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Erroneous or Arrhenius: A Degradation Rate-Based Model for EPDM during Homogeneous Ageing
- To improve the predictive capability of long-term stress relaxation of elastomers during thermo-oxidative ageing, a method to separate reversible and irreversible processes was adopted. The separation is performed through the analysis of compression set after tempering. On the Basis of this separation, a numerical model for long-term stress relaxation during homogeneous ageing is proposed. The model consists of an additive contribution of physical and chemical relaxation. Computer simulations of compression stress relaxation were performed for long ageing times and the results were validated with the Arrhenius treatment, the kinetic study and the time-temperature superposition technique based on experimental data. For chemical relaxation, two decay functions are introduced each with an activation energy and a degradative process. The first process with the lower activation energy dominates at lower ageing times, while the second one with the higher activation energy at longer ageingTo improve the predictive capability of long-term stress relaxation of elastomers during thermo-oxidative ageing, a method to separate reversible and irreversible processes was adopted. The separation is performed through the analysis of compression set after tempering. On the Basis of this separation, a numerical model for long-term stress relaxation during homogeneous ageing is proposed. The model consists of an additive contribution of physical and chemical relaxation. Computer simulations of compression stress relaxation were performed for long ageing times and the results were validated with the Arrhenius treatment, the kinetic study and the time-temperature superposition technique based on experimental data. For chemical relaxation, two decay functions are introduced each with an activation energy and a degradative process. The first process with the lower activation energy dominates at lower ageing times, while the second one with the higher activation energy at longer ageing times. A degradation-rate based model for the evolution of each process and ist contribution to the total system during homogeneous ageing is proposed. The main advantage of the model is the possibility to quickly validate the interpolation at lower temperatures within the range of slower chemical processes without forcing a straight-line extrapolation.…
Autor*innen: | Maha Zaghdoudi, Anja KömmlingORCiD, Matthias JaunichORCiD, Dietmar Wolff |
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Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Polymers |
Jahr der Erstveröffentlichung: | 2020 |
Organisationseinheit der BAM: | 3 Gefahrgutumschließungen; Energiespeicher |
3 Gefahrgutumschließungen; Energiespeicher / 3.4 Sicherheit von Lagerbehältern | |
Veröffentlichende Institution: | Bundesanstalt für Materialforschung und -prüfung (BAM) |
Jahrgang/Band: | 12 |
Ausgabe/Heft: | 9 |
Aufsatznummer: | 2152 |
Erste Seite: | 1 |
Letzte Seite: | 21 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik | |
Freie Schlagwörter: | Arrhenius; Chemical processes; Kinetic study; Modeling; Stress relaxation; TTS |
Themenfelder/Aktivitätsfelder der BAM: | Energie |
Energie / Kerntechnische Entsorgung | |
Material | |
Material / Degradation von Werkstoffen | |
DOI: | 10.3390/polym12092152 |
URN: | urn:nbn:de:kobv:b43-512931 |
ISSN: | 2073-4360 |
Verfügbarkeit des Dokuments: | Datei für die Öffentlichkeit verfügbar ("Open Access") |
Lizenz (Deutsch): | Creative Commons - CC BY - Namensnennung 4.0 International |
Datum der Freischaltung: | 23.09.2020 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 05.10.2020 |
Paper des Monats: | Ja |
Schriftenreihen ohne Nummerierung: | Wissenschaftliche Artikel der BAM |