Novel Boehmite-embedded organic/inorganic hybrid nanocomposite: cure behaviour, morphology and thermal properties
- Hybrid materials have attracted growing interest during the last decade, particularly due to their extraordinary properties. Cycloalyphatic-epoxy oligosiloxane (CEO) resin was shown to be a good candidate as a barrier material for the encapsulation purposes. Incorporation of inorganic nanoparticles such as Boehmite (BA) into polymers was observed to modify their specific characteristics, in particular, thermal, thermo-oxidative and barrier ones. In this work, novel BA-embedded organic inorganic hybrid nanocomposite material was engineered by combining the advantageous properties of hybrid polymers and nanoparticle enhancement effect. Impacts of particles on the photocuring kinetics, degree of crosslinking and the resultant changes in the thermal properties of the cured films were investigated. CEO synthesis via condensation reaction was confirmed by 1H and 29Si NMR. The particle distribution within the films was verified by SEM including transmission mode coupled with EDX elementalHybrid materials have attracted growing interest during the last decade, particularly due to their extraordinary properties. Cycloalyphatic-epoxy oligosiloxane (CEO) resin was shown to be a good candidate as a barrier material for the encapsulation purposes. Incorporation of inorganic nanoparticles such as Boehmite (BA) into polymers was observed to modify their specific characteristics, in particular, thermal, thermo-oxidative and barrier ones. In this work, novel BA-embedded organic inorganic hybrid nanocomposite material was engineered by combining the advantageous properties of hybrid polymers and nanoparticle enhancement effect. Impacts of particles on the photocuring kinetics, degree of crosslinking and the resultant changes in the thermal properties of the cured films were investigated. CEO synthesis via condensation reaction was confirmed by 1H and 29Si NMR. The particle distribution within the films was verified by SEM including transmission mode coupled with EDX elemental analysis. Photocuring kinetics and thermal properties of the films were studied by in situ FTIR spectroscopy and DSC with TGA, respectively.…
Autor*innen: | Ievgeniia TopolniakORCiD |
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Koautor*innen: | Vasile-Dan HodoroabaORCiD, Sigrid Benemann, Dietmar Pfeifer, Heinz SturmORCiD |
Dokumenttyp: | Posterpräsentation |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2018 |
Organisationseinheit der BAM: | 6 Materialchemie |
6 Materialchemie / 6.0 Abteilungsleitung und andere | |
6 Materialchemie / 6.1 Oberflächen- und Dünnschichtanalyse | |
6 Materialchemie / 6.6 Physik und chemische Analytik der Polymere | |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Freie Schlagwörter: | Boehmite; CEO; Cycloalyphatic epoxy oligosiloxane; Nanocomposite |
Themenfelder/Aktivitätsfelder der BAM: | Material |
Veranstaltung: | Deutschen Physikalischen Gesellschaft |
Veranstaltungsort: | Berlin, Germany |
Beginndatum der Veranstaltung: | 11.03.2018 |
Enddatum der Veranstaltung: | 16.03.2018 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 20.03.2018 |
Referierte Publikation: | Nein |