Determination of total sulfur in a metal matrix by ICP-IDMS: Example Cu matrix
- Previously on sulfur determination in metal revealed a lack of traceability and inconsistent results. Solving the problems a reference procedure for sulfur measurement in metal are required to build up a reliable reference value. In this study a procedure was developed for quantification of total sulfur at low concentration (in sub ppm level) in metal using inductively coupled plasma-isotope dilution mass spectrometry (ICP-IDMS). The ion exchange method and complexing agent were applied in this procedure to avoid loading large amount of metal into the instrument. Adding ammonia as a complexing agent into sample solution to reduce sulfur-metal co-elute. The procedure shows high performance and it is expressed in % recovery of sulfur (> 90%) and % metal elimination (>99 %). Additionally, relative measurement uncertainties were calculated less than 1.5 % and the results are traceable directly to SI units. This study would establish as reference procedure for sulfur measurement in metalPreviously on sulfur determination in metal revealed a lack of traceability and inconsistent results. Solving the problems a reference procedure for sulfur measurement in metal are required to build up a reliable reference value. In this study a procedure was developed for quantification of total sulfur at low concentration (in sub ppm level) in metal using inductively coupled plasma-isotope dilution mass spectrometry (ICP-IDMS). The ion exchange method and complexing agent were applied in this procedure to avoid loading large amount of metal into the instrument. Adding ammonia as a complexing agent into sample solution to reduce sulfur-metal co-elute. The procedure shows high performance and it is expressed in % recovery of sulfur (> 90%) and % metal elimination (>99 %). Additionally, relative measurement uncertainties were calculated less than 1.5 % and the results are traceable directly to SI units. This study would establish as reference procedure for sulfur measurement in metal sample which fit for these purpose as follows; for certified reference material and assigned value for inter-laboratory comparison.…
Autor*innen: | Pranee Phukphatthanachai |
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Koautor*innen: | Jochen Vogl, Norbert Jakubowski, Ulrich Panne |
Dokumenttyp: | Posterpräsentation |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2016 |
DDC-Klassifikation: | Naturwissenschaften und Mathematik / Chemie / Analytische Chemie |
Freie Schlagwörter: | IDMS; Purity assessment; Sulfur-matrix separatio |
Veranstaltung: | Anwendertreffen Plasmaspektrometrie 2016 |
Veranstaltungsort: | Berlin, Germany |
Beginndatum der Veranstaltung: | 22.02.2016 |
Enddatum der Veranstaltung: | 22.02.2016 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 02.05.2017 |
Referierte Publikation: | Nein |