ZIF-derived Atomically Dispersed Non-precious Metal Catalysts (M-N-C) for Electrochemical Energy Applications

  • Zeolitic imidazolate frameworks (ZIFs) which are a subtype of metal organic frameworks (MOFs) have been extensively used to prepare catalyst materials for a variety of electrochemical reactions for energy conversion and storage applications. Most notable examples of ZIFs used for that purpose include ZIF-8 and ZIF-67 etc. Particularly ZIF-8 with its high surface area, defined pore structure and tunable particle size is widely utilized as a platform material to prepare so-called metal- and nitrogen-doped carbon (M-N-C) catalysts with M= Co, Fe, Ni, Zn etc., which are an emerging class of catalyst materials and consist of nitrogen-doped porous carbon matrix hosting atomically distributed active metal sites.[1, 2] The active sites in M-N-Cs ideally have M-N4 coordination resembling to metal centres in macromolecules such as porphyrins and phthalocyanines.[3] Most representative examples of M-N-Cs include Fe-N-Cs, Co-N-Cs and Ni-N-Cs etc. which are showing promising activities for aZeolitic imidazolate frameworks (ZIFs) which are a subtype of metal organic frameworks (MOFs) have been extensively used to prepare catalyst materials for a variety of electrochemical reactions for energy conversion and storage applications. Most notable examples of ZIFs used for that purpose include ZIF-8 and ZIF-67 etc. Particularly ZIF-8 with its high surface area, defined pore structure and tunable particle size is widely utilized as a platform material to prepare so-called metal- and nitrogen-doped carbon (M-N-C) catalysts with M= Co, Fe, Ni, Zn etc., which are an emerging class of catalyst materials and consist of nitrogen-doped porous carbon matrix hosting atomically distributed active metal sites.[1, 2] The active sites in M-N-Cs ideally have M-N4 coordination resembling to metal centres in macromolecules such as porphyrins and phthalocyanines.[3] Most representative examples of M-N-Cs include Fe-N-Cs, Co-N-Cs and Ni-N-Cs etc. which are showing promising activities for a variety of electrochemical reactions e.g. oxygen reduction reaction (ORR), carbon dioxide reduction reaction (CO2RR) and hydrogen evolution reaction (HER). The structures of M-N-C catalysts are quite complex and require a fine balance between morphological, electronic, and chemical properties to reach optimal electrocatalytic activities. In this talk, I will present our activities on (i) preparation of phase-pure M-N-C catalysts derived from ZIF-8 via active-site imprinting [4, 5] and highlight the benefits of our strategy to achieve high density of active sites and enhanced electrochemical performance levels [6] and (ii) feasibility of using gas physisorption techniques as a new approach to quantify active sites in M-N-Cs. The challenges of maximizing active site utilization and eliminating unfavourable mass-transport characteristics faced by ZIF-8 derived M-N-Cs in electrochemical energy devices e.g. fuel cells will also be briefly discussed.zeige mehrzeige weniger

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Metadaten
Autor*innen:Asad Mehmood
Koautor*innen:Simon Dietzmann, Jian Liang LowORCiD, Tim-Patrick FellingerORCiD
Dokumenttyp:Vortrag
Veröffentlichungsform:Präsentation
Sprache:Englisch
Jahr der Erstveröffentlichung:2025
Organisationseinheit der BAM:3 Gefahrgutumschließungen; Energiespeicher
3 Gefahrgutumschließungen; Energiespeicher / 3.6 Elektrochemische Energiematerialien
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik
Freie Schlagwörter:Electrochemical CO2 reduction; Electrochemical energy conversion; Electrolyzers; Fuel cells; Single atom catalysts
Themenfelder/Aktivitätsfelder der BAM:Energie
Energie / Elektrische Energiespeicher und -umwandlung
Veranstaltung:Materials for Sustainable Development Conference (MAT-SUS)
Veranstaltungsort:Sevilla, Spain
Beginndatum der Veranstaltung:03.03.20225
Enddatum der Veranstaltung:07.03.20225
DOI:https://doi.org/10.29363/nanoge.matsusspring.2025.251
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:10.04.2025
Referierte Publikation:Nein
Eingeladener Vortrag (wissenschaftliche Konferenzen):Nein
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