Fluorescent molecularly imprinted polymer particles for detection of environmental contaminants
- Analysis of environmental contaminants such as pesticides is increasing in importance due to frequent detection of residues in water reserves and food stuff, as well as lowering of maximum residue levels (MRLs). Molecularly imprinted polymers (MIPs) have been developed for preconcentration of these analytes prior to analysis by chromatographic techniques. MIPs are prepared by polymerization of monomers in a matrix containing the analyte, followed by extraction of the analyte to obtain binding sites that are complementary to the analyte of interest. Recently, our group developed MIPs containing fluorescent reporter molecules that can be used for direct detection and quantification of 2,4-D in contaminated water. Core/shell MIP particles were employed, consisting of submicron silica nanoparticles coated with a MIP shell containing a fluorescent reporter whose signal was enhanced upon binding with 2,4-D in water. A limit of detection of 20 nM was attained. We present here a comparableAnalysis of environmental contaminants such as pesticides is increasing in importance due to frequent detection of residues in water reserves and food stuff, as well as lowering of maximum residue levels (MRLs). Molecularly imprinted polymers (MIPs) have been developed for preconcentration of these analytes prior to analysis by chromatographic techniques. MIPs are prepared by polymerization of monomers in a matrix containing the analyte, followed by extraction of the analyte to obtain binding sites that are complementary to the analyte of interest. Recently, our group developed MIPs containing fluorescent reporter molecules that can be used for direct detection and quantification of 2,4-D in contaminated water. Core/shell MIP particles were employed, consisting of submicron silica nanoparticles coated with a MIP shell containing a fluorescent reporter whose signal was enhanced upon binding with 2,4-D in water. A limit of detection of 20 nM was attained. We present here a comparable system, composed of fluorescent core-shell MIPs for the direct analysis of pesticides in environmental samples.…
Autor*innen: | Victor Pérez-PadillaORCiD |
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Koautor*innen: | Martha Wamaitha KimaniORCiD, Virginia Valderrey, Kornelia GawlitzaORCiD, Knut RurackORCiD |
Dokumenttyp: | Posterpräsentation |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2021 |
Organisationseinheit der BAM: | 1 Analytische Chemie; Referenzmaterialien |
1 Analytische Chemie; Referenzmaterialien / 1.9 Chemische und optische Sensorik | |
DDC-Klassifikation: | Naturwissenschaften und Mathematik / Chemie / Analytische Chemie |
Freie Schlagwörter: | Core-Shell Particles; Fluorescent Probes; Glyphosate; Guanidinium Receptors; Molecularly Imprinted Polymers |
Themenfelder/Aktivitätsfelder der BAM: | Umwelt |
Umwelt / Sensorik | |
Veranstaltung: | Europtrode 2021 |
Veranstaltungsort: | Warsaw, Poland |
Beginndatum der Veranstaltung: | 29.11.2021 |
Enddatum der Veranstaltung: | 01.12.2021 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 03.12.2021 |
Referierte Publikation: | Nein |