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Duplex stainless steels combine the positive properties of its two phases, austenite and ferrite. Due to its good corrosion resistance, high tensile strength, and good ductility, it has multiple applications. But laser beam welding of duplex steels changes the balanced phase distribution in favor of ferrite. This results in a higher vulnerability to corrosion and a lower ductility. Herein, different powder combinations consisting of duplex and nickel for coating layers by laser metal deposition (LMD) are investigated. Afterward, laser tracks are welded, and the temperature cycles are measured. The ferrite content of the tracks is analyzed by feritscope, metallographic analysis, and electron backscatter diffraction. The goal is the development of a powder mixture allowing for a duplex microstructure in a two-step process, where first the edges of the weld partners are coated with the powder mixture by LMD and second those edges are laser beam welded. The powder mixture identified by the pretests is tested in the two-step process and analyzed by metallographic analysis, energy-dispersive X-ray spectroscopy, and
Vickers hardness tests. The resulting weld seams show a balanced duplex microstructure with a homogenous nickel distribution and a hardness of the weld seam similar to the base material.
Nine different stainless steel alloys were exposed for 5 years under marine environment and their corrosion behaviour was compared and assessed. The investigation of four different surface finishes for all alloys tested further enabled to consider industry-specific features of the surface finish for the material comparison. The results of the exposure tests yield conclusions regarding the influence of alloy composition, surface finish and exposure duration under marine environment. The three duplex stainless steels revealed excellent corrosion resistance even in case of crevices during the 5 years of exposure under the given exposure conditions. Also the molybdenum-alloyed ferritic steel 1.4521 showed good corrosion resistance comparable to the classical austenitic materials 1.4301 and 1.4404.
A laser-induced breakdown spectroscopy (LIBS) system was combined with a bead-on-plate Tungsten Inert Gas (TIG) welding process for the in situ measurement of chemical compositions in austenitic stainless steels during welding.Monitoring the weld pool's chemical composition allows governing the weld pool solidification behavior, and thus enables the reduction of susceptibility to weld defects. Conventional inspection methods for weld seams (e.g. ultrasonic inspection) cannot be performed during the welding process. The analysis system also allows in situ study of the correlation between the occurrence ofweld defects and changes in the chemical composition in theweld pool or in the two-phase regionwhere solid and liquid phase coexist. First experiments showed that both the shielding Ar gas and the welding arc plasma have a significant effect on the selected Cr II, Ni II and MnII characteristicemissions, namely an artificial increase of intensity values via unspecific emission in the spectra.
In situ investigations showed that this artificial intensity increase reached a maximum in presence of weld plume. Moreover, an explicit decay has been observedwith the termination of thewelding plumedue to infrared radiation during sample cooling. Furthermore, LIBS can be used after welding to map element distribution. For austenitic stainless steels,Mnaccumulations on both sides of theweld could be detected between the heat affected zone (HAZ) and the base material.
Due to significant developments over the last decades, laser beam welding has become a well-established industrial process offering high processing speeds and causing low component distortions. But an important issue currently preventing its intense use, especially in the energy or plant construction sector where high alloy steels are applied, concerns hot crack formation. Although considerable advances in understanding hot cracking mechanisms have been made, most of the known influencing factors are metallurgical in character. The thermo-mechanical effects are barely considered or quantified. Up to the present, there exist numerous hot cracking tests that were however conceived for welding methods other than laser beam welding. Considering the special features of the laser welding process, such as high cooling rates and the narrow process zone, results obtained with other welding techniques and test procedures cannot be transferred to laser beam welding. In this study, the laser beam weldability of various stainless steels was examined in terms of their susceptibility to hot cracking by means of the controlled tensile weldability test, which was proven to be suitable for use in conjunction with CO2 laser welding. This test allows the application of tensile strain at a variable fixed cross-head speed transverse to the welding direction. Full and partial penetration bead-on-plate welds were produced. In a first attempt to determine the impact of the applied external strain on the local transient strains and strain rates near the weld pool, an optical system was used to measure the backside surface of partial penetration welds. The results showed the influence of the strain and the strain rates on hot crack formation. Furthermore, a classification of the studied austenitic, duplex and ferritic stainless steels according to the established test criteria (critical strain and cross-head speed) was conducted.