Zitieren Sie bitte immer diesen URN: urn:nbn:de:kobv:b43-594018
High CO2 reduction activity on AlCrCoCuFeNi multi-principal element alloy nanoparticle electrocatalysts prepared by means of pulsed laser ablation
- Noble metal-free nanoparticles (NPs) based on multi-principal element alloys (MPEAs) were synthesized using a one-step pulsed laser ablation in liquids (PLALs) method for the electrochemical reduction of CO2. Laser ablation was performed in pure water or poly-(diallyldimethylammonium chloride) (PDADMAC)-containing an aqueous solution of Al8Cr17Co17Cu8Fe17Ni33 MPEA targets. Transmission electron microscopy (TEM) measurements combined with energy dispersive X-ray (EDX) mapping were used to characterize the structure and composition of the laser-generated MPEA nanoparticles (MPEA-NPs). These results confirmed the presence of a characteristic elemental distribution of a core-shell phase structure as the predominant NP species. The electrocatalytic performance of the laser-generated MPEA-NPs was characterized by linear sweep voltammetry (LSV) demonstrating an enhanced electrocatalytic CO2 activity for PDADMAC-stabilized NPs. The findings of these investigations indicate that MPEAs haveNoble metal-free nanoparticles (NPs) based on multi-principal element alloys (MPEAs) were synthesized using a one-step pulsed laser ablation in liquids (PLALs) method for the electrochemical reduction of CO2. Laser ablation was performed in pure water or poly-(diallyldimethylammonium chloride) (PDADMAC)-containing an aqueous solution of Al8Cr17Co17Cu8Fe17Ni33 MPEA targets. Transmission electron microscopy (TEM) measurements combined with energy dispersive X-ray (EDX) mapping were used to characterize the structure and composition of the laser-generated MPEA nanoparticles (MPEA-NPs). These results confirmed the presence of a characteristic elemental distribution of a core-shell phase structure as the predominant NP species. The electrocatalytic performance of the laser-generated MPEA-NPs was characterized by linear sweep voltammetry (LSV) demonstrating an enhanced electrocatalytic CO2 activity for PDADMAC-stabilized NPs. The findings of these investigations indicate that MPEAs have great potential to replace conventional, expensive noble metal electrocatalysts.…
Autor*innen: | H. Pérez Blanes, P. Ghiasi, J. Sandkühler, Yasemin Yesilcicek, Simone Pentzien, Andrea Conradi, Carsten Prinz, Dominik Al-Sabbagh, Andreas ThünemannORCiD, Ozlem Ozcan, Julia WittORCiD |
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Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Journal of Materials Research and Technology |
Jahr der Erstveröffentlichung: | 2023 |
Organisationseinheit der BAM: | 6 Materialchemie |
6 Materialchemie / 6.2 Material- und Oberflächentechnologien | |
6 Materialchemie / 6.3 Strukturanalytik | |
6 Materialchemie / 6.5 Synthese und Streuverfahren nanostrukturierter Materialien | |
Veröffentlichende Institution: | Bundesanstalt für Materialforschung und -prüfung (BAM) |
Verlag: | Elsevier BV |
Jahrgang/Band: | 24 |
Erste Seite: | 9434 |
Letzte Seite: | 9440 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Freie Schlagwörter: | CCMat; Carbon dioxide reduction; Chemically Complex Materials; Electrocatalysis; Multi-principal element alloys; Pulsed laser ablation |
Themenfelder/Aktivitätsfelder der BAM: | Energie |
Energie / Elektrische Energiespeicher und -umwandlung | |
Material | |
Material / Materialdesign | |
DOI: | 10.1016/j.jmrt.2023.05.143 |
URN: | urn:nbn:de:kobv:b43-594018 |
Verfügbarkeit des Dokuments: | Datei für die Öffentlichkeit verfügbar ("Open Access") |
Lizenz (Deutsch): | Creative Commons - CC BY - Namensnennung 4.0 International |
Datum der Freischaltung: | 23.01.2024 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 23.01.2024 |
Schriftenreihen ohne Nummerierung: | Wissenschaftliche Artikel der BAM |