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Cement hydration mechanisms through time – a review
- In this article the progress of the research on cement hydration mechanisms is critically reviewed, starting with the work of Le Chatelier and Michaelis during the late 19th century. Proposed mechanisms are discussed in the light of experimental data to highlight the role of new or improved analytical techniques. The focus of this article lies on the dormant period and the silicate reaction. Today many of the mechanisms proposed throughout time cannot withstand experimental evidence and need to be rejected, including the classical protective hydrate layer theory. However, it seems likely that hydrated surface species are involved in the mechanism. Theories that aim to explain the rate changes solely based on the nucleation and growth of portlandite can also not withstand experimental evidence. Nevertheless, the retardation of portlandite crystal growth through silicate ions is a relevant factor. Especially since it might present a mechanism for the nucleation of calcium silicateIn this article the progress of the research on cement hydration mechanisms is critically reviewed, starting with the work of Le Chatelier and Michaelis during the late 19th century. Proposed mechanisms are discussed in the light of experimental data to highlight the role of new or improved analytical techniques. The focus of this article lies on the dormant period and the silicate reaction. Today many of the mechanisms proposed throughout time cannot withstand experimental evidence and need to be rejected, including the classical protective hydrate layer theory. However, it seems likely that hydrated surface species are involved in the mechanism. Theories that aim to explain the rate changes solely based on the nucleation and growth of portlandite can also not withstand experimental evidence. Nevertheless, the retardation of portlandite crystal growth through silicate ions is a relevant factor. Especially since it might present a mechanism for the nucleation of calcium silicate hydrate (C-S-H), backing up theories that propose C-S-H and portlandite to grow from the same nuclei. Finally, an overview over facts, that are currently considered to be valid and hence need to be regarded in future mechanisms is given.…
Autor*innen: | Elisabeth JohnORCiD, Barbara Lothenbach |
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Persönliche Herausgeber*innen: | C. B. Carter |
Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Journal of Materials Science |
Jahr der Erstveröffentlichung: | 2023 |
Organisationseinheit der BAM: | 6 Materialchemie |
6 Materialchemie / 6.1 Oberflächen- und Dünnschichtanalyse | |
Veröffentlichende Institution: | Bundesanstalt für Materialforschung und -prüfung (BAM) |
Verlag: | Springer Science + Business Media B.V |
Verlagsort: | Dordrecht [u.a.] |
Jahrgang/Band: | 58 |
Ausgabe/Heft: | 24 |
Erste Seite: | 9805 |
Letzte Seite: | 9833 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Freie Schlagwörter: | Calcium silicate hydrate; Cement hydration |
Themenfelder/Aktivitätsfelder der BAM: | Material |
DOI: | 10.1007/s10853-023-08651-9 |
URN: | urn:nbn:de:kobv:b43-577460 |
ISSN: | 1573-4803 |
Verfügbarkeit des Dokuments: | Datei für die Öffentlichkeit verfügbar ("Open Access") |
Lizenz (Deutsch): | Creative Commons - CC BY - Namensnennung 4.0 International |
Datum der Freischaltung: | 22.06.2023 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 22.06.2023 |
Schriftenreihen ohne Nummerierung: | Wissenschaftliche Artikel der BAM |