Plasma reheating in LIBS with electric discharge to detect halogens in low concentrations
- The Laser-induced Breakdown Spectroscopy (LIBS) is an useful analytical technique for the chlorine detection in building materials, specifically in the reinforcement concrete. If chlorine exceeds a specific concentration threshold, the result can be pitting corrosion of the reinforcement, which affects the stability and lifetime of building structures like marine constructions, bridges or parking decks. The critical chlorine content based to cement is 0.4 wt.-% based to the cement for reinforced concrete. The ingress of chlorides from sea water or de-icing salt leads to corrosion of the reinforcement. The chlorine spectral line Cl I at 837.59 nm shows a good performance in helium atmosphere. For measurements without helium we used a electric discharge setup to reheat the Laser-induced plasma with a voltage below 100 V. In this case the reheating shows an increasing chlorine emission in air atmosphere. This work shows chlorine calibration curves with LIBS in a helium flow and LIBSThe Laser-induced Breakdown Spectroscopy (LIBS) is an useful analytical technique for the chlorine detection in building materials, specifically in the reinforcement concrete. If chlorine exceeds a specific concentration threshold, the result can be pitting corrosion of the reinforcement, which affects the stability and lifetime of building structures like marine constructions, bridges or parking decks. The critical chlorine content based to cement is 0.4 wt.-% based to the cement for reinforced concrete. The ingress of chlorides from sea water or de-icing salt leads to corrosion of the reinforcement. The chlorine spectral line Cl I at 837.59 nm shows a good performance in helium atmosphere. For measurements without helium we used a electric discharge setup to reheat the Laser-induced plasma with a voltage below 100 V. In this case the reheating shows an increasing chlorine emission in air atmosphere. This work shows chlorine calibration curves with LIBS in a helium flow and LIBS with electric discharge reheating in air atmosphere. The determination of the limit of detection (LOD) for both setups and the measurement results of a drill core sample with a quantitative chlorine ingress profile will be presented.…
Autor*innen: | Tobias Günther |
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Koautor*innen: | Cassian Gottlieb, Tobias Völker, Steven Millar, Gerd Wilsch |
Dokumenttyp: | Vortrag |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2018 |
Organisationseinheit der BAM: | 8 Zerstörungsfreie Prüfung |
8 Zerstörungsfreie Prüfung / 8.2 Zerstörungsfreie Prüfmethoden für das Bauwesen | |
DDC-Klassifikation: | Naturwissenschaften und Mathematik / Chemie / Analytische Chemie |
Freie Schlagwörter: | Electric discharge; LIBS; Laser induced plasma; Plasma reheating |
Themenfelder/Aktivitätsfelder der BAM: | Chemie und Prozesstechnik |
Veranstaltung: | Xth international conference on Laser-Induced Breakdown Spectroscopy |
Veranstaltungsort: | Atlanta, GA, USA |
Beginndatum der Veranstaltung: | 21.10.2018 |
Enddatum der Veranstaltung: | 26.10.2018 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 03.12.2018 |
Referierte Publikation: | Nein |
Eingeladener Vortrag: | Nein |