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Diesel-induced transparency of plastically deformed high-density polyethylene
- High-density polyethylene becomes optically transparent during tensile drawing when previously saturated with diesel fuel. This unusual phenomenon is investigated as it might allow conclusions with respect to the material behavior. Microscopy, differential scanning calorimetry, density measurements are applied together with two scanning X-ray scattering techniques: wide angle X-ray scattering (WAXS) and X-ray refraction, able to extract the spatially resolved crystal orientation and internal surface, respectively. The sorbed diesel softens the material and significantly alters the yielding characteristics. Although the crystallinity among stretched regions is similar, a virgin reference sample exhibits strain whitening during stretching, while the diesel-saturated sample becomes transparent. The WAXS results reveal a pronounced fiber texture in the tensile direction in the stretched region and an isotropic orientation in the unstretched region. This texture implies the formation ofHigh-density polyethylene becomes optically transparent during tensile drawing when previously saturated with diesel fuel. This unusual phenomenon is investigated as it might allow conclusions with respect to the material behavior. Microscopy, differential scanning calorimetry, density measurements are applied together with two scanning X-ray scattering techniques: wide angle X-ray scattering (WAXS) and X-ray refraction, able to extract the spatially resolved crystal orientation and internal surface, respectively. The sorbed diesel softens the material and significantly alters the yielding characteristics. Although the crystallinity among stretched regions is similar, a virgin reference sample exhibits strain whitening during stretching, while the diesel-saturated sample becomes transparent. The WAXS results reveal a pronounced fiber texture in the tensile direction in the stretched region and an isotropic orientation in the unstretched region. This texture implies the formation of fibrils in the stretched region, while spherulites remain intact in the unstretched parts of the specimens. X-ray refraction reveals a preferred orientation of internal surfaces along the tensile direction in the stretched region of virgin samples, while the sample stretched in the diesel-saturated state shows no internal surfaces at all. Besides from stretching saturated samples, optical transparency is also obtained from sorbing samples in diesel after stretching.…
Autor*innen: | Maren Erdmann, Andreas KupschORCiD, Bernd R. MüllerORCiD, Manfred P. Hentschel, Ute Niebergall, Martin BöhningORCiD, Giovanni BrunoORCiD |
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Persönliche Herausgeber*innen: | Maren Erdmann |
Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Journal of Materials Science |
Jahr der Erstveröffentlichung: | 2019 |
Organisationseinheit der BAM: | 5 Werkstofftechnik |
5 Werkstofftechnik / 5.3 Polymere Verbundwerkstoffe | |
7 Bauwerkssicherheit | |
7 Bauwerkssicherheit / 7.5 Technische Eigenschaften von Polymerwerkstoffen | |
8 Zerstörungsfreie Prüfung | |
8 Zerstörungsfreie Prüfung / 8.5 Röntgenbildgebung | |
Verlag: | Springer US |
Verlagsort: | US |
Jahrgang/Band: | 54 |
Ausgabe/Heft: | 17 |
Erste Seite: | 11739 |
Letzte Seite: | 11755 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik | |
Freie Schlagwörter: | Cavitation; Crystal Texture; Diesel Fuel; Internal Surfaces; PE-HD Sorption; WAXS; X-ray refraction |
Themenfelder/Aktivitätsfelder der BAM: | Energie |
Material | |
Material / Degradation von Werkstoffen | |
DOI: | 10.1007/s10853-019-03700-8 |
ISSN: | 1573-4803 |
ISSN: | 0022-2461 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 20.06.2019 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 04.07.2019 |