Direkt in-situ analysis of milling reactions: a look in the blackbox
- Mechanochemistry is increasingly used for synthesizing various materials. Although this synthesis approach offers a fast and pure synthesis in high yields, there is a lack in understanding the mechanisms of milling reactions. The necessary data can only be obtained by in situ experiments, which were only recently established for milling reactions. Herein, we present a novel setup combining in situ synchrotron XRD and Raman spectroscopy. This combination allows to study milling processes comprehensively on the level of the molecular and crystalline structure and thus obtaining reliable data for mechanistic studies. The formation process of MOFs, metal phosphonates and model cocrystals could be studied in detail. The results prove that the presented method combination is applicable for a wide range of materials and will provide the necessary understanding to tune and optimize mechanochemically synthesized compounds.
Autor*innen: | Anke Kabelitz |
---|---|
Koautor*innen: | Manuel Wilke, Franiska Fischer, Hannes Kulla, Lisa Batzdorf, Klaus-Jürgen Wenzel, Franziska EmmerlingORCiD |
Dokumenttyp: | Vortrag |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2016 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Freie Schlagwörter: | In situ; Mechanistic studies; Mechanochemistry |
Veranstaltung: | MS&T 2016: Mechanochemical Synthesis and Reactions in Materials Science |
Veranstaltungsort: | Salt Lake City, USA |
Beginndatum der Veranstaltung: | 24.10.2016 |
Enddatum der Veranstaltung: | 27.10.2016 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 10.11.2016 |
Referierte Publikation: | Nein |
Eingeladener Vortrag: | Nein |