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Mass fraction assignment of Bisphenol-A high purity material

  • The CCQM-K148.a comparison was coordinated by the BIPM on behalf of the CCQM Organic Analysis Working Group for NMIs and DIs which provide measurement services in organic analysis under the CIPM MRA. It was undertaken as a "Track A" comparison within the OAWG strategic plan. CCQM-K148.a demonstrates capabilities for assigning the mass fraction content of a solid organic compound having moderate molecular complexity, where the compound has a molar mass in the range (75 - 500) g/mol and is non-polar (pKow < −2), when present as the primary organic component in a neat organic solid and where the mass fraction content of the primary component in the material is in excess of 950 mg/g. Participants were required to report the mass fraction of Bisphenol A present in one supplied unit of the comparison material. Participants using a mass balance method for the assignment were also required to report their assignments of the impurity components present in the material. Methods used by theThe CCQM-K148.a comparison was coordinated by the BIPM on behalf of the CCQM Organic Analysis Working Group for NMIs and DIs which provide measurement services in organic analysis under the CIPM MRA. It was undertaken as a "Track A" comparison within the OAWG strategic plan. CCQM-K148.a demonstrates capabilities for assigning the mass fraction content of a solid organic compound having moderate molecular complexity, where the compound has a molar mass in the range (75 - 500) g/mol and is non-polar (pKow < −2), when present as the primary organic component in a neat organic solid and where the mass fraction content of the primary component in the material is in excess of 950 mg/g. Participants were required to report the mass fraction of Bisphenol A present in one supplied unit of the comparison material. Participants using a mass balance method for the assignment were also required to report their assignments of the impurity components present in the material. Methods used by the seventeen participating NMIs or DIs were predominantly based on either stand-alone mass balance (summation of impurities) or qNMR approaches, or the combination of data obtained using both methods. The results obtained using thermal methods based on freezing-point depression methods were also reported by a limited number of participants. There was excellent agreement between assignments obtained using all three approaches to assign the BPA content. The assignment of the values for the mass fraction content of BPA consistent with the KCRV was achieved by most of the comparison participants with an associated relative standard uncertainty in the assigned value in the range (0.1 - 0.5)%.zeige mehrzeige weniger

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Metadaten
Autor*innen:S. Westwood, G. Martos, R. Josephs, T. Choteau, R. Wielgosz, S. Davies, M. Moawad, G. Tarrant, B. Chan, M. Alamgir, E. de Rego, W. Wollinger, B. Garrido, J. Fernandes, R. de Sena, R. Oliveira, J. Melanson, J. Bates, P. Mai Le, J. Meija, C. Quan, T. Huang, W. Zhang, R. Ma, S. Zhang, Y. Hao, Y. He, S. Song, H. Wang, F. Su, T. Zhang, H. Li, W. Lam, W. Wong, W. Fung, Rosemarie Philipp, Ute Dorgerloh, Klas MeyerORCiD, Christian Piechotta, Juliane Riedel, Tanja Westphalen, P. Giannikopoulou, Ch. Alexopoulos, E. Kakoulides, Y. Kitamaki, T. Yamazaki, Y. Shimizu, M. Kuroe, M. Numata, A. Pérez-Castorena, M. Balderas-Escamilla, J. Garcia-Escalante, A. Krylov, A. Mikheeva, M. Beliakov, M. Palagina, I. Tkachenko, S. Spirin, V. Smirnov, T. Tang Lin, C. Pui Sze, W. Juan, W. Lingkai, L. Ting, L. Quinde, C. Yizhao, S. Lay Peng, M. Fernandes-Whaley, D. Prevoo-Franzsen, L. Quinn, N. Nhlapo, D. Mkhize, D. Marajh, S. Chamane, S. Ahn, K. Choi, S. Lee, J. Han, S. Baek, B. Kim, S. Marbumrung, P. Jongmesuk, K. Shearman, C. Boonyakong, M. Bilsel, S. Gündüz, I. Ün, H. Yilmaz, G. Bilsel, T. Gökçen, C. Clarkson, J. Warren, E. Achtar
Dokumenttyp:Zeitschriftenartikel
Veröffentlichungsform:Verlagsliteratur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Metrologia
Jahr der Erstveröffentlichung:2021
Organisationseinheit der BAM:1 Analytische Chemie; Referenzmaterialien
1 Analytische Chemie; Referenzmaterialien / 1.4 Prozessanalytik
1 Analytische Chemie; Referenzmaterialien / 1.7 Organische Spuren- und Lebensmittelanalytik
1 Analytische Chemie; Referenzmaterialien / 1.8 Umweltanalytik
Herausgeber (Institution):Bureau International des Poids et Mesures (BIPM)
Verlag:IOP Publishing
Jahrgang/Band:58
Ausgabe/Heft:1A
Aufsatznummer:08015
Erste Seite:08015
DDC-Klassifikation:Naturwissenschaften und Mathematik / Chemie / Analytische Chemie
Freie Schlagwörter:Bisphenol-A; Interlaboratory key comparison; Metrology; Purity assessment
Themenfelder/Aktivitätsfelder der BAM:Chemie und Prozesstechnik
Chemie und Prozesstechnik / Chemische Charakterisierung und Spurenanalytik
DOI:10.1088/0026-1394/58/1A/08015
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:05.01.2022
Referierte Publikation:Ja
Datum der Eintragung als referierte Publikation:05.01.2022
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