phenomenon and can be generated in a contactless, single-step process on almost any type of solid upon irradiation with intense laser pulses. They represent a (quasi-)periodic modulation of the surface topography in the form of a linear grating and are typically formed in a “self-ordered” way in the focus of a laser beam. Thus, they are often accompanying laser material processing applications. The structural sizes of LIPSS typically range from several micrometers down to less than 100 nanometers – far beyond the optical diffraction limit – while their orientations exhibit a clear correlation with the local polarization direction of the laser radiation.
From a theoretical point of view, a controversial debate has emerged during the last decades, whether LIPSS originate from electromagnetic effects (seeded already during the laser irradiation) – or whether they emerge from matter-reorganization processes (distinctly after the laser irradiation). From a practical point of view, however, LIPSS represent a simple and robust way for the nanostructuring of solids that allows creating a wide range of different surface functionalities featuring applications in optics, tribology, medicine, energy technologies, etc.
This presentation reviews the currently existent theories of LIPSS. A focus is laid on the historic development of the fundamental ideas behind the LIPSS, their corresponding mathematical descriptions and numerical implementations, along with a comparison and critical assessment of the different approaches.
Fourth generation light sources, namely short wavelength, short pulse free electron lasers (FELs) are offering new and fascinating possibilities to resolve laser-induced structure formation at surfaces on the sub-micrometer to nanometer length scale and in temporal regimes ranging from picoseconds to several nanoseconds with sub-picosecond resolution. This unique spatio-temporal resolution allows to reveal early signatures of coherent/plasmonic electromagnetic scattering effects followed by the excitation of hydrodynamic capillary waves – providing new insights to the above-mentioned debate.
Finally, some unsolved scientific problems related to LIPSS are identified and the pending technological limitations are discussed. While the currently available laser and scanner technology already allows large area surface processing with rates at the m2/min level, industrial applications of LIPSS are sometimes limited by the complex interplay between the nanoscale surface topography and the specific surface chemistry. This typically manifests in difficulties to control the processing of LIPSS and in limitations to ensure the long-term stability of the created surface functions. Strategies for overcoming such limitations are outlined.
Multi-sensory monitoring and ultrasound for quality assurance at underground sealing structures
(2023)
Within the safety concepts of underground disposal sites of nuclear waste, engineered barriers play an important role. As these sealing structures have high demands concerning integrity, we aim at advancing the available construction materials, monitoring and inspection techniques within the project SealWasteSafe.
After successful laboratory analysis on the cm-scale, cylindrical and cuboid specimens on the m-scale are produced from classical salt concrete and a specifically developed alkali-activated material. A comprehensive multi-sensory monitoring scheme is applied to compare the setting process of both materials and to demonstrate the sensors’ resistance to highly alkaline environments. Besides temperature and humidity of the materials, strain variations using fibre optic sensors and acoustic emissions are recorded over periods of at least 28 days, partly for more than 8 months. Passive sensor systems based on radiofrequency identification technology (RFID) embedded in the concrete allow for wireless access to temperature and humidity measurements and are compared to conventional cabled systems. After hardening and removal of the outer casings of the specimens, further non-destructive evaluations using ultrasonic echo and thermographic measurements are conducted. Preliminary results clearly highlight differences between the tested materials, particularly showing lower acoustic emission activity for the newly developed alkali-activated material potentially indicating less phase changes or cracks.
Complementary, ultrasonic methods are improved to be used for quality assurance to detect obstacles, potential cracks and delamination at in-situ sealing structure scale. A unique large aperture ultrasonic system (LAUS) with depth penetration as large as 9 m has already successfully been applied at the test site in Morsleben, Germany, of the federal company for radioactive waste disposal (BGE). Modelling studies help to further optimize the measurement layout. Advanced imaging techniques applied to the modelled and measured data will further improve the obtained images of internal structures. Additionally, an ultrasonic borehole probe is developed and constructed using phased arrays to further enhance the detection of potential cracks. Modelling and preliminary results from laboratory specimens prove the feasibility and potential of the directional response even in heterogeneous material such as concrete. Final investigations under in-situ conditions at the test site of the sealing structure are planned.
Overall, the project SealWasteSafe improves the construction material, multi-sensory monitoring, and ultrasound for quality assurance to allow for the development of safe nuclear sealing structures. Although the techniques are tailored for sealing structures within salt as a host rock, they are transferrable to a wider field of applications and alternative disposal conditions.