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- Pool fire (5) (entfernen)
The mass burning rate of pool fires of organic peroxides do not vary appreciably with the pool size as have been observed for the hydrocarbons. Instead the decomposition temperature largely controls the same. The dependence of mass burning rate on the decomposition temperatures namely self-accelerating decomposition temperature (SADT) and extrapolated onset temperature measured by differential scanning calorimetry (DSC) for organic peroxide pool fires are identified and correlations are developed.
Dampening of energetic properties and the effects of blending proportions of isododecane on the diffusive burning behaviour of peroxy-fuels are experimentally studied. Blended peorxy-fuels are obtained by adding isododecane in the proportions of 25 wt.%, 50 wt.% and 75 wt.%, respectively, in technical pure peroxy-fuels. The fuels were burned in form of pool fires with diameters 0.02 m ≤ d ≤ 1 m. The mass burning rates and relative flame lengths are found to be weakened with increasing diluent proportions. By measuring the mass burning rates and visible flame lengths of pool fires of different samples of fuel blends an optimum blending criterion is developed. Furthermore, it is shown that the dilution proportions and flame characteristics can be correlated by empirical equations.
Data and predictions for the mass burning rates of di-tert-butyl peroxide (DTBP) pool fires (0.003 m < pool diameter < 3 m) are presented. The mass burning rates of DTBP fires are up to five times higher and are less dependent on pool diameter compared to hydrocarbon pool fires caused by an additional heat release rate due to exothermic decomposition reaction in the liquid phase. This heat release rate is calculated using a first-order reaction kinetic obtained from microcalorimetric measurements. A new model is derived considering the heat release rate due to the decomposition reaction, which is shown to be 40% of the heat release rate radiated to the pool surface. With the presented model, which also includes physical quantities, especially the limiting fuel concentration for upward flame propagation, it is possible to predict the mass burning rates of large DTBP pool fires. The predicted values are in very good agreement with the experiments.
Computational fluid dynamics (CFD) simulation is used to predict transient and time-averaged glame temperatures and species concentrations of an n-hexane pool flame. Employing a combination of an assumed probability density function approach with laminar flamelets using detailed kinetic data and large-eddy simulation with Smagorinsky submodel is shown to be a promising way in modeling pool and tank fires. The measured species concentration and flame temperature profiles from gas chromatography, thermocouple measurements and holographic interferometry are used to validate the submodels for CFD simulation of pool flames.
A simple model that divides the heat flux to the bodies engulfed in a diffusion flame into different components, namely radiation and convection is studied. Different sizes of brass and stainless steel (SS 304L) rods varying from 25.4 mm to 50.8 mm in length and 25.4 mm in diameter are used as specimens in this study. Experiments are conducted with each body inside a diesel pool fire of different diameters, namely 0.5 m, 0.7 m and 1.0 m. The temperature history of the body engulfed in a pool fire is measured to compute the thermal energy absorbed by the lumped body. Using an energy balance, the total energy is divided into three different components. The gas velocity in the flame is measured to be 1.53 m/s to 1.79 m/s for the diesel pool fires of 0.5 m to 1.0 m in diameter. The dominant mode of heat transfer in this study is radiative in nature. This simple model is reasonably able to predict the heat flux incident on to the lumped bodies engulfed by diesel pool fires using the measured temperature history. A three dimensional formulation for an axi-symmetric pool fire of a measured flame shape, flame temperature and a gray flame absorption coefficient is employed to predict the temperature of the body engulfed in pool fires. This formulation has to be modified to capture the absolute temperature values of the flame.