Zitieren Sie bitte immer diesen URN: urn:nbn:de:kobv:b43-472023
High-throughput fire tests and weathering-induced degradation behaviour of intumescent coatings
- In this work, the weathering-induced degradation of intumescent coatings was investigated by a systematic and comprehensive approach. A mechanism is revealed that is proposed to be responsible for the loss of function of intumescent coatings induced by weathering. First, the thermal decomposition of artificially weathered intumescent coatings was examined. To get a better understanding of the weathering and ageing phenomena, the degradation behaviour of the single ingredients during the weathering process was investigated, as well as their chemical and physical interactions. For the systematic approach, the materials that are essential for intumescence (ammonium polyphosphate, pentaerythritol, titanium dioxide, melamine and the binder) are treated with moisture, elevated temperature and UV radiation. Thermogravimetry (TG) and IR spectroscopy were used to compare the initial samples with their different grades of weathering. We demonstrate that ammonium polyphosphate, melamine andIn this work, the weathering-induced degradation of intumescent coatings was investigated by a systematic and comprehensive approach. A mechanism is revealed that is proposed to be responsible for the loss of function of intumescent coatings induced by weathering. First, the thermal decomposition of artificially weathered intumescent coatings was examined. To get a better understanding of the weathering and ageing phenomena, the degradation behaviour of the single ingredients during the weathering process was investigated, as well as their chemical and physical interactions. For the systematic approach, the materials that are essential for intumescence (ammonium polyphosphate, pentaerythritol, titanium dioxide, melamine and the binder) are treated with moisture, elevated temperature and UV radiation. Thermogravimetry (TG) and IR spectroscopy were used to compare the initial samples with their different grades of weathering. We demonstrate that ammonium polyphosphate, melamine and the binder are mainly responsible for the ageing process. Further, it was demonstrated that TG and IR spectroscopy are suitable measuring methods to detect the effects of weathering on intumescent coatings. Finally, a small-scale fire test procedure is introduced. Based on the reduction of the sample size, up to 50 samples can be tested in a single fire test. The results of this fire test have the same quality as the results from standard intermediate fire tests corresponding to DIN 4102-8.…
Autor*innen: | Lars-Hendrik Daus, Manfred Korzen, Bernhard SchartelORCiD |
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Dokumenttyp: | Beitrag zu einem Tagungsband |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Journal of Physics: Conference Series (JPCS) |
Jahr der Erstveröffentlichung: | 2018 |
Organisationseinheit der BAM: | 7 Bauwerkssicherheit |
7 Bauwerkssicherheit / 7.3 Brandingenieurwesen | |
7 Bauwerkssicherheit / 7.5 Technische Eigenschaften von Polymerwerkstoffen | |
Veröffentlichende Institution: | Bundesanstalt für Materialforschung und -prüfung (BAM) |
Verlag: | IOP Publishing |
Verlagsort: | Bristol |
Jahrgang/Band: | 1107 |
Erste Seite: | 032014 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurbau |
Freie Schlagwörter: | High-Throughput Fire Tests; Intumescent coatings; Weathering |
Themenfelder/Aktivitätsfelder der BAM: | Infrastruktur |
Infrastruktur / Fire Science | |
Veranstaltung: | 3rd European Symposium on Fire Safety Science |
Veranstaltungsort: | Nancy, France |
Beginndatum der Veranstaltung: | 12.09.1018 |
Enddatum der Veranstaltung: | 14.09.2018 |
DOI: | 10.1088/1742-6596/1107/3/032014 |
URN: | urn:nbn:de:kobv:b43-472023 |
URL: | http://iopscience.iop.org/article/10.1088/1742-6596/1107/3/032014/pdf |
Verfügbarkeit des Dokuments: | Datei für die Öffentlichkeit verfügbar ("Open Access") |
Lizenz (Deutsch): | Creative Commons - Namensnennung |
Datum der Freischaltung: | 21.01.2019 |
Referierte Publikation: | Nein |
Schriftenreihen ohne Nummerierung: | Wissenschaftliche Artikel der BAM |