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Redefining stable isotope analysis by molecular absorption spectrometry

  • Variations in the isotope amount composition of some elements like lithium, boron, magnesium, calcium, copper and strontium have been used as proof of provenance of a sample and to describe geological processes. Routinely, isotope compositions are determinate by mass spectrometry; the working horse of the isotope analysis. However, mass spectrometric methods are expensive, time consuming and they require a high qualified analysist. Here an alternative faster and low cost optical method for isotope ratio determination is proposed: high-resolution continuum source molecular absorption spectrometry (HR-CS-MAS). Stable isotope amount composition of X= Li, B, Mg, Ca, Cu and Sr have been determined by monitoring the absorption spectrum of their monohydride (XH) in graphite furnace HR-CS-MAS. For example, for the three Mg isotopes (24Mg, 25Mg and 26Mg) band (0→0) for the electronic transition X1Σ+ → A1Π was evaluated around wavelength 513.4 nm (Fig. 1). Partial least square regressionVariations in the isotope amount composition of some elements like lithium, boron, magnesium, calcium, copper and strontium have been used as proof of provenance of a sample and to describe geological processes. Routinely, isotope compositions are determinate by mass spectrometry; the working horse of the isotope analysis. However, mass spectrometric methods are expensive, time consuming and they require a high qualified analysist. Here an alternative faster and low cost optical method for isotope ratio determination is proposed: high-resolution continuum source molecular absorption spectrometry (HR-CS-MAS). Stable isotope amount composition of X= Li, B, Mg, Ca, Cu and Sr have been determined by monitoring the absorption spectrum of their monohydride (XH) in graphite furnace HR-CS-MAS. For example, for the three Mg isotopes (24Mg, 25Mg and 26Mg) band (0→0) for the electronic transition X1Σ+ → A1Π was evaluated around wavelength 513.4 nm (Fig. 1). Partial least square regression (PLS) for analysis of samples and reference materials were applied. For this, a spectral library with different isotopes ratios for PLS regression were built. Results are metrological compatible with those reported by mass spectrometric methods.zeige mehrzeige weniger

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Metadaten
Autor*innen:Carlos Enrique Abad AndradeORCiD
Koautor*innen:S. Florek, H. Becker-Ross, M.-D. Huang, Hans-Joachim Heinrich, Sebastian Recknagel, Jochen Vogl, Norbert Jakubowski, Ulrich Panne
Dokumenttyp:Posterpräsentation
Veröffentlichungsform:Präsentation
Sprache:Englisch
Jahr der Erstveröffentlichung:2017
DDC-Klassifikation:Naturwissenschaften und Mathematik / Chemie / Analytische Chemie
Freie Schlagwörter:Graphite furnace; HR-CS-MAS; High-Resolution Continuum Source Molecular Absorption Spectrometry; Isotopes; Isotopic shift; Metal hydrides; Molecular absorption
Veranstaltung:Adlershofer Forschungsforum 2017
Veranstaltungsort:Berlin, Germany
Beginndatum der Veranstaltung:10.11.2017
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:07.12.2017
Referierte Publikation:Nein
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