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Lifetime prediction and degradation assessment of FKM and FFKM O-rings under high temperature thermo-oxidative ageing

  • To support the development of solar reactor technologies for hydrogen production, this study investigates the thermo-oxidative degradation mechanisms of fluorinated elastomers and predicts their lifetimes at high temperatures (200–300 ◦C) consistent with the application requirements. An accelerated ageing programme is conducted with FKM and FFKM O-rings and flat samples for up to 21 days. Optical microscopy is used to analyse the exposed seals’ morphological changes, while IR microscopy is utilised to investigate the underlying chemical degradation mechanisms of both elastomers. Findings suggest that FKM’s degradation arises from dehydrofluorination of the polymer, followed by chain scission and backbone cleavage as a result of the oxidation of newly formed C=C double bonds. FFKM’s degradation is primarily associated with chain scission, but there is also indication that post-curing processes may occur during material ageing. Furthermore, hardness, equilibrium compression set (CS),To support the development of solar reactor technologies for hydrogen production, this study investigates the thermo-oxidative degradation mechanisms of fluorinated elastomers and predicts their lifetimes at high temperatures (200–300 ◦C) consistent with the application requirements. An accelerated ageing programme is conducted with FKM and FFKM O-rings and flat samples for up to 21 days. Optical microscopy is used to analyse the exposed seals’ morphological changes, while IR microscopy is utilised to investigate the underlying chemical degradation mechanisms of both elastomers. Findings suggest that FKM’s degradation arises from dehydrofluorination of the polymer, followed by chain scission and backbone cleavage as a result of the oxidation of newly formed C=C double bonds. FFKM’s degradation is primarily associated with chain scission, but there is also indication that post-curing processes may occur during material ageing. Furthermore, hardness, equilibrium compression set (CS), continuous compression stress relaxation (CSR) and leakage rate tests are used to evaluate changes in the mechanical properties and sealing performance of the elastomers. Equilibrium CS data is extrapolated using time-temperature shifts (TTS) and used to derive an end-of-life criterion of 75 % equilibrium CS, which correlates to leakage rates higher than a predetermined threshold. Service lifetime predictions of FKM and FFKM O-rings at several temperatures are performed and a seal operating temperature of 200 ◦C is suggested, which ensures reasonable O-ring replacement intervals of more than half a year in the solar reactor for both considered materials.zeige mehrzeige weniger

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Autor*innen:E. Vega PugaORCiD, Volker WachtendorfORCiD, Anja KömmlingORCiD, S. Brendelberger, Matthias JaunichORCiD, C. SattlerORCiD
Dokumenttyp:Zeitschriftenartikel
Veröffentlichungsform:Verlagsliteratur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Polymer Testing
Jahr der Erstveröffentlichung:2025
Organisationseinheit der BAM:3 Gefahrgutumschließungen; Energiespeicher
3 Gefahrgutumschließungen; Energiespeicher / 3.4 Sicherheit von Lagerbehältern
7 Bauwerkssicherheit
7 Bauwerkssicherheit / 7.5 Technische Eigenschaften von Polymerwerkstoffen
Veröffentlichende Institution:Bundesanstalt für Materialforschung und -prüfung (BAM)
Verlag:Elsevier BV
Verlagsort:Amsterdam
Jahrgang/Band:147
Aufsatznummer:108820
Erste Seite:1
Letzte Seite:17
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten
Freie Schlagwörter:Compression set; Fluoroelastomer; Lifetime prediction; Perfluoroelastomer; Thermo-oxidative ageing
Themenfelder/Aktivitätsfelder der BAM:Energie
Energie / Wasserstoff
Material
Material / Degradationsmechanismen
DOI:10.1016/j.polymertesting.2025.108820
URN:urn:nbn:de:kobv:b43-630112
ISSN:1873-2348
Verfügbarkeit des Dokuments:Datei für die Öffentlichkeit verfügbar ("Open Access")
Lizenz (Deutsch):License LogoCreative Commons - CC BY-NC-ND - Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International
Datum der Freischaltung:30.04.2025
Referierte Publikation:Ja
Datum der Eintragung als referierte Publikation:12.05.2025
Paper des Monats:Ja
Schriftenreihen ohne Nummerierung:Wissenschaftliche Artikel der BAM
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