Safety related properties of low-GWP refrigerants

  • Most fluorinated hydrocarbons that shall replace refrigerants with high GWP, like R134a, are flammable. For evaluating inertization measures for explosion protection, flammability of low-GWP refrigerants R1234yf, R32 and R1132a blended with carbon dioxide, nitrogen and argon were studied experimentally in a closed autoclave at atmospheric conditions. Furthermore, a calculation method was adapted to reduce the experimental costs for flammability studies on these gas mixtures. For igniting R1234yf in the closed autoclave a newly developed ignition system was used that allows generating electric arcs with high ignition energy. Gas mixtures containing the mildly flammable R1234yf and R32 could be inerted by adding much less inert gas than mixtures containing R1132a, which is more similar to unfluorinated hydrocarbons regarding the explosion regions. By using the adapted model of constant adiabatic flame temperature profiles estimating the explosion limits of fluorinated hydrocarbons wasMost fluorinated hydrocarbons that shall replace refrigerants with high GWP, like R134a, are flammable. For evaluating inertization measures for explosion protection, flammability of low-GWP refrigerants R1234yf, R32 and R1132a blended with carbon dioxide, nitrogen and argon were studied experimentally in a closed autoclave at atmospheric conditions. Furthermore, a calculation method was adapted to reduce the experimental costs for flammability studies on these gas mixtures. For igniting R1234yf in the closed autoclave a newly developed ignition system was used that allows generating electric arcs with high ignition energy. Gas mixtures containing the mildly flammable R1234yf and R32 could be inerted by adding much less inert gas than mixtures containing R1132a, which is more similar to unfluorinated hydrocarbons regarding the explosion regions. By using the adapted model of constant adiabatic flame temperature profiles estimating the explosion limits of fluorinated hydrocarbons was possible with similar accuracy as for unfluorinated hydrocarbons. Keywords: Explosion Protection, Inertization, Flammability, HFOs, HFC., R1234yf, R32, R1132azeige mehrzeige weniger

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Autor*innen:Enis AskarORCiD, Volkmar Schröder, T. Göpfert, E. Winterleitner, M. Schwarze
Dokumenttyp:Beitrag zu einem Tagungsband
Veröffentlichungsform:Graue Literatur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Proceedings of the 25th IIR International Congress of Refrigeration
Jahr der Erstveröffentlichung:2019
Organisationseinheit der BAM:2 Prozess- und Anlagensicherheit
2 Prozess- und Anlagensicherheit / 2.1 Sicherheit von Energieträgern
Erste Seite:1
Letzte Seite:9
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurbau
Freie Schlagwörter:Explosion Protection; Flammability; HFC; HFOs; Inertization; R1132a; R1234yf; R32
Themenfelder/Aktivitätsfelder der BAM:Infrastruktur
Veranstaltung:25th IIR Internationa Congress of Refrigeration
Veranstaltungsort:Montreal, Canada
Beginndatum der Veranstaltung:24.08.2019
Enddatum der Veranstaltung:30.08.2019
DOI:10.18462/iir.icr.2019.0767
ISSN:1025-9031
ISBN:978-2-36215-035-7
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:18.11.2019
Referierte Publikation:Nein
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