Contaminant release from aged microplastic
- Recycled plastic granules of high-density polyethylene, polyvinyl chloride and polystyrene the size of microplastics were exposed to artificial aging conditions (2000 h; photooxidative and thermo-oxidative) to simulate their fate outdoors. Their potential to leach into water during the aging process was investigated using column percolation tests. Aging-related changes on the surface of the material were characterised by IR measurements indicating oxidation reactions with the formation of new adsorption bands (C=O, C–O and OH), especially in the case of photooxidative aging. These findings were confirmed by the identification of leachable organic compounds. Leaching of total organic carbon, Cl, Ca, Cu and Zn is clearly affected by changes due to aging, and their release is increased after photooxidative aging. In general, exposure to photooxidative conditions shows a greater influence on aging and thus on leaching and seems to be the more important mechanism for the aging ofRecycled plastic granules of high-density polyethylene, polyvinyl chloride and polystyrene the size of microplastics were exposed to artificial aging conditions (2000 h; photooxidative and thermo-oxidative) to simulate their fate outdoors. Their potential to leach into water during the aging process was investigated using column percolation tests. Aging-related changes on the surface of the material were characterised by IR measurements indicating oxidation reactions with the formation of new adsorption bands (C=O, C–O and OH), especially in the case of photooxidative aging. These findings were confirmed by the identification of leachable organic compounds. Leaching of total organic carbon, Cl, Ca, Cu and Zn is clearly affected by changes due to aging, and their release is increased after photooxidative aging. In general, exposure to photooxidative conditions shows a greater influence on aging and thus on leaching and seems to be the more important mechanism for the aging of microplastic in the environment. Comparison with the total content of inorganic species revealed that, for most elements, less than 3% of the total content is released after 2000 h of photooxidative aging.…
Autor*innen: | Nicole Bandow, Verena Will, Volker WachtendorfORCiD, Franz-Georg SimonORCiD |
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Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Environmental Chemistry |
Jahr der Erstveröffentlichung: | 2017 |
Jahrgang/Band: | 14 |
Ausgabe/Heft: | 6 |
Erste Seite: | 394 |
Letzte Seite: | 405 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Sanitär- und Kommunaltechnik; Umwelttechnik |
Freie Schlagwörter: | Column percolation tests; Heavy metals; Photo-oxidation; Thermo-oxidation |
DOI: | 10.1071/EN17064 |
ISSN: | 1448-2517 |
ISSN: | 1449-8979 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 01.12.2017 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 14.12.2017 |