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Thermally sprayed titanium suboxide coatings for piston ring/cylinder liners under mixed lubrication and dry-running conditions

  • Two new substoichiometric titania (TiOx) coatings designated for cylinder liner application were deposited on specimen of grey cast iron GG20HCN with high carbon content by plasma spraying. First, a TinO2n-1 coating was prepared by atmospheric plasma spraying (APS) using a sintered and agglomerated Magnéli-type spray powder. Second a TiO1.95-x coating was deposited with a vacuum plasma spray (VPS) process using a commercial, fused and crushed TiO1.95 powder. The tribological behaviour of these coatings under lubricated conditions was compared with uncoated specimen of this grey cast iron. As counter bodies a widespread used APS-sprayed Mo-NiCrBSi piston ring coating (MKP81A®), an advanced HVOF-sprayed WC/Cr3C2-based (MKJet502®) ring coating as well as non-commercial prototype APS-sprayed TinO2n-1 and APS-sprayed (Ti,Mo)(C,N) + 23NiMo (TM23-1) coatings were tribotested. The interaction of the pairs with prototype engine oils based on esters and polyglycols were studied underTwo new substoichiometric titania (TiOx) coatings designated for cylinder liner application were deposited on specimen of grey cast iron GG20HCN with high carbon content by plasma spraying. First, a TinO2n-1 coating was prepared by atmospheric plasma spraying (APS) using a sintered and agglomerated Magnéli-type spray powder. Second a TiO1.95-x coating was deposited with a vacuum plasma spray (VPS) process using a commercial, fused and crushed TiO1.95 powder. The tribological behaviour of these coatings under lubricated conditions was compared with uncoated specimen of this grey cast iron. As counter bodies a widespread used APS-sprayed Mo-NiCrBSi piston ring coating (MKP81A®), an advanced HVOF-sprayed WC/Cr3C2-based (MKJet502®) ring coating as well as non-commercial prototype APS-sprayed TinO2n-1 and APS-sprayed (Ti,Mo)(C,N) + 23NiMo (TM23-1) coatings were tribotested. The interaction of the pairs with prototype engine oils based on esters and polyglycols were studied under mixed/boundary lubrication using the BAM test method. Lubricants were factory fill engine oils, ester-containing lubricants with low-SAP (sulphur–ash–phosphor) and/or bio-no-tox properties as well as polyglycole-based lubricants. The ester and polyglycole-based engine oils respond both to bio-no-tox criteria and are polymer-free. They follow different strategies to reduce zinc, phosphorus and sulphur to assure a low ash content. Both TiOx coatings designated for cylinder liners meet or exceed the wear resistance of the grey cast iron with high carbon content when paired with APS-sprayed TinO2n-1 or Mo-NiCrBSi piston ring coatings. Overall, in nearly all pairs the wear rates of the APS TinO2n-1 coating were lower than those of the VPS TiO1.95-x coating. In order to characterize the tribological behaviour under oil-off, dry-running conditions, additional tests were performed under unlubricated unidirectional sliding conditions at 22 and 400 °C for a sliding speed of 1 m/s against sintered polycrystalline Al2O3 as stationary specimen.zeige mehrzeige weniger

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Metadaten
Autor*innen:André Skopp, Norbert Kelling, Mathias WoydtORCiD, L.-M. Berger
Dokumenttyp:Zeitschriftenartikel
Veröffentlichungsform:Verlagsliteratur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Wear
Jahr der Erstveröffentlichung:2007
Verlag:Elsevier
Verlagsort:Amsterdam
Jahrgang/Band:262
Ausgabe/Heft:9-10
Erste Seite:1061
Letzte Seite:1070
Freie Schlagwörter:Bio-oils (ester, PAG, glycols, bio-no-tox, low ash); Magnéli phases; Piston ring/cylinder liner wear simulation under mixed/boundary lubrication; Thermally sprayed coatings; Triboactive coatings
ISSN:0043-1648
Verfügbarkeit des Dokuments:Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")
Bibliotheksstandort:Sonderstandort: Publica-Schrank
Datum der Freischaltung:19.02.2016
Referierte Publikation:Ja
Datum der Eintragung als referierte Publikation:29.03.2007
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