Ultra-thin polymer layer deposition by aerosol-dielectric barrier discharge (DBD) and electrospray ionization (ESI) at atmospheric pressure
- Polyolefins are chemically inert and do not adhere well to metals, polymers or inorganics. To overcome this problem, polyolefin surfaces were modified thermally, plasmachemically, or by flame treatment with different oxygen-containing groups, however, unfortunately, such treatments were accompanied by undesired, adhesion lowering polymer degradation. To solve this dilemma, solutions of synthetic polymers and copolymers were prepared, sprayed into the barrier discharge or electrosprayed without discharge and deposited as thin adhesion-promoting layers. The deposited polymer layers from poly(vinylamine), poly(ethylene glycol)-poly(vinyl alcohol) copolymers and poly(acrylic acid) were endowed with monotype functional groups. Using the aerosol - dielectric barrier discharge only a fraction of functional groups survived the deposition process in contrast to the electrospray in which all functional groups were retained.
Autor*innen: | Jörg Florian Friedrich, Renate Mix, Rolf-Dieter Schulze, A. Rau |
---|---|
Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Journal of adhesion science and technology |
Jahr der Erstveröffentlichung: | 2010 |
Verlag: | VNU Science Press |
Verlagsort: | Utrecht |
Jahrgang/Band: | 24 |
Ausgabe/Heft: | 7 |
Erste Seite: | 1329 |
Letzte Seite: | 1350 |
Freie Schlagwörter: | Adhesion-promoting layers; Dielectric barrier discharge; Electrospray deposition; Polymer aerosols; Polymer surface modification |
DOI: | 10.1163/016942409X12598231568429 |
ISSN: | 0169-4243 |
ISSN: | 1568-5616 |
Verfügbarkeit des Dokuments: | Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access") |
Bibliotheksstandort: | Sonderstandort: Publica-Schrank |
Datum der Freischaltung: | 19.02.2016 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 07.06.2010 |