Carbon capture and storage technique (CCS): Reliability of pipe steels used in Ketzin, Germany verified in laboratory saline aquifer corrosion experiments
- During the compression emission gasses in deep geological layers (Carbon Capture and Storage, CCS) CO2-corrosion will become a relevant safety issue. The reliability of the steels used at the geological onshore CCS-site at Ketzin, Germany, (heat treated steel 42CrMo4 (1.7225, AISI 4140) used for casing, and the martensitic stainless injection pipe steels X46Cr13 (1.4034, AISI 420 C), X20Cr13 (1.4021, AISI 420 J), X35CrMo17 (1.4122)) is demonstrated in 1 and 2 years laboratory experiments. Samples were kept in a synthetic aquifer environment similar to the geological CCS-site at Ketzin, Germany at T=60 °C. This corrosive environment is then saturated with technical CO2 at a flow rate of 3 l/h. Microstructures were characterized by X-ray diffraction, light microscopy, scanning electron microscopy, and energy dispersive X-ray, after a series of heat treatments (700 h to 2 years). Due to very slow mass loss at extended exposure times to CCS-environment one year is sufficient to predictDuring the compression emission gasses in deep geological layers (Carbon Capture and Storage, CCS) CO2-corrosion will become a relevant safety issue. The reliability of the steels used at the geological onshore CCS-site at Ketzin, Germany, (heat treated steel 42CrMo4 (1.7225, AISI 4140) used for casing, and the martensitic stainless injection pipe steels X46Cr13 (1.4034, AISI 420 C), X20Cr13 (1.4021, AISI 420 J), X35CrMo17 (1.4122)) is demonstrated in 1 and 2 years laboratory experiments. Samples were kept in a synthetic aquifer environment similar to the geological CCS-site at Ketzin, Germany at T=60 °C. This corrosive environment is then saturated with technical CO2 at a flow rate of 3 l/h. Microstructures were characterized by X-ray diffraction, light microscopy, scanning electron microscopy, and energy dispersive X-ray, after a series of heat treatments (700 h to 2 years). Due to very slow mass loss at extended exposure times to CCS-environment one year is sufficient to predict stable surface corrosion rates from laboratory experiments. The non-linear isothermal surface corrosion behaviour of the steels reveals surface corrosion rates around 0.1 to 0.8 mm/year, when obtained by mass gain. The loss of the base material is higher when calculated from the corrosion layer magnitude due to the unpredictable local corrosion attacks. Severe pit corrosion (pit heights ca. 4.5 mm) are only located on the high chromium steels. Main phases of the continuous scales are siderite FeCO3 and goethite α-FeOOH. The formation of the non-protective layer is likely to form via a transient Fe(OH)2-phase.…
Autor*innen: | Anja Pfennig, Barbara Linke, Axel KranzmannORCiD |
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Dokumenttyp: | Beitrag zu einem Sammelband |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | MWWD & IEMES 2010 - 6th International conference on marine waste water discharges and coastal environment (Proceedings) |
Jahr der Erstveröffentlichung: | 2010 |
Herausgeber (Institution): | MWWD Organiszation |
Ausgabe/Heft: | Paper 047_P |
Erste Seite: | 1 |
Letzte Seite: | 17 |
Freie Schlagwörter: | CCS; CO2-injection; CO2-storage; Corrosion; Environmental issues; Phase formation; Saline aquiver |
Veranstaltung: | MWWD & IEMES 2010 - 6th International conference on marine waste water discharges and coastal environment |
Veranstaltungsort: | Langkawi, Malaysia |
Beginndatum der Veranstaltung: | 2010-10-25 |
Enddatum der Veranstaltung: | 2010-10-29 |
ISBN: | 978-9944-5566-4-4 |
Verfügbarkeit des Dokuments: | Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access") |
Bibliotheksstandort: | Sonderstandort: Publica-Schrank |
Datum der Freischaltung: | 19.02.2016 |
Referierte Publikation: | Nein |