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Hydrogen diffusion and desorption characteristics of a CoCrFeMnNi high entropy and a CoCrNi medium entropy alloy

  • High-entropy alloys (HEAs) are innovative high-performance materials that have attracted more and more research attention. HEAs are characterized by a solid solution of typically five equiatomic metallic elements. In addition, medium-entropy alloys (MEA, with three elements) are of interest and become more and more important. Depending on the alloy concept, HEAs and MEAs show exceptional mechanical properties, especially high-strength and ductility combinations at both cryogenic and elevated temperatures combined with excellent corrosion resistance. Future structural HEA/MEA components can be exposed to potential applications with hydrogen containing environments like high-temperature water in pressurized nuclear reactors or aerospace structures. Other potential applications could be in materials for vessel walls in the field of cryogenic and high-pressure hydrogen storage. So far, the susceptibility of HEAs/MEAs to hydrogen assisted cracking (if any) and the hydrogen diffusion is notHigh-entropy alloys (HEAs) are innovative high-performance materials that have attracted more and more research attention. HEAs are characterized by a solid solution of typically five equiatomic metallic elements. In addition, medium-entropy alloys (MEA, with three elements) are of interest and become more and more important. Depending on the alloy concept, HEAs and MEAs show exceptional mechanical properties, especially high-strength and ductility combinations at both cryogenic and elevated temperatures combined with excellent corrosion resistance. Future structural HEA/MEA components can be exposed to potential applications with hydrogen containing environments like high-temperature water in pressurized nuclear reactors or aerospace structures. Other potential applications could be in materials for vessel walls in the field of cryogenic and high-pressure hydrogen storage. So far, the susceptibility of HEAs/MEAs to hydrogen assisted cracking (if any) and the hydrogen diffusion is not investigated in detail yet and can limit or extend possible applications of HEA/MEA as structural materials. In our work, we focused on the hydrogen absorption, diffusion, and distribution in a HEA (CoCrFeMnNi the original Cantor-alloy) and a MEA (CoCrNi). Cathodic hydrogen charging was carried out for the hydrogen ingress, and thermal desorption analysis (TDA) revealed complex hydrogen trapping in both alloy types up to 300 °C. The absorbed total hydrogen concentrations were > 100 ppm for the HEA and > 40 ppm for MEA. In addition, the assessment of the peak deconvolution is not trivial and must consider both experimental and microstructure influences.zeige mehrzeige weniger

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Autor*innen:Michael RhodeORCiD, Jonathan Nietzke, Tim Richter
Dokumenttyp:Beitrag zu einem Tagungsband
Veröffentlichungsform:Graue Literatur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Proceedings of the Fourth International Conference on Metals & Hydrogen
Jahr der Erstveröffentlichung:2022
Organisationseinheit der BAM:9 Komponentensicherheit
9 Komponentensicherheit / 9.0 Abteilungsleitung und andere
9 Komponentensicherheit / 9.2 Versuchsanlagen und Prüftechnik
Herausgeber (Institution):OCAS
Verlagsort:Ghent, Belgium
Aufsatznummer:H03
Erste Seite:1
Letzte Seite:11
DDC-Klassifikation:Naturwissenschaften und Mathematik / Chemie / Analytische Chemie
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik
Freie Schlagwörter:Diffusion; High-entropy alloy; Hydrogen; Multiple principal element alloy; Thermal desorption analysis
Themenfelder/Aktivitätsfelder der BAM:Chemie und Prozesstechnik
Energie
Energie / Wasserstoff
Material
Material / Degradation von Werkstoffen
Material / Materialdesign
Veranstaltung:4th International Conference on Metals and Hydrogen - Steely & Hydrogen 2022
Veranstaltungsort:Ghent, Belgium
Beginndatum der Veranstaltung:11.10.2022
Enddatum der Veranstaltung:13.10.2022
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:24.10.2022
Referierte Publikation:Nein
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