Mixing Reactions Enable Green Synthesis of ZIF-8 at Large Scale: Batch and Continuous Modes
- We report the scale-up of a batch solid synthesis of zeolitic imidazolate framework-8 (ZIF-8) for reactive extrusion. The crystalline product forms in the extruder directly under the mixture of solid 2-methylimidazole and basic zinc carbonate in the presence of a catalytic amount of liquid. The process parameters such as temperature, liquid type, feeding rate, and linker excess were optimized using the setup specifically designed for in situ Raman spectroscopy. Highly crystalline ZIF-8 with a Brunauer–Emmett–Teller (BET) surface area of 1816 m2 g–1 was quantitatively prepared at mild temperature using a catalytic amount of ethanol and a small excess of the linker. Finally, we developed a simple and comprehensive approach to evaluating the environmental friendliness and scalability of metal–organic framework (MOF) syntheses in view of their large-scale production.
Autor*innen: | Nikita Gugin |
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Weitere Person: | José Antonio Villajos ColladoORCiD, Michael MaiwaldORCiD, Franziska Emmerling |
Dokumenttyp: | Posterpräsentation |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2023 |
Organisationseinheit der BAM: | 1 Analytische Chemie; Referenzmaterialien |
1 Analytische Chemie; Referenzmaterialien / 1.4 Prozessanalytik | |
6 Materialchemie | |
6 Materialchemie / 6.3 Strukturanalytik | |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Freie Schlagwörter: | Green chemistry; Large-scale production; MOFs; Mechanochemistry; Reactive extrusion; Zeolitic imidazolate framework |
Themenfelder/Aktivitätsfelder der BAM: | Material |
Material / Materialdesign | |
Veranstaltung: | 2023 #RSCPoster Twitter Conference |
Veranstaltungsort: | Online meeting |
Beginndatum der Veranstaltung: | 28.02.2023 |
URL: | https://twitter.com/NikitaGugin/status/1630538555675099139 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 30.11.2023 |
Referierte Publikation: | Nein |