Developments Towards a fluorometric sensing device for multiple hazardous gases

  • Fluorometric sensing is a versatile approach for trace analysis outside of the laboratory, requiring suitable sensor materials and their integration into sensing devices. The versatility of fluorophores as probes, especially in terms of the possibility to tailor their optical as well as their recognition properties by synthetic modifications in a wide range, renders them as superior active component for the preparation of optical sensor devices. Recent works at BAM in this field include, for example, the detection of nerve gas agents,illustrating impressively the aforementioned benefits of fluorophores in optical sensing applications. In the interdisciplinary approach presented here, we target hazardous gases such as ammonia, benzene, and hydrogen sulfide, next to others, which pose a major threat to human health and environmental safety and for which the availability of a sensitive and reliable detection method is highly desirable. The dyes presented follow a “turn-on” fluorescenceFluorometric sensing is a versatile approach for trace analysis outside of the laboratory, requiring suitable sensor materials and their integration into sensing devices. The versatility of fluorophores as probes, especially in terms of the possibility to tailor their optical as well as their recognition properties by synthetic modifications in a wide range, renders them as superior active component for the preparation of optical sensor devices. Recent works at BAM in this field include, for example, the detection of nerve gas agents,illustrating impressively the aforementioned benefits of fluorophores in optical sensing applications. In the interdisciplinary approach presented here, we target hazardous gases such as ammonia, benzene, and hydrogen sulfide, next to others, which pose a major threat to human health and environmental safety and for which the availability of a sensitive and reliable detection method is highly desirable. The dyes presented follow a “turn-on” fluorescence schematic, which allows for the selective and sensitive detection of the respective gaseous analyte. The immobilization of the probe in polymeric matrices is then the next step toward the fabrication of a prototype device for molecular sensing. Further steps in the project include the assembly of instruments for test-atmosphere generation, the referencing of the sensor system, development and implementation of an optical setup, and the testing of the prototype device under laboratory conditions and in the field. In this presentation, we give an overview over the recent developments on this topic in our groups, including fluorophore designs investigated for the detection of benzene, ammonia, and hydrogen sulfide as well as approaches for the design of the sensing device.zeige mehrzeige weniger

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Metadaten
Autor*innen:Jürgen Bartelmeß
Koautor*innen:Kornelia Gawlitza, Carlo Tiebe, Matthias Bartholmai, Knut Rurack
Dokumenttyp:Vortrag
Veröffentlichungsform:Präsentation
Sprache:Englisch
Jahr der Erstveröffentlichung:2018
Organisationseinheit der BAM:1 Analytische Chemie; Referenzmaterialien
1 Analytische Chemie; Referenzmaterialien / 1.9 Chemische und optische Sensorik
8 Zerstörungsfreie Prüfung
8 Zerstörungsfreie Prüfung / 8.1 Sensorik, mess- und prüftechnische Verfahren
DDC-Klassifikation:Naturwissenschaften und Mathematik / Chemie / Analytische Chemie
Freie Schlagwörter:BODIPY dye; Fluorometric sensing; Gas sensor
Themenfelder/Aktivitätsfelder der BAM:Chemie und Prozesstechnik
Umwelt
Umwelt / Sensorik
Veranstaltung:EUROPT(R)ODE XIV
Veranstaltungsort:Neapel, Italy
Beginndatum der Veranstaltung:25.03.2018
Enddatum der Veranstaltung:28.03.2018
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:06.08.2018
Referierte Publikation:Nein
Eingeladener Vortrag:Nein
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