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Pore Solution composition of GGBFS-containing cement pastes

  • Ground Granulated Blast-Furnace Slag (GGBFS), a by-product of the iron-making process, has gained significant attention as a supplementary cementitious material and has become increasingly popular in recent years due to its remarkable properties. GGBFS can significantly reduce the environmental impact of cement production when it comes to building concrete structures. GGBFS can either be blended with ordinary Portland cement (OPC) (up to a 90% replacement), or it can be used in the production of alkali-activated materials (AAMs). However, a comprehensive understanding of the pore solution composition is necessary for understanding various aspects of cementitious materials and their durability, including corrosion behavior, passivation of steel, and resistance to deteriorative processes. In the present work, the pore solutions of seven different GGBFS-containing cements (alkali-activated slag, alkali-activated slag/fly ash blends, a hybrid alkaline cement, CEM III/C, and CEM III/B) wereGround Granulated Blast-Furnace Slag (GGBFS), a by-product of the iron-making process, has gained significant attention as a supplementary cementitious material and has become increasingly popular in recent years due to its remarkable properties. GGBFS can significantly reduce the environmental impact of cement production when it comes to building concrete structures. GGBFS can either be blended with ordinary Portland cement (OPC) (up to a 90% replacement), or it can be used in the production of alkali-activated materials (AAMs). However, a comprehensive understanding of the pore solution composition is necessary for understanding various aspects of cementitious materials and their durability, including corrosion behavior, passivation of steel, and resistance to deteriorative processes. In the present work, the pore solutions of seven different GGBFS-containing cements (alkali-activated slag, alkali-activated slag/fly ash blends, a hybrid alkaline cement, CEM III/C, and CEM III/B) were extracted and analysed by inductively coupled plasma-optical emission spectroscopy, ion chromatography, pH, redox potential, and conductivity measurements. For comparison, a Portland cement pore solution was analysed similarly. The Concentrations of reduced sulfur were noteworthy in all GGBFS-containing cements, particularly in alkali-activated cements, where concentrations were notably higher compared to standard cements. The redox potentials of the pore solutions were primarily dictated by the concentrations of reduced sulfur, although other factors may contribute. Additionally, sulfur species in the pore solutions had an impact on pH, electrical conductivity, and other properties pertinent to the corrosion of reinforcements.zeige mehrzeige weniger

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Metadaten
Autor*innen:Ali Nikoonasab, M. Licht, L. Weiler, R. Achenbach, M. Raupach, Gregor Gluth
Dokumenttyp:Vortrag
Veröffentlichungsform:Präsentation
Sprache:Englisch
Jahr der Erstveröffentlichung:2024
Organisationseinheit der BAM:7 Bauwerkssicherheit
7 Bauwerkssicherheit / 7.4 Baustofftechnologie
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten
Freie Schlagwörter:AAM; GGBFS; Pore solution composition; Redox potential; Sulfide
Themenfelder/Aktivitätsfelder der BAM:Material
Material / Degradation von Werkstoffen
Veranstaltung:RILEM Spring Convention 2024 & Conference on Advanced Construction Materials and Processes for a Carbon Neutral Society
Veranstaltungsort:Milan, Italy
Beginndatum der Veranstaltung:10.04.2024
Enddatum der Veranstaltung:12.04.2024
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:02.05.2024
Referierte Publikation:Nein
Eingeladener Vortrag:Nein
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