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Evaluation of UV-induced embrittlement of PE-HD by Charpy impact test
- The impact fracture behavior of two common high-density polyethylene grades for container applications were intensively studied by the instrumented Charpy impact test after well-defined exposure to UV-irradiation. Individual stages of the impact event, such as crack initiation and crack propagation energy as well as maximum impact load, were investigated from the recorded load–deflection curves. UV-induced material property changes were further investigated by infrared spectroscopy, differential scanning calorimetry, and dynamic-mechanical analysis as well as density measurements. Based on the results of the Charpy impact test, three indicators were identified to describe the extend of photooxidation on high-density polyethylene: (a) a reduced Charpy impact strength—at least to half of its initial value for a distinctly brittle impact fracture, (b) a marked decrease in the crack propagation contribution to the impact strength, and (c) an increase of the brittle features of the fractureThe impact fracture behavior of two common high-density polyethylene grades for container applications were intensively studied by the instrumented Charpy impact test after well-defined exposure to UV-irradiation. Individual stages of the impact event, such as crack initiation and crack propagation energy as well as maximum impact load, were investigated from the recorded load–deflection curves. UV-induced material property changes were further investigated by infrared spectroscopy, differential scanning calorimetry, and dynamic-mechanical analysis as well as density measurements. Based on the results of the Charpy impact test, three indicators were identified to describe the extend of photooxidation on high-density polyethylene: (a) a reduced Charpy impact strength—at least to half of its initial value for a distinctly brittle impact fracture, (b) a marked decrease in the crack propagation contribution to the impact strength, and (c) an increase of the brittle features of the fracture surface.…
Autor*innen: | Maren Erdmann, Ute Niebergall, Volker WachtendorfORCiD, Martin BöhningORCiD |
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Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Journal of Applied Polymer Science |
Jahr der Erstveröffentlichung: | 2020 |
Organisationseinheit der BAM: | 5 Werkstofftechnik |
5 Werkstofftechnik / 5.3 Polymere Verbundwerkstoffe | |
7 Bauwerkssicherheit | |
7 Bauwerkssicherheit / 7.5 Technische Eigenschaften von Polymerwerkstoffen | |
Veröffentlichende Institution: | Bundesanstalt für Materialforschung und -prüfung (BAM) |
Verlag: | Wiley |
Jahrgang/Band: | 137 |
Ausgabe/Heft: | 36 |
Erste Seite: | 49069 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Freie Schlagwörter: | Degradation; Mechanical properties; Packaging; Polyethylene; Polyolefins |
Themenfelder/Aktivitätsfelder der BAM: | Material |
Material / Degradation von Werkstoffen | |
DOI: | 10.1002/APP.49069 |
URN: | urn:nbn:de:kobv:b43-509130 |
ISSN: | 0021-8995 |
Verfügbarkeit des Dokuments: | Datei für die Öffentlichkeit verfügbar ("Open Access") |
Lizenz (Deutsch): | Creative Commons - CC BY - Namensnennung 4.0 International |
Datum der Freischaltung: | 22.06.2020 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 22.06.2020 |
Schriftenreihen ohne Nummerierung: | Wissenschaftliche Artikel der BAM |