Zitieren Sie bitte immer diesen URN: urn:nbn:de:kobv:b43-530571
Description of the concrete carbonation process with adjusted depth resolved thermogravimetric analysis
- The thermal gravimetric analysis (TG) is a common method for the examination of the carbonation progress of cement-based materials. Unfortunately, the thermal properties of some components complicate the evaluation of TG results. Various hydrate phases, like ettringite (AFt), C-S-H and AFm decompose almost simultaneously in the temperature range up to 200 °C. Additionally, physical bound water is released in the same temperature range. In the temperature range between 450 °C and 600 °C the decomposition of calcium hydroxide and amorphous or weakly bound carbonates takes place simultaneously. Carbonates, like calcite, from limestone powder or other additives may be already contained in the noncarbonated sample material. For this research an attempt was made to minimise the influence of these effects. Therefore, differential curves from DTG-results of non-carbonated areas and areas with various states of carbonation of the same sample material were calculated and evaluated. ConcretesThe thermal gravimetric analysis (TG) is a common method for the examination of the carbonation progress of cement-based materials. Unfortunately, the thermal properties of some components complicate the evaluation of TG results. Various hydrate phases, like ettringite (AFt), C-S-H and AFm decompose almost simultaneously in the temperature range up to 200 °C. Additionally, physical bound water is released in the same temperature range. In the temperature range between 450 °C and 600 °C the decomposition of calcium hydroxide and amorphous or weakly bound carbonates takes place simultaneously. Carbonates, like calcite, from limestone powder or other additives may be already contained in the noncarbonated sample material. For this research an attempt was made to minimise the influence of these effects. Therefore, differential curves from DTG-results of non-carbonated areas and areas with various states of carbonation of the same sample material were calculated and evaluated. Concretes based on three different types of cement were produced and stored under accelerated carbonation conditions (1 % CO2 in air). The required sample material was obtained by cutting slices from various depth of previously CO2-treated specimen and subsequent grinding. During the sample preparation, a special attention was paid that no additional carbonation processes took place. As reference method for the determination of the carbonation depth the sprayed application of phenolphthalein solution was carried out. Microscopic analysis where examined to confirm the assumptions made previously. Furthermore, the observed effect of encapsulation of calcium hydroxide by carbonates caused by the accelerated carbonation conditions was examined more closely.…
Autor*innen: | Nico VoglerORCiD, Philipp Drabetzki, Mathias Lindemann, Hans-Carsten KühneORCiD |
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Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Journal of Thermal Analysis and Calorimetry |
Jahr der Erstveröffentlichung: | 2021 |
Organisationseinheit der BAM: | 7 Bauwerkssicherheit |
7 Bauwerkssicherheit / 7.1 Baustoffe | |
7 Bauwerkssicherheit / 7.4 Baustofftechnologie | |
Veröffentlichende Institution: | Bundesanstalt für Materialforschung und -prüfung (BAM) |
Verlag: | Springer |
Jahrgang/Band: | 147 |
Ausgabe/Heft: | 11 |
Erste Seite: | 1 |
Letzte Seite: | 14 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurbau |
Freie Schlagwörter: | Accelerated carbonation; Carbonation behaviour; Concrete; Microscopy; Thermal Analysis |
Themenfelder/Aktivitätsfelder der BAM: | Infrastruktur |
DOI: | 10.1007/s10973-021-10966-1 |
URN: | urn:nbn:de:kobv:b43-530571 |
Verfügbarkeit des Dokuments: | Datei für die Öffentlichkeit verfügbar ("Open Access") |
Lizenz (Deutsch): | Creative Commons - CC BY - Namensnennung 4.0 International |
Datum der Freischaltung: | 04.08.2021 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 04.08.2021 |
Schriftenreihen ohne Nummerierung: | Wissenschaftliche Artikel der BAM |