Recovery of rare earth elements - optimized elemental analysis of fluorescent lamp shredder waste
- Rare earth elements (REE) are a crucial component of fluorescence lamps. Several procedures have been developed to recovery these technological important elements. Nevertheless, actual REE recycling from fluorescence lamps is scarce so far (recovery rate of less than 1 %), with current recycling approaches concentrating on glass recovery. Since most recycling processes include several, also wet-chemical steps, a complete knowledge of the actual elemental composition of the respective mass flows is necessary for an efficient REE recovery. We tested seven different reagent mixtures for microwave-assisted digestion of fluorescent lamp shredder, including HF, HClO4, and H2O2. We determined the concentrations of 25 of the most relevant rare earth and other trace elements in the respective dilutions. Two independent digestions, one a mixture of perchlorid/nitric/hydrofluoric acid and the other aqua regia, showed the highest concentrations of 23 of these elements, excluding only Sn and Tb.Rare earth elements (REE) are a crucial component of fluorescence lamps. Several procedures have been developed to recovery these technological important elements. Nevertheless, actual REE recycling from fluorescence lamps is scarce so far (recovery rate of less than 1 %), with current recycling approaches concentrating on glass recovery. Since most recycling processes include several, also wet-chemical steps, a complete knowledge of the actual elemental composition of the respective mass flows is necessary for an efficient REE recovery. We tested seven different reagent mixtures for microwave-assisted digestion of fluorescent lamp shredder, including HF, HClO4, and H2O2. We determined the concentrations of 25 of the most relevant rare earth and other trace elements in the respective dilutions. Two independent digestions, one a mixture of perchlorid/nitric/hydrofluoric acid and the other aqua regia, showed the highest concentrations of 23 of these elements, excluding only Sn and Tb. The REE concentrations in the tested lamp shredder sample (stated in g/kg) were 10.2 (Y), 12.1 (La), 7.77 (Ce), 6.91 (Eu), 1.90 (Gd), and 4.11 (Tb).…
Autor*innen: | Christian AdamORCiD, J. Hobohm, K. Kuchta, Sebastian van Wasen, Oliver Krüger |
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Dokumenttyp: | Beitrag zu einem Tagungsband |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Crete 2016 Conference Proceedings |
Jahr der Erstveröffentlichung: | 2016 |
Erste Seite: | 1 |
Letzte Seite: | 4 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Sanitär- und Kommunaltechnik; Umwelttechnik |
Freie Schlagwörter: | Critical raw materials; Rare earth elements; Resource recovery; WEEE |
Veranstaltung: | 5th International conference industrial and hazardous waste management - Crete 2016 |
Veranstaltungsort: | Chania, Crete, Greece |
Beginndatum der Veranstaltung: | 27.09.2016 |
Enddatum der Veranstaltung: | 30.09.2016 |
ISSN: | 2241-3138 |
ISBN: | 978-960-8475-20-5 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 13.10.2016 |
Referierte Publikation: | Nein |