Structure-properties relationships in cadmium benzylphosphonates
- The exploration of metal phosphonates has gained great interest during the last decades, because of their structural diversity. They are promising candidates for a variety of applications ranging from adsorbance to electrocatalysis. The knowledge of the Crystal structure is significant for assigning a coordination polymer for a specific function. We investigated the influence of the fluorination degree of the organic linker on the Crystal packing, the interlayer distance, and the hydrophobicity of the resulting compounds. With fluorinated and nonfluorinated benzylphosphonic acids as starting materials in mechanochemical synthesis, four novel cadmium benzylphosphonates were obtained. Their structures were solved from powder X-ray diffraction.
Autor*innen: | Irina Akhmetova |
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Weitere Person: | C. Roth, Franziska EmmerlingORCiD |
Dokumenttyp: | Posterpräsentation |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2019 |
Organisationseinheit der BAM: | 6 Materialchemie |
6 Materialchemie / 6.3 Strukturanalytik | |
DDC-Klassifikation: | Naturwissenschaften und Mathematik / Chemie / Analytische Chemie |
Freie Schlagwörter: | DVS; Mechanochemistry; Metal phosphonates; PXRD |
Themenfelder/Aktivitätsfelder der BAM: | Chemie und Prozesstechnik |
Veranstaltung: | 2nd European Workshop on Metal Phosphonates |
Veranstaltungsort: | Berlin, Germany |
Beginndatum der Veranstaltung: | 24.09.2019 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 09.12.2019 |
Referierte Publikation: | Nein |