A Dual Glow Discharge Optical Emission Spectroscopic and Mass Spectrometric Study of Manufacturing and Aging in Lithium-Ion Batteries

  • Lithium-ion batteries (LIBs) are extensively employed to power small electric and stationary devices as well as electric vehicles (EVs), due to their high energy density, long cycle life, and relatively low self discharge. The rapid expansion of the EV market is expected to increase significantly the global demand for LIBs, with sales projected to reach 245 million units by 2030, according to the International Energy Agency. In order to meet this demand, it is essential to reduce manufacturing scrap rates and extend battery life. [1,2] Production efficiency can be increased by limiting production failures and detecting process deflections at early stages of manufacturing chain, for example through rigorous control of the electrode homogeneity. On the other hand, the prolongation of a battery life assumes deep knowledge of the degradation processes, such as dendrite formation and electrolytes degradation, directly correlated with a change in the elemental distribution inside theLithium-ion batteries (LIBs) are extensively employed to power small electric and stationary devices as well as electric vehicles (EVs), due to their high energy density, long cycle life, and relatively low self discharge. The rapid expansion of the EV market is expected to increase significantly the global demand for LIBs, with sales projected to reach 245 million units by 2030, according to the International Energy Agency. In order to meet this demand, it is essential to reduce manufacturing scrap rates and extend battery life. [1,2] Production efficiency can be increased by limiting production failures and detecting process deflections at early stages of manufacturing chain, for example through rigorous control of the electrode homogeneity. On the other hand, the prolongation of a battery life assumes deep knowledge of the degradation processes, such as dendrite formation and electrolytes degradation, directly correlated with a change in the elemental distribution inside the battery. [3] As techniques capable of in-depth elemental analysis at scales from a few nm to 100 μm, Glow Discharge Optical Emission Spectroscopy (GD-OES) and Glow Discharge Mass Spectrometry (GD-MS) are suited for investigating both the homogeneity of the cathodic material in the manufacturing phase, as well as changes in its elemental distribution caused by aging. Focus has been given to lithium and fluorine distribution, whose migration inside the battery is correlated to the cycling and the electrolyte and binder degradation, respectively. A few previous reports described depth profiling of positive and negative electrodes in LIBs using GD OES. [4 6] In this work, GD-OES spectroscopic analysis has been performed on self-made cathodes for LIBs to gain insight into the quality of the manufacturing process, targeting a standardized electrodes production. With the same cathode material, coin cells have been built and artificially aged. Post mortem analysis conducted by GD-OES with the use of an argon/neon mixture as discharge gas, helped correlating the variation of fluorine distribution with the battery state of health (SOH). GD MS analysis was employed to gain insight into battery degradation phenomena upon aging, such as transition metal dissolution from the positive electrode and lithium isotopic fractionation [3,7]. This work marks GD-techniques as versatile and efficient tools to study LIBs, unveiling significant application in both academical research and industrial manufacture.zeige mehrzeige weniger

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Autor*innen:Beatrice BattistellaORCiD
Koautor*innen:Volker Hoffmann, Dalia Morcillo, Silke RichterORCiD, Sebastian Recknagel, Carlos Enrique Abad AndradeORCiD
Dokumenttyp:Vortrag
Veröffentlichungsform:Präsentation
Sprache:Englisch
Jahr der Erstveröffentlichung:2025
Organisationseinheit der BAM:1 Analytische Chemie; Referenzmaterialien
1 Analytische Chemie; Referenzmaterialien / 1.6 Anorganische Referenzmaterialien und Gasanalytik
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik
Freie Schlagwörter:GD-MS; GD-OES; Lithium-Ion Battery
Themenfelder/Aktivitätsfelder der BAM:Energie
Energie / Elektrische Energiespeicher und -umwandlung
Veranstaltung:20th European Winter Conference on Plasma Spectrochemistry
Veranstaltungsort:Berlin, Germany
Beginndatum der Veranstaltung:02.03.2025
Enddatum der Veranstaltung:07.03.2025
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:01.04.2025
Referierte Publikation:Nein
Eingeladener Vortrag (wissenschaftliche Konferenzen):Nein
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