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Multifunctional persistent luminescent and photochromic hackmanite-based materials prepared by microwave-assisted solid-state synthesis

  • Advanced optical materials inspired by natural minerals and non-toxic light elements, such as the Hackmanites (Na8Al6Si6O24(Cl,S)2), find vast possibilities of applications as they can simultaneously perform photochromism and persistent luminescence (PersL). In this work, we have explored a rapid and energy-efficient microwaveassisted (MASS) methodology for the synthesis of PersL and photochromic hackmanites. In addition, we have prepared hackmanite materials using a zeolite-free precursor to control the Na–Al–Si ratio and study its influence on the materials photoluminescent properties. The PersL hackmanites showed a white-bluish emission color, with up to 2 h of emission time. Zeolite-free photochromic materials were able to change the color from white to purple/blue efficiently with a few seconds of 254 nm excitation, but the usage of zeolite precursors enhanced the overall optical performance. Microwave synthesis times of 10–40 min were demonstrated to be optimal, as longer timesAdvanced optical materials inspired by natural minerals and non-toxic light elements, such as the Hackmanites (Na8Al6Si6O24(Cl,S)2), find vast possibilities of applications as they can simultaneously perform photochromism and persistent luminescence (PersL). In this work, we have explored a rapid and energy-efficient microwaveassisted (MASS) methodology for the synthesis of PersL and photochromic hackmanites. In addition, we have prepared hackmanite materials using a zeolite-free precursor to control the Na–Al–Si ratio and study its influence on the materials photoluminescent properties. The PersL hackmanites showed a white-bluish emission color, with up to 2 h of emission time. Zeolite-free photochromic materials were able to change the color from white to purple/blue efficiently with a few seconds of 254 nm excitation, but the usage of zeolite precursors enhanced the overall optical performance. Microwave synthesis times of 10–40 min were demonstrated to be optimal, as longer times boosted the formation of nepheline spurious phase, which decreases luminescence efficiency. In this way, the MASS method led to a reduction of reaction time up to 98 %, yielding hackmanite materials with similar photoluminescent or photochromic properties compared to those obtained by a 24 h conventional solid-state synthesis. This work represents a significant improvement toward coupling eco-friendly synthetic processes to eco-friendly solid-state materials for PersL illumination and PersL/photochromism optical marking.zeige mehrzeige weniger

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Autor*innen:Leonnam Gotardo MerízioORCiD, Ian Pompermayer MachadoORCiD, Roosa VastamäkiORCiD, Andréa Simone Stucchi de CamargoORCiD, Mika LastusaariORCiD
Dokumenttyp:Zeitschriftenartikel
Veröffentlichungsform:Verlagsliteratur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Optical Materials
Jahr der Erstveröffentlichung:2024
Organisationseinheit der BAM:5 Werkstofftechnik
5 Werkstofftechnik / 5.6 Glas
Verlag:Elsevier B.V.
Jahrgang/Band:155
Aufsatznummer:115826
Erste Seite:1
Letzte Seite:13
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten
Freie Schlagwörter:Hackmanite; Microwave-assisted synthesis; Persistent luminescence; Photochromism
Themenfelder/Aktivitätsfelder der BAM:Material
Material / Materialdesign
DOI:10.1016/j.optmat.2024.115826
ISSN:0925-3467
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:12.08.2024
Referierte Publikation:Ja
Datum der Eintragung als referierte Publikation:19.08.2024
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