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Diesel-induced transparency of plastically deformed high-density polyethylene

  • High-density polyethylene becomes optically transparent during tensile drawing when previously saturated with diesel fuel. This unusual phenomenon is investigated as it might allow conclusions with respect to the material behavior. Microscopy, differential scanning calorimetry, density measurements are applied together with two scanning X-ray scattering techniques: wide angle X-ray scattering (WAXS) and X-ray refraction, able to extract the spatially resolved crystal orientation and internal surface, respectively. The sorbed diesel softens the material and significantly alters the yielding characteristics. Although the crystallinity among stretched regions is similar, a virgin reference sample exhibits strain whitening during stretching, while the diesel-saturated sample becomes transparent. The WAXS results reveal a pronounced fiber texture in the tensile direction in the stretched region and an isotropic orientation in the unstretched region. This texture implies the formation ofHigh-density polyethylene becomes optically transparent during tensile drawing when previously saturated with diesel fuel. This unusual phenomenon is investigated as it might allow conclusions with respect to the material behavior. Microscopy, differential scanning calorimetry, density measurements are applied together with two scanning X-ray scattering techniques: wide angle X-ray scattering (WAXS) and X-ray refraction, able to extract the spatially resolved crystal orientation and internal surface, respectively. The sorbed diesel softens the material and significantly alters the yielding characteristics. Although the crystallinity among stretched regions is similar, a virgin reference sample exhibits strain whitening during stretching, while the diesel-saturated sample becomes transparent. The WAXS results reveal a pronounced fiber texture in the tensile direction in the stretched region and an isotropic orientation in the unstretched region. This texture implies the formation of fibrils in the stretched region, while spherulites remain intact in the unstretched parts of the specimens. X-ray refraction reveals a preferred orientation of internal surfaces along the tensile direction in the stretched region of virgin samples, while the sample stretched in the diesel-saturated state shows no internal surfaces at all. Besides from stretching saturated samples, optical transparency is also obtained from sorbing samples in diesel after stretching.zeige mehrzeige weniger

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Metadaten
Autor*innen:Maren Erdmann, Andreas KupschORCiD, Bernd R. MüllerORCiD, Manfred P. Hentschel, Ute Niebergall, Martin BöhningORCiD, Giovanni BrunoORCiD
Persönliche Herausgeber*innen:Maren Erdmann
Dokumenttyp:Zeitschriftenartikel
Veröffentlichungsform:Verlagsliteratur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Journal of Materials Science
Jahr der Erstveröffentlichung:2019
Organisationseinheit der BAM:5 Werkstofftechnik
5 Werkstofftechnik / 5.3 Polymere Verbundwerkstoffe
7 Bauwerkssicherheit
7 Bauwerkssicherheit / 7.5 Technische Eigenschaften von Polymerwerkstoffen
8 Zerstörungsfreie Prüfung
8 Zerstörungsfreie Prüfung / 8.5 Röntgenbildgebung
Verlag:Springer US
Verlagsort:US
Jahrgang/Band:54
Ausgabe/Heft:17
Erste Seite:11739
Letzte Seite:11755
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik
Freie Schlagwörter:Cavitation; Crystal Texture; Diesel Fuel; Internal Surfaces; PE-HD Sorption; WAXS; X-ray refraction
Themenfelder/Aktivitätsfelder der BAM:Energie
Material
Material / Degradation von Werkstoffen
DOI:10.1007/s10853-019-03700-8
ISSN:1573-4803
ISSN:0022-2461
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:20.06.2019
Referierte Publikation:Ja
Datum der Eintragung als referierte Publikation:04.07.2019
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