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Operation and Optimal Control of Multiphase Systems – Hydroformylation in Microemulsions on the Mini-plant Scale

  • Hydroformylation of short-chained olefins has been established as a standard industrial process for the production of C2 to C6 aldehydes. Using aqueous solutions of transition metal complexes these processes are carried out homogeneously catalyzed. A biphasic approach allows for highly efficient catalyst recovery. Regarding renewable feedstocks, the hydroformylation of long-chained alkenes (> C10) in a biphasic system, using highly selective rhodium catalysts has yet not been shown. Therefore, the Collaborative Research Center SFB/TR 63 InPROMPT develops new process concepts, involving innovative tuneable solvent systems to enable rather difficult or so far nonviable synthesis paths. One possible concept is the hydroformylation of long-chained alkenes in microemulsions. For this, a modular mixer-settler concept was proposed, combining high reaction rates and efficient catalyst recycling via the application of technical grade surfactants. The feasibility of such a concept is evaluatedHydroformylation of short-chained olefins has been established as a standard industrial process for the production of C2 to C6 aldehydes. Using aqueous solutions of transition metal complexes these processes are carried out homogeneously catalyzed. A biphasic approach allows for highly efficient catalyst recovery. Regarding renewable feedstocks, the hydroformylation of long-chained alkenes (> C10) in a biphasic system, using highly selective rhodium catalysts has yet not been shown. Therefore, the Collaborative Research Center SFB/TR 63 InPROMPT develops new process concepts, involving innovative tuneable solvent systems to enable rather difficult or so far nonviable synthesis paths. One possible concept is the hydroformylation of long-chained alkenes in microemulsions. For this, a modular mixer-settler concept was proposed, combining high reaction rates and efficient catalyst recycling via the application of technical grade surfactants. The feasibility of such a concept is evaluated in a fully automated, modular mini-plant system within which the characteristics of such a multiphase system pose several obstacles for the operation. Maintaining a stable phase separation for efficient product separation and catalyst recycling is complicated by small and highly dynamic operation windows as well as poor measurability of component concentrations in the liquid phases. In this contribution, a model-based strategy is presented to enable concentration tracking and phase state control within dynamic mini-plant experiments. Raman spectroscopy is used as an advanced process analytical tool, which allows for online in-situ tracking of concentrations. Combined with optical and conductivity analysis optimal plant trajectories can be calculated via the solution of dynamic optimization problem under uncertainty. Applying these, a stable reaction yield of 40 % was achieved, combined with an oil phase purity of 99,8 % (total amount of oily components in the oil phase) and catalyst leaching below 0.1 ppm.zeige mehrzeige weniger

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  • EuroPACT_2017_Illner_et_al_92.pdf
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  • BoA_EuroPACT_2017_titel.pdf
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Metadaten
Autor*innen:M. Illner, Klas MeyerORCiD, Andrea PaulORCiD, E. Esche, Michael MaiwaldORCiD, J.-U. Repke
Dokumenttyp:Beitrag zu einem Tagungsband
Veröffentlichungsform:Graue Literatur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):Processdings of 4th European Conference on Process Analytics and Control Technology (EuroPACT 2017)
Jahr der Erstveröffentlichung:2017
Herausgeber (Institution):DECHEMA e. V., Frankfurt
Verlagsort:Frankfurt a. M.
Erste Seite:92
Letzte Seite:92
DDC-Klassifikation:Naturwissenschaften und Mathematik / Chemie / Analytische Chemie
Freie Schlagwörter:Dispersion; EuroPACT; Hydroformylation; Micoemulsion; Mini-plant; Process Analytical Technology
Veranstaltung:4th European Conference on Process Analytics and Control Technology (EuroPACT 2017)
Veranstaltungsort:Potsdam, Germany
Beginndatum der Veranstaltung:10.05.2017
Enddatum der Veranstaltung:12.05.2017
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:15.05.2017
Referierte Publikation:Nein
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